四川大学化学学院
师资力量

万贤楷     特聘研究员

研究方向:金属团簇化学

联系方式:          Email:xkwan@scu.edu.cn

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学习及工作经历

2021.06—至今    四川大学化学学院,特聘研究员

2018.10—2021.04 名古屋大学 JSPS特别研究员

2017.09—2018.09 南洋理工大学 博士后研究员

2011.09—2017.07 厦门大学化学化工学院 理学博士

2007.09—2011.07 重庆大学化学化工学院 工学学士

主要研究方向

配体保护金属纳米团簇的可控合成、分离与表征

金属纳米团簇的催化(催化有机反应/电催化小分子转化)应用研究

原子精确金属纳米团簇发光性质研究

课题组诚招博士、硕士研究生、研究助理以及联合培养学生,欢迎对团簇化学、材料学、催化、电化学、发光材料、晶体学等感兴趣的学生加入本课题组!

主要工作业绩

主要从事金属纳米团簇精准合成、表征以及发光、催化应用等性质方面的研究。包括创新性的采用直接还原前驱体法和引入炔配体,首次合成并结构测定了系列结构与性质新颖的金属纳米团簇,原子水平揭示界面结构、建立构效关系;首次原子水平揭示团簇催化中的配体效应,多孔限域纳米团簇电催化转化(析氢、氧还原、二氧化碳还原等)丰富了团簇科学,促进团簇实际应用和纳米科学向原子精确水平发展。截至目前已发表学术论文20余篇,以第一作者在Sci. Adv.J. Am. Chem. Soc.Angew. Chem. Int. Ed.Adv. Mater. Dalton. Trans.等杂志发表多篇论文,累积引用超过1500次,其中包括ESI高被引、VIPEditor Choice文章。

主要奖励和荣誉

2021 四川大学双百B人才项目

2019 日本学术振兴会(JSPS)特别研究员

2017 厦门大学优秀毕业生

2015 博士研究生国家奖学金,“卢嘉锡”全国优秀研究生奖

2014 厦门大学“本栋”奖学金(校三大奖)

2012 硕士研究生国家奖学金,厦门大学三好学生

代表性成果 (获奖成果、专著、论文、专利)

1.   Xian-Kai Wan, Gabor Samjeské*, Hirosuke Matsui, Chaoqi Chen, Satoshi Muratsugu, Mizuki Tada*. Ultrafine Pt-Ni Nanoparticles in Hollow Porous Carbon Spheres for Remarkable Oxygen Reduction Reaction Catalysis. Dalton. Trans. 2021, 50, 6811-6822. (back cover)

2.   Xian-Kai Wan,# Hao Bin Wu,# Bu Yuan Guan, Deyan Luan, and Xiong Wen (David) Lou*. Confining Subnanometer Pt Clusters in Hollow Mesoporous Carbon Spheres for Boosting Hydrogen Evolution Activity, Adv. Mater. 2020, 32, e1901349.

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3.  Xian-Kai Wan, Jia-Qi Wang, Zi-Ang Nan and Quan-Ming Wang*. Ligand Effects in Catalysis by Atomically Precise Gold Nanoclusters, Sci. Adv. 2017, 3, e1701823. (ESI 高被引论文)

4.   Xian-Kai Wan, Zong-Jie Guan, and Quan-Ming Wang*. Homoleptic Alkynyl-Protected Gold Nanoclusters: Au44(PhCC)28 and Au36(PhCC)24, Angew. Chem. Int. Ed. 2017, 56, 11494. (VIP文章)

5.   Xian-Kai Wan, Xiao-Ling Cheng, Qing Tang, Ying-Zi Han, Guoxiang Hu,, De-En Jiang*, and Quan-Ming Wang*. Atomically Precise Bimetallic Au19Cu30 Nanocluster with an Icosidodecahedral Cu30 Shell and an Alkynyl–Cu Interface, J. Am. Chem. Soc. 2017, 139, 9451-9454.

6.   Xian-Kai Wan, Wen-Wu Xu, Shang-Fu Yuan, Yi Gao*, Xiao-Cheng Zeng, and Quan-Ming Wang*. Near Infrared Emissive Alkynyl-Protected Au24 Nanocluster, Angew. Chem. Int. Ed. 2015 54, 9683-9686.

7.   Xian-Kai Wan, Shang-Fu Yuan, Qing Tang, De-En Jiang*, and Quan-Ming Wang*. Alkynyl-Protected Au23 Nanocluster: A 12-Electron System, Angew. Chem. Int. Ed. 2015, 54, 5977-5980.

8.  Xian-Kai Wan, Qing Tang, Shang-Fu Yuan, De-En Jiang*, and Quan-Ming Wang*. Au19 Nanocluster Featuring a V‑Shaped Alkynyl−Gold Motif, J. Am. Chem. Soc. 2015, 137, 652−655. (editor choice)

9.  Xian-Kai Wan, Shang-Fu Yuan, Zhi-Wei Lin and Quan-Ming Wang*. Chiral Gold Nanocluster Au20 Protected by Tetradentate Phosphines, Angew. Chem. Int. Ed. 2014, 53, 5923-5926.

10.  Xian-Kai Wan, Zhi-Wei Lin and Quan-Ming Wang*. Au20 Nanocluster Protected by Hemilabile Phosphines, J. Am. Chem. Soc. 2012, 134, 14750.

11.  Shang-Fu Yuan, Heng-Wang Luyang, Zhen Lei, Xian-Kai Wan, Jiao-Jiao Li, Quan-Ming Wang* A stable well-defined copper hydride cluster consolidated with hemilabile phosphines. Chem. Commun. 2021, 57, 4315-4318.

12.  Zhen Lei, Xian-Kai Wan, Shang-Fu Yuan, Zong-Jie Guan, Quan-Ming Wang*. Alkynyl Approach toward the Protection of Metal Nanoclusters, Acc. Chem. Res. 2018, 51, 2465.

13.  Zhen Lei, Jiao-Jiao Li, Xian-Kai Wan, Wen-Han Zhang, Quan-Ming Wang*. Isolation and Total Structure Determination of an All AlkynylProtected Gold Nanocluster Au144. Angew. Chem. Int. Ed. 2018, 57, 8639.

14.  Shang-Fu Yuan, Pei Li, Qing Tang, Xian-Kai Wan, Zi-Ang Nan, De-En Jiang*, and Quan-Ming Wang*. Alkynyl-protected silver nanoclusters featuring an anticuboctahedral kernel. Nanoscale 2017, 9, 11405-11409.

15.  Zhen Lei, Xian-Kai Wan, Shang-Fu Yuan, Jia-Qi Wang and Quan-MingWang*. Alkynyl-Protected Gold and Gold-Silver Nanoclusters, Dalton. Trans. 2017, 46, 3427.

16.  Wang Yu, Xian-Kai Wan, Li-Ting Ren, Hai-Feng Su, Gang Li, Sami Malola, Shui-Chao Lin, Zi-Chao Tang, Hannu Häkkinen, Boon K Teo, Quan-Ming Wang*, Nan-Feng Zheng*. Atomically Precise Alkynyl-Protected Metal Nanoclusters as a Model Catalyst: Observation of Promoting Effect of Surface Ligands on Catalysis by Metal Nanoparticles, J. Am. Chem. Soc. 2016, 138, 3278-3281.

17.  Zong-Jie Guan, Jiu-Lian Zeng, Zi-Ang Nan, Xian-Kai Wan, Yu-Mei Lin*, Quan-Ming Wang*. Thiacalix[4]arene: New protection for metal nanoclusters, Sci. Adv. 2016, 2, e1600323.

18.  Zhen Lei, Zong-Jie Guan, Xiao-Li Pei, Shang-Fu Yuan, Xian-Kai Wan, Jin-Yuan Zhang, Quan-Ming Wang*. An Atomically Precise Au10Ag2 Nanocluster with Red–Near-IR Dual Emissio, Chem. Eur. J. 2016, 22, 11156-11160.

19.  Stefan Knoppe*, Qian-Fan Zhang, Xian-Kai Wan, Quan-Ming Wang, Lai-Sheng Wang, Thierry Verbiest. Second-Order Nonlinear Optical Scattering Properties of Phosphine-Protected Au20 Clusters, Ind. Eng. Chem. Res. 2016, 55, 10500-10506.

20.  Xiao-Li Pei, Yang Yang, Zhen Lei, Shan-Shan Chang, Zong-Jie Guan, Xian-Kai Wan, Ting-Bin Wen, and Quan-Ming Wang*. Highly Active Gold(I)-Silver(I) Oxo Cluster Activating sp3 C-H Bonds of Methyl Ketones under Mild Conditions, J. Am. Chem. Soc. 2015, 137, 5520-5525.

21.  Meng Zhou, Sa-Ran Long, Xian-kai Wan, Yang Li, Ying-li Niu, Qian-Jin Guo, Quan-Ming Wang*, An-Dong Xia*. Ultrafast relaxation dynamics of phosphine-protected, rod-shaped Au20 clusters: interplay between solvation and surface trapping, Phys. Chem. Chem. Phys. 2014, 16, 18288-18293.

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