四川大学化学学院
师资力量

李建梅     副教授

研究方向:绿色化学/物理化学

联系方式:85415608          Email:lijianmei@scu.edu.cn

个人主页:点击进入

简历:

教育及工作经历:

2016.9-至今,四川大学化学学院,副教授(绿色化学、物理化学),硕士生导师

2009.72016.9,四川大学化学学院,讲师(绿色化学、物理化学)

2004.92009.6,四川大学化学学院,攻读硕、博士学位(物理化学),导师:孟祥光、胡常伟

主要研究方向:

生物质能源化学

均相、多相催化化学

(手性)羧酸产品的绿色合成

欢迎本科生加入本课题组开展“大创”项目和本科毕业设计!

主要工作业绩

面向生物质资源高效利用的国家重大战略需求,助力实现国家“双碳”目标,李建梅博士针对“生物质组成结构复杂及天然手性结构难以保持,造成产品选择性差、光学纯度低、过程C原子利用率低的难题开展了系统研究,主要成果如下:1)首次实现了由生物质基糖高对映选择性制备D-乳酸,揭示了手性中心的形成机制,建立了由真实生物质制备手性乳酸的催化工艺;2)构建了多功能催化体系,实现生物质基糖类C-CC-O键的多路线可控转化,在提高转化过程C原子利用率方面取得突破性进展,选择性获得了多种类小分子(手性)含氧化学品。 

以第一/通讯作者(含共同通讯作者)在本领域主流期刊发表SCI论文40余篇,包括Angew. Chem. Int. Ed., ACS Catal. Appl. Catal. B: Environ.IF 24.32篇)、Chem. Eng. J.IF 16.75篇)、Sci. Total Environ.IF 10.71篇)、J. Catal.ACS Sustainable Chem. Eng.Renew. EnergyChemSusChemInd. Eng. Chem. Res.等。其中中科院一区19 ESI 高被引论文(1%1 篇、亮点论文1 篇。单篇最高引用超过200次、论文总被引约1200次(1500余次,Google),H 指数19Web of Science)。申请中国发明专利8项,授权6项。主持国家自然科学基金面上项目2项、青年项目1项,四川省应用基础项目等,参与多项国家自然科学基金面上、重点项目及973项目等。以第二完成人编著专著一部(《生物质转化利用》,2019,科学出版社,北京)。多次应邀参与国际国内学术会议,并作邀请报告。担任国际高水平杂志审稿人,如Chem. Eng. JGreen Chem.等。

近期承担科研项目:

1. 官能团修饰法调控生物质基糖C-C键选择性断裂制备双中心手性羧酸研究,国家自然科学基金面上项目,批准号:224782632025.1-2028.12,直接经费50万,在研,主持。

2. 由生物质基糖类选择性转化制备高光学纯度手性C3酸研究,国家自然科学基金面上项目,批准号:221782342022.1-2025.1275.9万元,主持。

3. Yolk/shell 固体催化剂催化乙酰丙酸和甲酸制备γ-戊内酯的研究,国家自然科学基金青年基金,批准号:216061552017.1-2019.12 主持。

4. Core-Shell 双功能催化剂催化乙酰丙酸和甲酸制备γ-戊内酯的研究,四川省应用基础项目,批准号: 2016JY0189 主持。

主要奖励和荣誉

1. 教育部第三届基础学科拔尖培养计划2.0“提问与猜想”活动, 优秀指导教师 (2023)

2.四川大学2023年基础学科拔尖学生“挑战与猜想”活动二等奖指导教师 2023年)

3.“挑战杯”四川大学2022-2023年度大学生课外学术科技作品三等奖指导教师 2023年)。

4. 所在“生物质转化与绿色化学合成团队”荣获四川大学第七届“徳渥群芳”育人文化建设标兵团队 2021年)。

5. 四川大学“课堂教学优秀质量奖” 2019年)。

6. 第三届四川大学互联网+创新创业大赛三等奖指导教师 2017年)。

7. 四川大学 “全英语授课教学质量优秀奖” 2012 年)。

8. 四川大学 “精品开放课程建设突出贡献奖” 2013年)。

代表性成果(获奖成果、专著、论文、专利)

主要发表论文:

1. R. Yang, S. Xu, X. Wang, Y. Xiao, J. Li*, C. Hu*, Selective Stereoretention of Carbohydrates upon C-C Cleavage Enabling D-Glyceric Acid Production with High Optical Purity over Ag/γ-Al2O3 catalyst, Angew. Chem. Int. Ed. 2024, 63, e202403547.

2. J. Qin , R. Li , Q. Tian , G. Li , J. Li*, C. HuInsights into the selectivity to glyceric acid and lactic acid from biomass: Reaction mechanism and temperature effect, Chem. Eng. J., 2024, 494, 153038.

3.Y. Liu, S. Zhou, X. Wang, J. Qin, C. Hu, J. Li*, Coproduction of glyceric acid and glycolic acid from biomass-based sugars over Ru/Co3O4 catalyst, ACS Catalysis, 2024, 14, 7609−7623.

4.  Y. Xiao, S. Xu, X. Wang, Z. Lu, C. Hu, J. Li*, Enteromorpha prolifera valorization to acetol over supported Pd catalysts: Role of the support, Chemical Engineering Journal, 2023, 475, 146295.

5.  W. Zhang, S. Xu, X. Wang, Y. Liu, R. Yang, J. Li*, C. Hu*,The chemo-catalytic racemization of lactic acid enantiomer derived from biomass via keto-enol tautomerization, Industrial Crops & Products, 2023, 193, 116260.

6. J. Li, R. Yang, S. Xu, C. Zhou, Y. Xiao, C. Hu*, D. C.W. Tsang*, Biomass-derived polyols valorization towards glycolic acid production with high atom-economy, Applied Catalysis B: Environmental, 2022, 317, 121785.

7. S. Xu, Y. Xiao, J. Li*, W. Zhang, C. Hu*, Oligomer-first mechanism in the transformation of biomass derivatives selectively to produce D-lactic acid, Chemical Engineering Journal, 2022, 134359.

8. S. Xu, Y. Xiao, W. Zhang, S. Liao, R. Yang, J. Li*, C. Hu*, Relay catalysis of copper-magnesium catalyst on efficient valorization of glycerol to glycolic acid, Chemical Engineering Journal, 2022, 428, 132555.

9. Y. Xiao, S. Chen, J. Li, Z. Lu, C. Hu, Cooperative roles of Sn(IV) and Cu(II) for efficient transformation of biomass-derived acetol towards lactic acid production, Science of the Total Environment, 2022, 833, 155044.

10. Y. Xiao, S. Liao, S. Xu, J. Li*, Z. Lu*, C. Hu, Selective transformation of typical sugars to lactic acid catalyzed by dealuminated ZSM-5 supported erbium, Renewable Energy, 2022, 187, 551-560.

11. S. Liao, Q. Tian, Y. Xiao, D. Qin, J. Li*, and C. Hu*, Glycerol Valorization Towards Glycolic Acid Production Over Cu-Based Biochar Catalyst, ChemSusChem, 2022, 15, e202201537.

12. Q. Tian, X. Wang, W. Zhang, S. Liao, C. Hu, and J. Li*, Low-Temperature Production of Glyceric Acid from Biomass-Based Sugar via the Cooperative Roles of MgO and NaBF4, Ind. Eng. Chem. Res., 2022, 61, 16689−16701.

13. S. Xu, Q. Tian, Y. Xiao, W. Zhang, S. Liao, J. Li*, C. Hu*, Regulating the competitive reaction pathway in glycerol conversion to lactic acid/glycolic acid selectively, Journal of Catalysis, 2022, 413, 407–416.

14. S. Xu, T. He, J. Li*, Z. Huang, C. Hu*, Enantioselective synthesis of D-lactic acid via chemocatalysis using MgO: Experimental and molecular-based rationalization of the triose's reactivity and preliminary insights with raw biomass. Applied Catalysis B: Environmental. 2021, 292,120145.

15. W. Zhang, S. Xu, Y. Xiao, D. Qin, J. Li*, C. Hu*, The insights into the catalytic performance of rare earth metal ions on lactic acid formation from biomass via microwave heating, Chemical Engineering Journal, 2021, 421, 130014.

16. C. Zhou, Y. Xiao, S. Xu, J. Li*, C. Hu*, gamma-Valerolactone Production from Furfural Residue with Formic Acid as the Sole Hydrogen Resource via an Integrated Strategy on Au-Ni/ZrO2, Industrial & Engineering Chemistry Research, 2020, 59(39), 17228–17238.

17. Y. Xiao, S. Xu, W. Zhang, J. Li* and C. Hu*, One-Pot Chemo-Catalytic Conversion of Glucose to Methyl Lactate Over In/γ-Al2O3 Catalyst, Catal. Today, 2021, 365, 249-256.

18. S. Xu, Y. Wu, J. Li*, T. He, Y. Xiao, C. Zhou, and C. Hu*, Directing the Simultaneous Conversion of Hemicellulose and Cellulose in Raw Biomass to Lactic Acid, ACS Sustainable Chem. Eng. 2020, 8, 4244−4255.

19. J. Li, W. Zhang, S. Xu and C. Hu*, The Roles of H2O/Tetrahydrofuran System in Lignocellulose Valorization, Front. Chem. 2020, 8:70.

20. S. Xu, J. Li, J. Li*, Y. Wu, Y. Xiao, and C. Hu*, D-Excess-LaA Production Directly from Biomass by Trivalent Yttrium Species, iScience, 2019, 12, 132–140.

21. P. Zhao, C. Zhou, J. Li*, S. Xu, and C. Hu*, Synergistic Effect of Different Species in Stannic Chloride Solution on the Production of Levulinic Acid from Biomass, ACS Sustainable Chem. Eng. 2019, 7, 5176−5183.

22. Z. Jiang, P. Zhao, J. Li*, X. Liu, and C. Hu*, Effect of Tetrahydrofuran on the Solubilization and Depolymerization of Cellulose in a Biphasic System, ChemSusChem, 2018, 11, 397−405.

23. H. Zhang, X. Liu, J. Li*, Z. Jiang, C. Hu*, Performances of Several Solvents on the Cleavage of Inter and Intramolecular Linkages of Lignin in Corncob Residue, ChemSusChem, 2018, 11, 1494 –1504.

24. S. Xu, K. Lan, J. Li*, T. He, C. Hu*, Separation of lactic acid from synthetic solutions and the mixture directly derived from corn stover by aqueous two phase extraction, Separation and Purification Technology, 2018, 204, 281–289.

25. X. Li, J. Li*, X. Liu, Q. Tian and C. Hu*, The Promoting Effect of Ce on the Performance of Au/CexZr1-xO2 for -Valerolactone Production from Biomass-Based Levulinic Acid and Formic Acid, Catalysts, 2018, 8, 241.

26. T. He, Z. Jiang, P. Wu, J. Yi, J. Li* & C. Hu*, Fractionation for further conversion: from raw corn stover to lactic acid, Scientific Reports, 2016, 6: 38623.

27. J. Yi, Y. Luo, T. He, Z. Jiang, J. Li*, C. Hu*, High Efficient Hydrogenation of Lignin-Derived Monophenols to Cyclohexanols over Pd/γ-Al2O3 under Mild Conditions. Catalysts, 2016, 6, 12.

28. Z. Jiang, J. Yi, J. Li*, T. He and C. Hu*, Promoting Effect of Sodium Chloride on the Solubilization and Depolymerization of Cellulose from Raw Biomass Materials in Water, ChemSusChem, 2015, 8(11), 1901-1907.

29. J. Li, Z. Jiang, L. Hu, C. Hu*, Selective conversion of cellulose in corncob residue to levulinic acid in an aluminum trichloride-sodium chloride system, ChemSusChem, 2014, 79: 2482-2488. 

30. Z. Jiang, T. He, J. Li*, C. Hu*, Selective conversion of lignin in corncob residue to monophenols with high yield and selectivity, Green Chemistry, 2014, 16(9): 4257-4265.

授权、申请专利:

1. 胡常伟,蒋智成,李建梅,胡立斌,罗倚坪,祝良芳,一种由生产木糖的废渣一步催化制备乙酰丙酸的方法,2015.5.20,中国,ZL201310116203.2.

2. 胡常伟,许曙光,李建梅,何婷,肖园,由木糖、葡萄糖、木聚糖、微晶纤维素及玉米秸秆催化转化制备D-构型过量的乳酸的方法,中国,ZL201810868191.1.

3. 胡常伟,许曙光,李建梅,何婷,黄志铭,一种由C3、木糖、葡萄糖和玉米秸秆一步制备D-乳酸的方法,申请日:20190430日,中国,ZL 201910366350.2 授权公告日:2021.7.13

4. 李建梅,杨若枫,许曙光,周翠清,胡常伟,一种由赤藓糖醇、甘露醇、山梨醇催化转化制备羟基乙酸的方法,申请日:2021.5.14,中国,ZL 202110531720.0 授权公告日:20231208日。

5. 李建梅,许曙光,张文瑜,胡常伟,一种由甘油催化转化制备羟基乙酸的方法,申请日:2021.4.26, 中国,授权公告日:20231117日,ZL 202110457991.6

6. 李建梅,杨若枫,周翠清,许曙光,胡常伟,一种由阿拉伯糖醇催化转化制备手性D-甘油酸的方法,申请日:2021.9.07,申请号:ZL 2021 1 1046350.8,中国,授权公告日:20240405

7. 李建梅,肖园,许曙光,胡常伟,一种由浒苔及其衍生物-鼠李糖、葡萄糖、木糖催化转化制备羟基丙酮的方法,申请号:2023106938363 申请日:2023 06 13

8. 李建梅,杨若枫,秦静莹,刘堰城,许曙光,胡常伟,一种由 D-/L-木糖、D-/L-阿拉伯糖、D-/L-核糖催化转化分别制备手性 D-/L-甘油酸的方法, 申请号 2023102978357   申请日:2023 03 24

 

 

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