四川大学化学学院
师资力量

余达刚     教授、博士生导师

研究方向:绿色有机合成化学(二氧化碳利用、可见光催化);过渡金属催化方法学(铜、铁等廉价金属催化)

联系方式:028-85470816          Email:yudagang86@163.com;dgyu@scu.edu.cn

个人主页:点击进入

简历:

余达刚博士,男,19869月出生于江西奉新。

学习经历

2003.09—2007.07 四川大学化学学院读本科,导师:冯小明教授,袁立华教授

2007.09—2012.07北京大学化学与分子工程学院有机化学专业攻读博士学位,导师:施章杰教授

工作经历

2012.10—2014.12  德国明斯特大学进行博士后研究,洪堡学者,导师:Prof. Frank Glorius

2015.01至今     四川大学化学学院从事教学和科研,教授, 博士生导师

学术兼职

Chemical Synthesis副主编

《化学学报》、Asian J. Org. Chem编委

《中国化学快报》高级编委

《中国科学-化学》、《有机化学》、《催化学报》青年编委

主要研究方向

绿色有机合成化学(二氧化碳利用、可见光催化)

过渡金属催化方法学(铜、铁等廉价金属催化)

功能分子构建新方法研究(重要杂环、羧酸合成)

诚招副研究员、博后、研究助理、硕博生以及交流生

主要工作业绩

二氧化碳(CO2)作为空气中的重要组分,也是广泛存在、廉价易得、无毒、稳定、可再生循环使用的碳一C1)资源。由于CO2在热力学和动力学方面有较高的稳定性,反应活性较低,CO2活化具有巨大的挑战。2015年余达刚博士独立建组以来,坚持围绕CO2活化与转化的基本科学问题开展独特研究,发展了CO2高效活化与选择性转化的新理念、新策略和新反应,具体如下:

针对碳氢键氧化羰基化反应中存在的问题(需要使用剧毒的CO和当量的氧化剂),我们首次提出“CO2 = CO + [O]”理念,利用CO2代替CO和氧化剂参与碳氢键羰基化反应,发展了近十类重要含羰基杂环类化合物的高效合成方法,提出了新反应机制,不仅变废为宝,还降低成本,提高安全性,具有较强的实用性;基于过渡金属催化和可见光催化策略,我们发展了自由基型CO2转化模式,一方面通过调控自由基参与不饱和烃转化反应的选择性,在室温常压下实现了噁唑啉酮和多种类型羧酸的高效制备,另一方面基于可见光促进单电子活化策略,通过单电子还原CO2或底物形成自由基负离子,实现了具有独特区域选择性的烯烃羧基化反应;基于极性翻转策略,我们通过惰性化学键(如碳氟键和碳氮键)的选择性断裂实现了CO2参与的羧基化反应;此外,我们实现了铜催化CO2参与的芳基烯烃和1,3-二烯的不对称还原羟甲基化反应,取得了优秀的对映选择性、化学选择性、区域选择性和Z/E选择性,高效构建了具有手性(季碳)中心的高苄醇和高烯丙醇。这些工作实现了CO2的变废为宝和高附加值产品的精准合成,为研究CO2活化的本质和规律提供了新的实验基础和理论模型,为促进我国CO2化学研究起了积极的作用。

独立工作以来,余达刚博士以通讯作者身份在Nature Catal.Acc. Chem. Res.CCS Chem.J. Am. Chem. Soc.Angew. Chem. Int. Ed.Nature Commun.,《中国科学:化学》和《中国化学》等学术刊物上发表学术论文50余篇,其中有多篇论文成为相应期刊封面、扉页文章、VIP和当月下载量前列的文章,多篇被ChemistryViewsSynfactsOrganic Chemistry PortalOPR&D和《有机化学》等作为亮点介绍。此外,在国内外学术会议、大学和企业做了60余次报告,其中包括2018国际配位化学会议二氧化碳化学专场上主题报告。此外,他还作为共同客座编辑组织《中国化学》、Green Chemistry 和《催化学报》的“二氧化碳化学”专辑。  

主要奖励和荣誉  

2020Science China Chemistry Emerging Investigator

2020Chemical Communications Emerging Investigator

2020 四川大学“中青年科技领军人才培育计划

2019年四川大学优秀本科毕业论文指导教师

2019年四川大学拔尖创新人才培养优秀指导教师

2019年四川大学大学生创新创业教育优秀指导教师

2019年四大学课堂教学质量优秀奖

2018年中国化学会青年化学奖

2018年国家自然科学基金委优秀青年基金

2018年霍英东青年教师基金

2018年四川大学优秀教师

2018年四川大学优秀青年科技人才奖

2017 ACP Lectureship Awards to Japan

2017 Thieme Chemistry Journal Award

2017年四川大学优秀本科毕业论文指导教师

2017年四川大学拔尖创新人才优秀指导教师

2017年四川大学大学生创新创业教育优秀指导教师

2016年四川大学青年科技人才奖

2016年四川大学优秀本科毕业论文指导教师

2014年海外高层次人才引进计划青年项目

2013-2014年德国洪堡奖学金

2013Reaxys PhD Prize (Finalist)

2012年陶氏化学可持续发展创新奖(特等奖)

2012年北京大学“学术十杰”

2012年北京大学化学与分子工程学院优秀博士论文

2011SciFinder Recognition in Excellence Program for OMCOS16

2011年北京大学化学与分子工程学院“化学之星”二等奖

2010年北京大学“三好学生”           

2010年北京大学“常青特等奖学金”    

2009年北京大学“常青一等奖学金”      

学术报告

1.        ChemComm 新锐科学家系列报告会,线上报告,2021429

2.        中国化学会第32届学术年会,珠海,2021421

3.        中国化学会2021电催化与电合成国际研讨会,福州,2021410

4.        厦大百年校庆系列学术论坛--有机化学前沿研讨会,厦门大学,202147

5.        合成化学青年学者研讨会,清华大学,20201223

6.        15th Syngenta International Conference,线上报告,20201021

7.        华东师范大学绿色化学导向的新药创制研究生学术论坛,线上报告,2020929

8.        2020兰州有机化学高峰论坛,兰州,2020817

9.        2019年第二届国际有机光化学合成论坛,南昌,20191123

10.     江西师范大学化学学院,南昌,20191122

11.     第一届全国二氧化碳资源化会议,天津,20191110

12.     清华大学化学系, 北京, 20191031

13.     1st International Green and Sustainable Chemistry Conference,北京,20191018

14.     中国化学会第十六届均相催化学术会议,武汉,2019927

15.     中国化学会第十一届全国有机化学学术会议,上海,201992

16.     德国雷根斯堡大学,20190704

17.     德国海德堡大学,20190702

18.     德国明斯特大学,20190701

19.     德国哥廷根大学,20190628

20.     The 17th International Conference on Carbon Dioxide Utilization,德国亚琛,20190626

21.     德国亚琛工业大学,20190625

22.     第十五届中美化学教授会议,新乡,20190618

23.     四川大学博士后交叉学科论坛,成都,2019426号。

24.     International Symposium on Radical Chemistry, 福建物构所,福州,2019416号。

25.     第二届全国有机自由基化学会议,南方科技大学,深圳,2019413号。

26.     华中师范大学有机光化学合成论坛,武汉,20181127号。

27.     第二十届全国金属有机化学学术讨论会,南京,2018113号。

28.     第一届全国光功能材料青年学者研讨会会议,昆明,2018916号。

29.     The 43rd International Conference on Coordination Chemistry (ICCC),日本仙台,201884号。

30.     北海道大学,日本札幌,2018730号。

31.     东京工业大学,日本东京,2018727号。

32.     RIKEN,日本东京,2018726号。

33.     京都大学,日本京都,2018724号。

34.     大阪大学,日本大阪,2018723号。

35.     第三届齐鲁有机论坛,山东大学,济南,2018615号。

36.     中国化学会第31届学术年会,杭州,201856号。

37.     华中师范大学,武汉,2018424号。

38.     南开大学,天津,2018411号。

39.     第十届全国有机化学学术会议,深圳,20171217号。

40.     空气中关键组分的活化及利用研讨会,新昌,2017129号。

41.     The 12th International Conference on Cutting-Edge Organic Chemistry in Asia (ICCEOCA-12),西安,2017114号。

42.     第十二届全国物理有机化学学术会议,武汉,20171017号。

43.     International Symposium on Organic Chemistry in Western China, Chengdu, 10/08/2017

44.     第十五届全国均相催化学术讨论会,杭州,2017927号。

45.     第十五届全国光化学学术讨论会,兰州,2017823号。

46.     19th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS19), 韩国济州,2017627号。

47.     教育部春晖计划德国专家工作团西南石油大学交流研讨会, 2017417号。

48.     江西同和药业公司,奉新,2017124号。

49.     四川师范大学双一流系列学术报告,成都,20161216号。

50.     Tateshina Conference on Organic Chemistry 2016, Tateshina, 20161110号。

51.     第十九届全国金属有机化学学术讨论会,杭州,20161030号。

52.     2016年纳米催化和清洁合成学术研讨会,苏州,20161029号。

53.     2016 International Symposium on C-O Activation, Himeji, 20161027号。

54.     The 12th International Symposium on Organic Free Radicals,上海,2016911号。

55.     2016西部有机化学论坛,成都,201685号。

56.     中国化学会第30届学术年会,大连,201672号。

57.     12届中美化学华人教授会议,广州,2016625日。

58.     中国化学会第九届全国有机化学学术会议,长春,2015729日。

59.     11届中美化学华人教授会议,苏州,2015623日。

60.     中国工程物理研究院材料所,江油,2015424日。

61.     第七届中德华人教授论坛,明斯特,德国,2015418号。

62.     2014 Reaxys Inspiring Chemistry Conference, Grindelwald,瑞士,2014922号。

63.     2nd International Symposium on C-H ActivationRennes法国,201472号。

64.     留德华人化学化工学会北威州分会(GCCCD-NRW)第7 届学术年会,波鸿,德国,2014517号。

65.     中国化学会留德华人化学化工学会(GCCCD)第25 届学术年会,杜伊斯堡,德国,201397号。

66.     第四届“CCME-IOC & ICCAS-LMRF”Alfa Aesar 研究生学术研讨会,2011218

代表性成果 (获奖成果、专著、论文、专利)

1.   J.-H. Ye, T. Ju, H. Huang, L.-L. Liao, D.-G. Yu*, Radical Carboxylative Cyclizations and Carboxylations with CO2. Acc. Chem. Res. 2021, DOI:10.1021/acs.accounts.1c00135 (Cover).

2.    T. Ju, Y.-Q. Zhou, K.-G. Cao, Q. Fu, J.-H. Ye, G.-Q. Sun, X.-F. Liu, L. Chen, L.-L. Liao, D.-G. Yu*, Dicarboxylation of alkenes, allenes, and (hetero)arenes with CO2 via visible-light photoredox catalysis. Nat. Catal. 2021, 4, 304–311.

3.    G.-M. Cao, X.-L. Hu, L.-L. Liao, S.-S. Yan, L. Song, J. J. Chruma, L. Gong, D.-G. Yu*, Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2. Nat. Commun. 2021, DOI : 10.1038/s41467-021-23447-8.


4.    Y.-N. Niu, X.-H. Jin, L.-L. Liao, H. Huang, B. Yu, Y.-M. Yu*, D.-G. Yu*, Visible-Light-Driven External-Photocatalyst-Free Alkylative Carboxylation of Alkenes with CO2. Sci. China Chem. 2021, https://doi.org/10.1007/s11426-021-1004-y.

5.    X.-W. Chen, J.-P. Yue, K. Wang, Y.-Y. Gui, Y.-N. Niu, J. Liu, C.-K. Ran, W. Kong,* W.-J. Zhou, D.-G. Yu*, Nickel-Catalyzed Asymmetric Reductive Carbo-Carboxylation of Alkenes with CO2. Angew. Chem. Int. Ed. 2021, DOI: 10.1002/anie.202102769. (Highlighted by WielyChem, X-Mol, CBG).

6.    L.-L. Liao, G.-M. Cao, Y.-X. Jiang, X.-H. Jin, X.-L. Hu, J. J. Chruma, G.-Q. Sun, Y.-Y. Gui, D.-G. Yu*, α-Amino Acids and Peptides as Bifunctional Reagents: Carbo-Carboxylation of Activated Alkenes via Recycling CO2. J. Am. Chem. Soc. 2021, 143, 2812 (One of the most read JACS papers in March, 2021. Highlighted by Synfacts, Chin. J. Org. Chem., CBG, X-Mol and WeeChem)

7.    Y.-M. Jiang, J. Liu, Q. Fu,* Y.-M. Yu,* D.-G. Yu*, Visible-Light-Driven Phosphonoalkylation of Alkenes. Synlett 2021, 32, 378 (Equal contribution. Invited contribution for "Radicals by Young Chinese Organic Chemists")

8.    C.-K. Ran, L. Song, Y.-N. Niu, M.-K. Wei, Z. Zhang,* X.-Y. Zhou, D.-G. Yu*, Transition-metal-free synthesis of thiazolidin-2-ones and 1,3-thiazinan-2-ones from arylamines, elemental sulfur and CO2. Green Chem. 2021, 23, 274 (Invited for Special Issue: CO2 Utilization. Highlighted by Chem-station and RSC China)

9.    Y.-X. Jiang, L. Chen, C.-K. Ran, L. Song, W. Zhang,* L.-L. Liao, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Ring-Opening Carboxylation of Cyclic Oxime Esters with CO2. ChemSusChem 2020, 13, 6312. (Invited for Special Issue: Green Carbon Science-CO2 Capture and Conversion)

10.   Z. Zhang, J.-H. Ye, T. Ju, L.-L. Liao, H. Huang, Y.-Y. Gui, W.-J. Zhou,* D.-G. Yu*, Visible Light-Driven Catalytic Reductive Carboxylation with CO2. ACS Catal. 2020, 10, 10871. (Equal contribution. Perspective)

11.   L. Song, D.-M. Fu, L. Chen, Y.-X. Jiang, J.-H. Ye, L. Zhu, Y. Lan,* Q. Fu, D.-G. Yu*, Visible-Light Photoredox-Catalyzed Remote Difunctionalizing Carboxylation of Unactivated Alkenes with CO2. Angew. Chem. Int. Ed. 2020, 59, 21121. (Hot Paper. Highlighted by Synfacts 2020, 16, 1372; Chin. J. Org. Chem2020, 40, 4375; WielyChem).

12.   H. Huang, J.-H. Ye, L. Zhu, C.-K. Ran, M. Miao, W. Wang, H. Chen, W.-J. Zhou, Y. Lan,* B. Yu, D.-G. Yu*, Visible Light-Driven Anti-Markovnikov Hydrocarboxylation of Acrylates and Styrenes with CO2. CCS Chem. 2020, 2, 1746  (Equal contribution.)

13.   W.-J. Zhou,* X.-D. Wu, M. Miao, Z.-H. Wang, L. Chen, S.-Y. Shan, G.-M. Cao, D.-G. Yu*,  Light Runs Across Iron Catalysts in Organic Transformations. Chem. Eur. J. 2020, 26, 15052. (Equal contribution. Invited Concept)

14.   W.-J. Zhou, Z.-H. Wang, L.-L. Liao, Y.-X. Jiang, K.-G. Cao, T. Ju, Y. Li, G.-M. Cao, D.-G. Yu*, Reductive Dearomative Arylcarboxylation of Indoles with CO2 via Visible-Light Photoredox Catalysis. Nat. Commun. 2020, 11, 3263. (Equal contribution)

15.   C.-K. Ran, X.-W. Chen, Y.-Y. Gui*, J. Liu, L. Song, K. Ren, D.-G. Yu*, Recent Advances in Asymmetric Synthesis with CO2. Sci. China Chem. 2020, 63, 1336. (Equal contribution. Sci. China Chem. Emerging Investigators themed collection)

16.   周文俊*,蒋元旭,陈亮,刘开兴,余达刚*可见光与钯协同催化的有机合成化学。有机化学202040, 3697应邀综述.Equal contribution

17.   L. Song, Y.-X. Jiang, Z. Zhang,* Y.-Y. Gui, X.-Y. Zhou, D.-G. Yu*, CO2 = CO + [O]: recent advances in carbonylation of C–H bonds with CO2. Chem. Commun. 2020, 56, 8355 (ChemComm Emerging Investigators themed collection)

18.   Z. Zhang,* X.-Y. Zhou, J.-G. Wu, L. Song, D.-G. Yu*, Transition-Metal-Free Lactamization of C(sp3)—H Bonds with CO2: Facile Generation of Pyrido[1,2-a]pyrimidin-4-ones. Green Chem. 2020, 22, 28. (Equal contribution)

19.   C.-K. Ran, H. Huang, X.-H. Li, W. Wang, J.-H. Ye, S.-S. Yan, B.-Q. Wang, C. Feng,* D.-G. Yu*, Cu-Catalyzed Selective Oxy-Cyanoalkylation of Allylamines with Cycloketone Oxime Esters and CO2. Chin. J. Chem. 2020, 38, 69 (Invited paper)

20.   X.-W. Chen, L. Zhu, Y.-Y. Gui, K. Jing, Y.-X. Jiang, Z.-Y. Bo, Y. Lan,* J. Li, D.-G. Yu*, Highly Selective and Catalytic Generation of Acyclic Quaternary Carbon Stereocenters via Functionalization of 1,3-Dienes with CO2. J. Am. Chem. Soc. 2019, 141, 18825. (Highlighted by ChemBeanGo and Chin. J. Org. Chem. 2020, 40, 247)

说明: E:\课题组网页 宣传栏\TOC\19 JACS.gif

21.   M. Miao, L.-L. Liao, G.-M. Cao, W.-J. Zhou,* D.-G. Yu*, Visible-light-mediated external-reductant-free reductive cross coupling of benzylammonium salts with (hetero)aryl nitriles. Sci. China Chem. 2019, 62, 1519. (Invited Contribution to SPECIAL ISSUE: Organic Free Radical Chemistry)

说明: E:\课题组网页 宣传栏\TOC\19 SCC MM.png

22.   Z. Zhang, L. Gong, X.-Y. Zhou, S.-S. Yan, J. Li*, D.-G. Yu*, Radical-Type Difunctionalization of Alkenes with CO2. Acta Chim. Sinica 2019, 77, 783 (Invited Contribution to SPECIAL ISSUE: Organic Radical Chemistry)

说明: E:\课题组网页 宣传栏\TOC\2019 化学学报.jpg

23.   Q. Fu, Z.-Y. Bo, J.-H. Ye, T. Ju, H. Huang, L.-L. Liao, D.-G. Yu*, Transition metal-free phosphonocarboxylation of alkenes with carbon dioxide via visible-light photoredox catalysis. Nat. Commun. 2019, 10, 3592.

说明: E:\课题组网页 宣传栏\TOC\19 NCOMM.jpg

24.   S.-S. Yan, D.-S. Wu, J.-H. Ye, L. Gong, X. Zeng, C.-K. Ran, Y.-Y. Gui, J. Li, D.-G. Yu*, Copper-Catalyzed Carboxylation of CF Bonds with CO2. ACS Catal. 2019, 9, 6987. (Highlighted by Synfacts 2019, 15, 1159)

说明: E:\课题组网页 宣传栏\TOC\19 ACS catalysis.gif

25.   W.-J. Zhou,* G.-M. Cao, Z.-P. Zhang, and D.-G. Yu*, Visible Light-Induced Palladium-Catalysis in Organic Synthesis. Chem. Lett. 2019, 48, 181. (Invited Contribution. Cover)

说明: E:\课题组网页 宣传栏\TOC\19 CL cover.jpg

26.   Y. Chen*, L.-Q. Lu*, D.-G. Yu*, C.-J. Zhu* and W.-J. Xiao*, Visible light-driven organic photochemical synthesis in China. Sci. China Chem. 2019, 62, 24. (Invited Contribution)

说明: E:\课题组网页 宣传栏\TOC\19 SCC photo.png

27.   L.-L. Liao, G.-M. Cao, J.-H. Ye, G.-Q. Sun, W.-J. Zhou, Y.-Y. Gui, S.-S. Yan, G. Shen, D.-G. Yu*, Visible-light-Driven External-Reductant-Free Cross-Electrophile Couplings of Tetraalkyl Ammonium Salts. J. Am. Chem. Soc. 2018, 140, 17338. (Top 1 most read JACS papers in December, 2018.)

 

28.   T. Ju, Q. Fu, J.-H. Ye, Z. Zhang, L.-L. Liao, S.-S. Yan, X.-Y. Tian, S.-P. Luo, J. Li, D.-G. Yu*, Selective and Catalytic Hydrocarboxylation of Enamides and Imines with CO2 to Generate α,α-Disubstituted α-Amino Acids. Angew. Chem. Int. Ed. 2018, 57, 13897.

29.   S.-S. Yan, Q. Fu, L.-L. Liao, G.-Q. Sun, J.-H. Ye, L. Gong, Y.-Z. Bo-Xue, D.-G. Yu*, Transition metal-catalyzed carboxylation of unsaturated substrates with CO2. Coord. Chem. Rev. 2018, 374, 439. (Invited Contribution)

 

30.   W.-J. Zhou,* Yi-Han Zhang, Y.-Y. Gui, L. Sun, D.-G. Yu*, Merging Transition Metal-Catalysis with Photoredox Catalysis: A Environmentally Friendly Strategy for C-H Functionalization. Synthesis 2018, 50, 3359. (Equal contribution. Invited Contribution to the Special Issue on “Photocatalysis”)

31.   L. Song, L. Zhu, Z. Zhang, J.-H. Ye, S.-S. Yan, J.-L. Han, Z.-B. Yin, Y. Lan*, D.-G. Yu*, Catalytic Lactonization of Unactivated Aryl C─H Bonds with CO2: Experimental and Computational Investigation. Org. Lett. 2018, 20, 3776. (Top 14 most read papers in July, 2018)

32.   Z. Zhang,*J.-H. Ye,D.-S. Wu, Y.-Q. Zhou, D.-G. Yu*, Synthesis of Oxazolidin-2-ones from Unsaturated Amines with CO2 via Homogeneous Catalysis. Chem. Asian J. 2018, 13, 2292. (Equal contribution. Invited Contribution to the Special Issue on “Homogeneous Catalysis from Young Investigators in Asia”)

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33.   L. Song, G.-M. Cao, W.-J. Zhou, J.-H. Ye, Z. Zhang, X.-Y. Tian, J. Li, D.-G. Yu*, Pd-catalyzed carbonylation of aryl C─H bonds in benzamides with CO2. Org. Chem. Front. 2018, 5, 2086. (Invited Contribution to the Special Issue on “Celebrating the 90th birthday of Professor Lu Xiyan”)

34.   G. Shen, W.-J. Zhou*, X.-B. Zhang, G.-M. Cao, Z. Zhang, J.-H. Ye, L.-L. Liao, J. Li, D.-G. Yu*, Synthesis of tetronic acids from propargylic alcohols and CO2. Chem. Commun. 2018, 54, 5610.

35.   S.-S. Yan, L. Zhu, J.-H. Ye, Z. Zhang, H. Huang, H. Zeng, C.-J. Li*, Y. Lan*, D.-G. Yu*, Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2. Chem. Sci. 2018, 9, 4873. (Highlighted by CBG.)

36.   L. Sun, J.-H. Ye, W.-J. Zhou*, X. Zeng, D.-G. Yu*, Oxy-Alkylation of Allylamines with Unactivated Alkyl Bromides and CO2 via Visible-Light-Driven Palladium Catalysis. Org. Lett. 2018, 20, 3049. (Top 8 most read papers in May, 2018. Highlighted by CBG.)

37.   Z. Zhang*, C.-J. Zhu, M. Miao, J.-L. Han, T. Ju, L. Song, J.-H. Ye, J. Li, D.-G. Yu*, Lactonization of C(sp2)─H Bonds in Enamides with CO2. Chin. J. Chem. 2018, 36, 430. (Cover. Invited Contribution to the Special Issue on “CO2 chemistry”)

38.   Z.-B. Yin, J.-H. Ye, W.-J. Zhou, Y.-H. Zhang, L. Ding, Y.-Y. Gui, S.-S. Yan, J. Li, D.-G. Yu*, Oxy-Difluoroalkylation of Allylamines with CO2 via Visible-Light Photoredox Catalysis. Org. Lett. 2018, 20, 190. (Equal contribution. ESI高被引论文)

39.   Y.-Y. Gui, Z.-X. Wang, W.-J. Zhou*, L.-L. Liao, L. Song, Z.-B. Yin, J. Li, D.-G. Yu*, Arylation of Aniline C(sp3)─H Bonds with Phenols by an in-situ Activation Strategy. Asian J. Org. Chem. 2018, 7, 537. (Selected as Cover and VIP. Highlighted by ChemistryViews. Invited paper for the Special Issue on Early Career Researchers in China)

40.   L. Zhu, J.-H. Ye, M. Duan, X. Qi, D.-G. Yu*, R. Bai*, Y. Lan*, On the Mechanism of Copper-Catalyzed Oxytrifluoromethylationof Allylamines with CO2: A Computational Study.  Org. Chem. Front. 2018, 5, 633. (ESI高被引论文)

41.   X. Yan, H. Sun, H. Xiang, D.-G. Yu, D. Luo, X. Zhou,* Palladium-Catalyzed C(carbonyl) –C Bond Cleavage of Amides: A Facile Access to Phenylcarbamate Derivatives with Alcohols. Chem. Commun. 2018, 54, 8606.

42.   Y.-Y. Gui, N. Hu, X.-W. Chen, L.-L. Liao, T. Ju, J.-H. Ye, Z. Zhang, J. Li, D.-G. Yu*, Highly Regio- and Enantioselective Copper-Catalyzed Reductive Hydroxymethylation of Styrenes and 1,3-Dienes with CO2. J. Am. Chem. Soc. 2017, 139, 17011. (Equal contribution. Cover. Top 4 most read JACS papers in November, 2017. Highlighted by Synfacts 2018, 14, 0177, CJOC, X-MOL, OPR&D and Organic Chemistry Portal)

43.   J.-H. Ye, M. Miao, H. Huang, S.-S. Yan, Z.-B. Yin, W.-J. Zhou, D.-G. Yu*, Visible light-driven and Iron-promoted Thiocarboxylation of Styrenes and Acrylates with CO2. Angew. Chem. Int. Ed. 2017, 56, 15416. (Top 11 most accessed papers in November, 2017. Highlighted by X-MOL)

44.   W.-J. Zhou, G.-M. Cao, G. Shen, X.-Y. Zhu, Y.-Y. Gui, J.-H. Ye, L. Sun, L.-L. Liao, J. Li, D.-G. Yu*, Visible-Light-Driven Pd-Catalyzed Radical Alkylation of CH Bonds with General Unactivated Alkyl Bromides. Angew. Chem. Int. Ed. 2017, 56, 15683. (Top 2 most accessed papers in November, 2017. Highlighted by X-MOL)

45.   J.-H. Ye, L. Zhu, S.-S. Yan, M. Miao, X.-C. Zhang, W.-J. Zhou, J. Li, Y. Lan*, D.-G. Yu*, Radical Trifluoromethylative Dearomatization of Indoles and Furans with CO2. ACS Catal. 2017, 7, 8324. (Equal contribution. Top 6 most read papers in November, 2017.)

46.   Y.-Y. Gui, X.-W. Chen, W.-J. Zhou*, D.-G. Yu*, Arylation of Amides and Ureas C(sp3)H Bonds with Aryl Tosylates via in situ Generation from Phenols. Synlett 2017, 28, 2581. (Cover. Invited paper for the issue of C-O activation)

47.   L.-L. Liao, Y.-Y. Gui, X.-B. Zhang, G. Shen, H.-D. Liu, W.-J. Zhou, J. Li, D.-G. Yu*, Phosphorylation of Alkenyl and Aryl C─O Bonds via Photoredox/Nickel Dual Catalysis. Org. Lett. 2017, 19, 3735. (Top 2 most read papers in July, 2017)

48.   周文俊*张逸寒曹光梅刘惠东余达刚*钯催化卤代烷烃参与的自由基型转化反应有机化学201737, 1322应邀综述

49.   Y.-Y. Gui, W.-J. Zhou, J.-H. Ye, D.-G. Yu*, Photochemical Carboxylation of Activated C(sp3)─H Bonds with CO2. ChemSusChem 2017, 10, 1337. (Equal contribution. Highlight)

 

50.   Z. Zhang, T. Ju, J.-H. Ye, D.-G. Yu*, CO2 = CO + O: Redox-neutral Lactamization and Lactonization of C─H Bonds with CO2. Synlett 2017, DOI: 10.1055/s-0036-1588403. (Invited Synpacts paper)

51.   Z. Zhang, T. Ju, M. Miao, J.-L. Han, Y.-H. Zhang, X.-Y. Zhu, J.-H. Ye, D.-G. Yu*, Y.-G. Zhi*, Transition-Metal-Free Lactonization of sp2 C─H Bonds with CO2. Org. Lett. 2017. 19, 396. (Equal contribution . Top 3 most read papers in January, 2017)

52.   Y.-Y. Gui, L.-L. Liao, L. Sun, Z. Zhang, J.-H. Ye, G. Shen, Z.-P. Lu, W.-J. Zhou, D.-G. Yu*, Coupling of C(sp3)─H Bonds with C(sp2)─O Electrophiles: Mild, General and Selective. Chem. Comm. 2017, 53, 1192.

53.   J.-H. Ye, L. Song, W.-J. Zhou, T. Ju, Z.-B. Yin, S.-S. Yan, Z. Zhang, J. Li, D.-G. Yu*, Selective Oxytrifluoromethylation of Allylamines with CO2. Angew. Chem. Int. Ed. 2016, 55, 10022. (Top 4 most read ACIE papers in July, 2016)

54.   Z. Zhang, L.-L. Liao, S.-S. Yan, L. Wang, Y.-Q. He, J.-H. Ye, J. Li, Y.-G. Zhi, D.-G. Yu*, Lactamization of sp2 C─H Bonds with CO2: Transition-metal-free and Redox-neutral. Angew. Chem. Int. Ed. 2016, 55, 7068. (扉页文章Highlighted by SynfactsX-MOL以及《有机化学》亮点介绍)

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55.   Y.-Y. Gui, L. Sun, Z.-P. Lu, D.-G. Yu*, Photoredox sheds new light on nickel catalysis: from carbon-carbon to carbon-heteroatom bond formation. Org. Chem. Front. 2016, 3, 522. (From themed collection 2015 Emerging Investigators by OCF)

56.   X. Wang, D.-G. Yu, F. Glorius*, Cp*Rh(III)-Catalyzed Arylation of sp3 C−H Bonds. Angew. Chem. Int. Ed. 2015, 54, 10280. (Equal contribution)

57.   D.-G. Yu, T. Gensch, F. de Azambuja, S. Vásquez-Céspedes, F. Glorius*, Co(III)-Catalyzed C–H Activation/Formal SN-type Reactions: Selective and Efficient Cyanation, Halogenation, and Allylation. J. Am. Chem. Soc. 2014, 136, 17722. (Top 3 most read JACS papers in December, 2014).

58.   D.-G. Yu, F. de Azambuja, T. Gensch, C. G. Daniliuc, F. Glorius*, The C–H Activation/1,3-Diyne Strategy: Highly Selective Direct Synthesis of Diverse Bisheterocycles by RhIII-Catalysis. Angew. Chem. Int. Ed. 2014, 53, 9650. (Highlighted by Synfacts 2014, 10, 1023)

59.   D.-G. Yu, F. de Azambuja, F. Glorius*, Direct Functionalization with Complete and Switchable Positional Control: Free Phenol as A Role Model. Angew. Chem. Int. Ed. 2014, 53, 7710. (Highlight)

60.   D.-G. Yu, F. de Azambuja, F. Glorius*, α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed CH Activation for the Synthesis of N-Heterocycles. Angew. Chem. Int. Ed. 2014, 53, 2754. (Top 6 most accessed ACIE paper in Feb. 2014, Highlighted by Synfacts 2014, 10, 567.)

61.   D.-G. Yu, S. Luo, F. Zhao, Z.-J. Shi*, Homogeneous Transition-Metal-Catalzyed CO Bond Activation. In Homogeneous Catalysis for Unreactive Bond Activation, Chapter 5, Pages 347439, 2014 (Wiley book).

62.   D.-G. Yu, M. Suri, F. Glorius*, RhIII/CuII-Cocatalyzed Synthesis of 1H-Indazoles through C−H Amidation and N−N Bond Formation. J. Am. Chem. Soc. 2013, 135, 8802. (equal contribution, most read JACS papers in June, 2013)

63.   Z.-J. Shi*, D.-G. Yu, Cross-Coupling Reactions. In Comprehensive Inorganic Chemistry II (Second Edition), Volume 6, Pages 47–77 (2013).

64.   D.-G. Yu, X. Wang, R.-Y. Zhu, S. Luo, X.-B. Zhang, B.-Q. Wang, L. Wang, Z.-J. Shi*, Direct Arylation/Alkylation/Magnesiation of Benzyl Alcohols in the Presence of Grignard Reagents via Ni, Fe or Co-Catalyzed sp3 CO Bond Activation. J. Am. Chem. Soc. 2012, 134, 14638. (Highlighted by Synfacts 2012, 8, 1358)

65.   D.-G. Yu, Z.-J. Shi*, Mutual Activation: Suzuki–Miyaura Coupling through Direct Cleavage of sp2 CO Bond of Naphtholate. Angew. Chem. Int. Ed. 2011, 50, 7097. (Highlighted by Synfacts 2011, 10, 1111)

66.   D.-G. Yu, B.-J. Li, S. F. Zheng, B.-T. Guan, B.-Q. Wang, Z.-J. Shi*, Direct Application of Phenolic Salts in Nickel-Catalyzed Cross-Coupling with Aryl Grignard Reagents. Angew. Chem. Int. Ed. 2010, 49, 4566. (Hot paper, the frontpieces of Communications, highlighted by ChemistryViews, Synfacts 2010, 9, 1051以及《有机化学》亮点介绍)

67.   D.-G. Yu, B.-J. Li, Z.-J. Shi*, Exploration of new CO electrophiles in cross-coupling reactions. Acc. Chem. Res. 2010, 43, 1486. (Invited account. Top ten most-accessed articles of Acc. Chem. Res. in 2010)

68.   C.-L. Sun, H. Li, D.-G. Yu, M. Yu, X. Zhou, X.-Y. Lu, K. Huang, S.-F. Zheng, B.-J. Li, Z.-J. Shi*, An efficient organocatalytic method for constructing biaryls through aromatic CH activation. Nature Chem. 2010, 2, 1044. (C.-L. Sun, H. Li, and D.-G. Yu performed the experiments and analysed the data and contributed equally to this work, highlighted by Nature Chem., Nature China and Synform)

69.   S. Luo, D.-G. Yu, R.-Y. Zhu, X. Wang, L. Wang, Z.-J. Shi*, Fe-promoted cross coupling of homobenzylic methyl ethers with Grignard reagents via sp3 C–O bond cleavage. Chem. Comm. 2013. 49, 7794. (equal contribution)

70.   D.-G. Yu, M. Yu, B.-T. Guan, B.-J. Li, Y. Zheng, Z.-H. Wu, Z.-J. Shi*, CarbonCarbon Formation via Ni-Catalyzed Suzuki-Miyaura Coupling through CCN Bond Cleavage of Aryl Nitrile. Org. Lett. 2009, 11, 3374. (Highlighted by Synfacts 2009, 11, 1255)

71.   施章杰* 余达刚,合成化学中的焊接技术。科技导报2010 28 29。(综述)

72.   D.-G. Yu, B.-J. Li, Z.-J. Shi*, Challenges in C-C Bond Formation through Direct Transformations of sp2 CH Bonds. Tetrahedron 2012, 68, 5130. (Invited account in special issue for Tetrahedron Young Investigator Award 2012 Advances in Metal-Mediated Organic Synthesis Zhang-Jie Shi. Cover. Top 3 hottest paper in 2012)

73.   Z.-C. Cao, D.-G. Yu, R.-Y. Zhu, J.-B. Wei, Z.-J. Shi*, Direct Cross Coupling of Benzyl Alcohols to Construct Diarylmethanes via Palladium Catalysis. Chem. Comm. 2015, 51, 2683.

Graphical abstract: Direct cross-coupling of benzyl alcohols to construct diarylmethanes via palladium catalysis

74.   F. Zhao, D.-G. Yu, R.-Y. Zhu, Z.-F. Xi*, Z.-J. Shi*, Cross-Coupling of Aryl/Alkenyl Silyl Ether with Grignard Reagents through Nickel-Catalyzed CO Bonds Activation. Chem. Lett. 2011, 40, 1001. (Invited research paper in Celebration for the 2010 Nobel Prize in Chemistry)

75.   B.-J. Li, D.-G. Yu, C.-L. Sun, Z.-J. Shi*, Activation of “Inert” Alkenyl/Aryl CO Bond and its Application in Cross-Coupling Reactions. Chem. Eur. J. 2011, 17, 1728. (Review)

76.   K. Huang, D.-G. Yu, S.-F. Zheng, Z.-H. Wu, L. Xu, B.-Q. Wang, Z.-J. Shi*, Direct Borylation of Aryl and Vinyl Carbamates via Ni-Catalyzed CO Activation. Chem. Eur. J. 2010, 17, 786.

77.   H. Wang, B. Beiring, D.-G. Yu, K. Collins, F. Glorius, [3]Dendralene Synthesis: Rhodium(III)-Catalyzed Alkenyl C–H Activation and Coupling Reaction with Allenyl Carbinol Carbonate, Angew. Chem. Int. Ed. 2013, 52, 12430.

78.   F. Zhao, Y.-F. Zhang, J. Wen, D.-G. Yu, J.-B. Wei, Z.-F. Xi*, Z.-J. Shi*, Programmed Selective sp2 C–O Bond Activation toward Multiarylated Benzenes. Org. Lett. 2013, 15, 3230.

79.   K. Huang, G. Li, W.-P. Huang, D.-G. Yu, Z.-J. Shi*, Arylation of α-pivaloxyl Ketones with Arylboronic Reagents via Ni-catalyzed sp3 CO Activation. Chem. Commun. 2011, 47, 7224.

80.   H. Li, C.-L. Sun, M. Yu, D.-G. Yu, B.-J. Li, Z.-J. Shi*, The Catalytic Ability of Various Transition Metals in the Direct Functionalization of Aromatic C–H Bonds. Chem. Eur. J. 2011, 17, 3593.

81.   C.-L. Sun, N. Liu, B.-J. Li, D.-G. Yu, Y. Wang, Z.-J. Shi*, Pd-Catalyzed C-H Functionalizations of O-Methyl Oximes with Arylboronic Acids. Org. Lett. 2010, 12, 184.

82.   B.-T. Guan, X.-Y. Lu, Y. Zheng, D.-G. Yu, T. Wu, K.-L. Li, B.-J. Li, Z.-J. Shi*, Biaryl Construction through Kumada Coupling with Diaryl Sulfates as One-by-One Electrophiles under Mild Conditions. Org. Lett. 2010, 12, 396. (Highlighted by Synfacts 2010, 4, 0455)

83.   B.-T. Guan, Y. Wang, B.-J. Li, D.-G. Yu, Z.-J. Shi*, Biaryl Construction via Ni-Catalyzed CO Activation of Aryl Carboxylates. J. Am. Chem. Soc. 2008, 130, 14468. (Highlighted by Angew. Chem. Int. Ed2009, 48, 3569)

 

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