四川大学化学学院
师资力量

蔡中正     特聘副研究员

研究方向:高分子化学,无机化学

联系方式:          Email:zzcai@scu.edu.cn

个人主页:点击进入

简历:

2021.12–至今,四川大学化学学院,特聘副研究员

2019.01–2021.05,美国俄亥俄州立大学,博士后,合作导师:Prof. Casey R Wade

2013.09–2018.08,美国休斯顿大学化学专业,理学博士,导师:Prof. Loi H Do

2009.09–2013.06,中国人民大学化学专业,理学学士, 导师: 徐立进教授

主要研究方向

高性能可循环高分子设计与合成

高分子聚合催化剂的设计

主要工作业绩

博士主要研究方向为聚烯烃催化剂的开发,博士后的主要研究方向为金属有机框架材料的设计与开发。论文发表在J. Am. Chem. Soc, Angew. Chem. Int. Ed., Chem. Mater. 以及 Organometallics等国际期刊,申请专利2项。获得休斯顿大学校长奖学金, Axalta & PCI企业奖学金,化学系优秀科研奖学金等。以参与人的身份申请并参与实验的项目基金4项,包括美国自然科学基金,Welch基金与美国航天局的基金。现研究方向为新型可循环高分子材料。

主要奖励和荣誉

2018 Graduate Research Excellence Award (University of Houston)

2016 The Axalta PCI Scholarship

2013 Presidential Graduate Fellowship (University of Houston)

2013 中国人民大学理学院优秀毕业生

2011-2012 中国人民大学二等奖学金

2010 平安励志奖学金 

代表性成果 (获奖成果、专著、论文、专利)

13. Yang, X.; Zhang, W.; Huang, H.-Y.; Dai, J.; Wang, M.-Y.; Fan, H.-Z.; Cai, Z.*; Zhang, Q.*; Zhu, J.-B*. Stereoselective Ring-Opening Polymerization of Lactones with a Fused Ring Leading to Semicrystalline Polyesters. Macromolecules 2022, 55 (7), 2777–2786.

12. Fan, H.-Z.; Yang, X.; Chen, J.-H.; Tu, Y.-M.; Cai, Z.*; Zhu, J.-B.* Advancing the Development of Recyclable Aromatic Polyesters by Functionalization and Stereocomplexation. Angew. Chem. Int. Ed. 2022, e202117639.

11. Zhang, W.; Dai, J.; Wu, Y.-C.; Chen, J.-X.; Shan, S.-Y.; Cai, Z.*; Zhu, J.-B.* Highly Reactive Cyclic Carbonates with a Fused Ring toward Functionalizable and Recyclable Polycarbonates. ACS Macro Lett. 2022, 11, 2, 173–178.

10. Tu, Y.-M.; Wang, X.-M.; Yang, X.; Fan, H.-Z.; Gong, F.-L.; Cai, Z.*; Zhu, J.-B.* Biobased High-Performance Aromatic–Aliphatic Polyesters with Complete Recyclability. J. Am. Chem. Soc. 2021, 143, 20591.

9. Cai Z.; Tao W.; Curtis M.; Zhang S.; Wade C. R.* Direct NO reduction by a Biomimetic Iron(II) Pyrazolate MOF. Angew. Chem. Int. Ed., 2021, 60, 21221.

8. Cai Z.; Xiao D.; Do L. H.* Fine-Tuning Nickel Phenoxyimine Olefin Polymerization Catalysts: Performance Boosting by Alkali Cations. J. Am. Chem. Soc. 2015, 137, 15501.

7. Cai Z.; Bien C.; Liu Q.; Wade C. R.* Insights into CO2 Adsorption in M-OH Functionalized MOFs. Chem. Mater. 2020, 32, 4257.

6. Bien C ; Cai Z; Wade C. R.* Using Postsynthetic X-type Ligand Exchange (PXLE) to Enhance CO2Adsorption in MOFs with Kuratowski-type Building Units. Inorg. Chem. 2021, 60, 11784. (co-first author)

5. Cai Z.; Do L. H.* Customizing Polyolefin Morphology by Selective Pairing of Alkali Ions with Nickel Phenoxyimine-Polyethylene Glylcol Catalyst. Organometallics 2017, 36, 4691.

4. Cai Z.; Do L. H.* Thermally Robust Heterobimetallic Palladium-Alkali Catalysts for Ethylene and Alkyl Acrylate Copolymerization. Organometallics 2018, 37, 3874.

3. Cai Z.; D. Xiao, Do L. H.* Cooperative Heterobimetallic Catalysts in Coordination Insertion Polymerization. Comment Inorg. Chem. 2019, 39, 27.

2. Xiao D.; Cai Z.; Do L. H.* Accelerating Ethylene Homo- and Copolymerization Capabilities Using Secondary Metal Ions in Tetrahydrofuran. Dalton Trans. 2019, 48, 17887.

1. Jiang Z.; Zhang L.; Dong C.; Cai Z.; Tang W.; Li H.; Xu L.*; Xiao J.* Palladium-catalyzed Highly Regioselective Arylation of Electron-rich Allylamines with Thiophenes and Furans. Adv. Synth. Catal. 2012, 354, 3225.

专利

1. PCT/US19/39149 “Heterobimetallic Catalysts and Site-Differentiated Ligands for Preparation”.

2. PCT/US19/036597 “Metal-Organic Frameworks Containing Metal-Hydroxide Moieties and Methods of Making and Using”.

关闭