四川大学化学学院
师资力量

兰静波     教 授(博导)

研究方向:有机化学

联系方式:028-85418887          Email:jingbolan@scu.edu.cn;jingbolan@163.com

个人主页:点击进入

  历:   

1999.09-2004.06,四川大学化学学院有机化学专业,研究生/理学博士

2006.07-2011.07,四川大学化学学院,副教授

2011.07——至今,四川大学化学学院,教授

主要研究方向:

1、高选择性有机合成

2、有机光电材料的设计合成、性能及应用研究

3、有机功能分子的超分子识别及生物应用研究

主要工作业绩:   

近年来主持国家自然科学基金面上项目5项、青年基金1项、四川省科技厅人才项目1项,承担国家重点研发计划重点专项子课题1项,经费累计500余万元。2012年入选四川省杰出青年学术和技术带头人资助计划。在国内外学术刊物上以第一作者及通讯作者发表SCI论文50余篇。申请专利25项,授权15项。参与编写专著2部、教材2本。

主持科研项目   

1、国家自然科学基金:激发态分子内质子转移型有机共轭分子的反卡莎发光行为与应用研究(22071162)2021.01~2024.12(主持)

2、国家自然科学基金:π-共轭稠环骨架的高效构筑及超分子识别、自组装与光电性能研究(21871193)2019.01~2022.12(主持)

代表性研究成果:

1)    Yuanyuan Luo,† Zheng Liu,† Ge Yang, Tianhong Wang, Zhengyang Bin, Jingbo Lan,* Di Wu, Jingsong You.* Ir(III)-Catalyzed Diarylation/Annulation of Benzoic Acids: Facile Access to Multi-Aryl Spirobifluorenes as Pure Hydrocarbon Hosts for High-Performance OLEDs. Angew. Chem. Int. Ed. 2021, DOI: 10.1002/anie.202106315.

2)    Quan Huang, Qiang Guo, Jingbo Lan,* Rongchuan Su, You Ran, Yudong Yang, Zhengyang Bin, Jingsong You.* Mechanically induced single-molecule white-light emission of excited-state intramolecular proton transfer (ESIPT) materials. Mater. Horiz. 2021, 8, 1499–1508.

图表描述已自动生成

3)    Quan Huang, Qiang Guo, Jingbo Lan,* Jingsong You.* Tuning the dual emission of keto/enol forms of excited-state intramolecular proton transfer (ESIPT) emitters via intramolecular charge transfer (ICT). Dyes Pigments 2021, 193, 109497.

图表, 散点图描述已自动生成

4)    Lipeng Yan, Weixin Ma, Jingbo Lan,* Hu Cheng, Zhengyang Bin, Di Wu, Jingsong You.* Molecular engineering enabling reversible transformation between helical and planar conformations by cyclization of alkynes. Chem. Sci. 2021, 12, 2419–2426.

5)    Zhishuo Wang, Linfeng Jiang, Jinwen Ji, Fulin Zhou, Jingbo Lan,* Jingsong You.* Build-up of cationic azahelicenes via regioselective three-component annulation using in situ activation strategy. Angew. Chem. Int. Ed. 2020, 59, 23532–23536.

6)    Lipeng Yan, Jingbo Lan,* Hu Cheng, Yihang Li, Mangang Zhang, Di Wu, Jingsong You. * Regioselective addition/annulation of ferrocenyl thioamides with 1,3-diynes via a sulfur-transfer rearrangement to construct extended pconjugated ferrocenes with luminescent properties. Chem. Sci. 2020, 11, 11030–11036.

7)    Anping Luo, Min Zhang, Zhangyi Fu, Jingbo Lan,* Di Wu and Jingsong You.* Copper-catalyzed remote C–H arylation of polycyclic aromatic hydrocarbons (PAHs). Beilstein J. Org. Chem. 2020, 16, 530–536.

8)    Menglei Wang, Min Zhang, Yuanyuan Luo, Zheng Liu, Chengyong Yang, Jingbo Lan,* Di Wu, and Jingsong You.* Pd(II)-catalyzed regioselective multiple C−H arylations of 1‑naphthamides with cyclic diaryliodonium salts: one-step access to [4]- and [5]carbohelicenes. Org. Lett. 2020, 22, 135−139.

9)  Jian Li, Junjie Liu, Jiangliang Yin, Yuming Zhang, Weiguo Han, Jingbo Lan,* Di Wu, Zhengyang Bin, Jingsong You.* Double ortho-C−H activation/annulation of benzamides with aryl alkynes: A route to double-helical polycyclic heteroaromatics. J. Org. Chem. 2019, 84, 15697−15705.

10)   Shiping Yang, Rui Cheng, Tingxing Zhao, Anping Luo, Jingbo Lan,* and Jingsong You.* Rhodium-catalyzed C−H/C−H cross coupling of benzylthioethers or benzylamines with thiophenes enabled by flexible directing groups. Org. Lett. 2019, 21, 5086−5090.

11)  Denan Sun, Jiping Du, Hao Fang, Jingbo Lan,* Di Wu, Jingsong You.* Transient directing ligand- and solvent-controlled C−H/C−H cross-coupling/quaternization cyclization/dequaternization of benzaldehydes with thiophenes. Chem. Commun. 2019, 55, 7518-7521.

12)  Mangang Zhang, Rui Cheng, Jingbo Lan,* Huaxing Zhang, Lipeng Yan, Xingwen Pu, Zhenmei Huang, Di Wu, Jingsong You.* Oxidative C−H/C−H cross-coupling of [1,2,4]triazolo[1,5-a]pyrimidines with indoles and pyrroles: discovering excited-state intramolecular proton transfer (ESIPT) fluorophores. Org. Lett. 2019, 21, 4058−4062.

13)  Luoqiang Zhang, Yanbing Wang, Yang Shi, Yimin Wu, Jingbo Lan,* Weixin Ma, Jingsong You.* Highly regio- and chemoselective oxidative C−H/C−H cross-couplings of anilines and phenols enabled by a co-oxidant-free Rh(I)/Zn(NTf2)2/air catalytic system. ACS Catal. 2019, 9, 5358−5364.

14)  Zheng Liu, Yonghua Xian, Jingbo Lan,* Yuanyuan Luo, Weixin Ma, Jingsong You.* Fusion of aromatic ring to azoarenes: one-pot access to 5,6-phenanthroliniums for mitochondria-targeted far-red/NIR fluorescent probes. Org. Lett. 2019, 21, 1037-1041.

15)  Xingwen Pu, Mangang Zhang, Jingbo Lan*, Shuyou Chen, Zheng Liu, Wenbo Liang, Yudong Yang, Min Zhang, Jingsong You.* Tandem Rh(III)-catalyzed C−H heteroarylation of indolyl ketones and Cu(II)-promoted intramolecular cyclization: one-pot access to blue-emitting phenanthrone-type polyheterocycles. Org. Lett. 2019, 21, 1139-1143.

16)  Yang Shi, Luoqiang Zhang, Jingbo Lan,* Min Zhang, Fulin Zhou, Wenlong Wei, Jingsong You.* Oxidative C–H/C–H cross-coupling reactions between N-acylanilines and benzamides enabled by a Cp*-free RhCl3/TFA catalytic system. Angew. Chem. Int. Ed. 2018, 57, 9108–9112.

17)   Bijin Li, Linsen Zhou, Hu Cheng, Quan Huang, Jingbo Lan,* Liang Zhou,* Jingsong You.* Dual-emissive 2-(2’-hydroxyphenyl)oxazoles for high performance organic electroluminescent devices: discovery of a new equilibrium of excited state intramolecular proton transfer with a reverse intersystem crossing process. Chem. Sci. 2018, 9, 1213–1220.

18)   Huaxing Zhang, Xingyu Chen, Jingbo Lan,* Yanhong Liu, Fulin Zhou, Di Wu,* Jingsong You.* Silver-mediated direct C–H amination of BODIPYs for screening endoplasmic reticulum-targeting reagents. Chem. Commun. 2018, 54, 3219–3222.

19)   Xiuguang Yang, Linfeng Jiang, Mufan Yang, Huaxing Zhang, Jingbo Lan,* Fulin Zhou, Xingyu Chen, Di Wu,* Jingsong You. Pd-catalyzed direct C−H functionalization/annulation of BODIPYs with alkynes to access unsymmetrical benzo[b]‑fused BODIPYs: discovery of lysosome-targeted turn-on fluorescent probes. J. Org. Chem., 2018, 83, 9538−9546.

20)    Wen Wang, Xiaoyu Li, Jingbo Lan,* Di Wu, Ruilin Wang,* Jingsong You. Construction of 3,7-dithienyl phenothiazine-based organic dyes via multistep direct C−H arylation reactions. J. Org. Chem., 2018, 83, 8114−8126.

21)    Yan Wang, Jingbo Lan.* Oxygen as an oxidant in rhodium(III) catalyzed oxidative C–H/C–H cross-coupling between indoles and oxazoles. Sci China Chem, 2018, 61, 200–205.

22)    Danni Zhou, Chunxia Wang, Mingliang Li, Zheng Long, Jingbo Lan.* Palladium-catalyzed 2-pyridylmethyl-directed β-C(sp3)–H activation and cyclization of aliphatic amides with gem-dibromoolefins: a rapid access to γ-lactams. Chin. Chem. Lett., 2018, 29, 191–193.

23)    Bijin Li, Guoqiang Tang, Linsen Zhou, Di Wu, Jingbo Lan,* Liang Zhou,* Zhiyun Lu, Jingsong You.* Unexpected sole enol-form emission of 2-(2'-hydroxyphenyl)oxazoles for highly efficient deep-blue-emitting organic electroluminescent devices. Adv. Funct. Mater. 2017, 27, 1605245.

24)    Guoqiang Tang, Bijin Li, Jingbo Lan,* Jingsong You.* An effective strategy to construct highly efficient deep-blue organic light-emitting field-effect transistors. Adv. Mater. Interfaces, 2017, 1700453.

25)     Xiaoyu Li, Shiqing Li, Ge Gao, Di Wu, Jingbo Lan,* Ruilin Wang,* Jingsong You.* High-performance ruthenium sensitizers containing imidazolium counterions for efficient dye sensitization in water. ChemSusChem, 2017, 10, 2914–2921.

26)     Jie Wu, Yangyang Cheng, Jingbo Lan*, Di Wu, Shengyou Qian, Lipeng Yan, Zhen He, Xiaoyu Li, Kai Wang, Bo Zou*, Jingsong You.* Molecular engineering of mechanochromic materials by programmed C–H arylation: making a counterpoint in the chromism trend. J. Am. Chem Soc. 2016, 138, 12803–12812.

27)      Denan Sun, Bijin Li, Jingbo Lan,* Quan Huang and Jingsong You.* Chelation-assisted Pd-catalysed ortho-selective oxidative C–H/C–H cross-coupling of aromatic carboxylic acids with arenes and intramolecular Friedel–Crafts acylation: one-pot formation of fluorenones, Chem. Commun., 2016, 52, 3635−3638.

28)     Bijin Li, Jingbo Lan,* Di Wu, Jingsong You.* Rhodium(III)-catalyzed ortho-heteroarylation of phenols through internal oxidative C-H activation: rapid screening of single-molecular white-light-emitting materials, Angew. Chem. Int. Ed. 2015, 54, 1400814012.

29)    Xurong Qin, Xiaoyu Li, Quan Huang, Hu Liu, Di Wu, Qiang Guo, Jingbo Lan,* Ruilin Wang, Jingsong You.* Rhodium(III)-catalyzed ortho CH heteroarylation of (hetero)aromatic carboxylic acids: a rapid and concise access to π-conjugated poly-heterocycles. Angew. Chem. Int. Ed. 2015, 54, 71677170.

30)   Xurong Qin, Denan Sun, Qiulin You, Yangyang Cheng, Jingbo Lan,* Jingsong You.* Rh(III)-Catalyzed decarboxylative ortho-heteroarylation of aromatic carboxylic acids by using the carboxylic acid as a traceless directing group. Org. Lett., 2015, 17, 1762−1765.

31)   Xingyan Liu, Xiaoyu Li, Hu Liu, Qiang Guo, Jingbo Lan,* Ruilin Wang, Jingsong You.* Aldehyde as a traceless directing group for Rh(III)-catalyzed C–H activation: a facile access to diverse indolo[1,2-a]quinolines, Org. Lett., 2015, 17, 2936–2939.

32)   Jing Wang, Dekun Qin, Jingbo Lan,* Yangyang Cheng, Shuai Zhang, Qiang Guo, Jie Wu, Di Wu, Jingsong You.* Rh-Catalysed direct cyclization of 1,4-naphthoquinone and 9,10-phenanthraquinone with alkyne: facile access to 1,8-dioxapyrenes and 1,12-dioxaperylenes as orange and red-emitting luminophores. Chem. Commun., 2015, 51, 6337–6339.

33)   Zhijie She, Yangyang Cheng, Luoqiang Zhang, Xiaoyu Li, Di Wu, Qiang Guo, Jingbo Lan,* Ruilin Wang,* Jingsong You.* Novel ruthenium sensitizers with a phenothiazine conjugated bipyridyl ligand for high-efficiency dye-sensitized solar cells, ACS Appl. Mater. Interfaces, 2015, 7, 27831–27837.

34)   Jie Wu, Qiulin You, Jingbo Lan,* Qiang Guo, Xiaoyu Li, Ying Xue, Jingsong You.* Cu-Catalysed direct C–H (hetero)arylation of [1,2,4]triazolo[4,3-a]pyridine to construct deep-blue-emitting luminophores. Org. Biomol. Chem., 2015, 13, 5372–5375.

35)   Hu Liu, Xingrong Liao, Xiaoyu Li, Di Wu, Qiang Guo, Jie Wu, Shengyou Qian, Jingbo Lan,* Ruilin Wang,* Jingsong You.* Molecular design of new organic sensitizers based on thieno[1,4]benzothiazine for dye-sensitized solar cells. RSC Adv., 2015, 5, 56865–56871.

36)   Jie Wu, Jingbo Lan,* Siyuan Guo, Jingsong You.* Pd-Catalyzed C−H carbonylation of (hetero)arenes with formates and intramolecular dehydrogenative coupling: a shortcut to indolo[3,2-c]coumarins. Org. Lett., 2014, 16, 5862−5865.

37)   Quan Huang, Xurong Qin, Bijin Li, Jingbo Lan,* Qiang Guo, Jingsong You.* Cu-catalysed oxidative C–H/C–H coupling polymerisation of benzodiimidazoles: an efficient approach to regioregular polybenzodiimidazoles for blue-emitting materials. Chem. Commun. 2014, 50, 1373913741.

38)   Ningjie Wu, Jingbo Lan,* Lipeng Yan, Jingsong You.* A sensitive colorimetric and fluorescent sensor based on imidazolium-functionalized squaraines for the detection of GTP and alkaline phosphatase in aqueous solution. Chem. Commun. 2014, 50, 44384441.

39)   Xurong Qin,  Hu Liu,  Dekun Qin,  Qian Wu,  Jingsong You,*  Dongbing Zhao,  Qiang Guo,  Xiaolei Huang, Jingbo  Lan,* Chelation-assisted Rh(III)-catalyzed C2-selective oxidative C–H/C–H cross-coupling of indoles/pyrroles with heteroarenes, Chem. Sci. 2013, 4, 1964–1969.

40)   Xuefeng Cong, Jingsong You,* Ge Gao, Jingbo Lan.* 2-Pyridylmethyl ether: a readily removable and efficient directing group for amino acid ligand accelerated ortho-C–H olefination of phenols. Chem. Commun., 2013, 49, 662–664.

41)   Lipeng Yan, Dongbing Zhao, Jingbo Lan,* Yangyang Cheng, Qiang Guo, Xiaoyu Li, Ningjie Wu, Jingsong You.* Palladium-catalyzed tandem N–H/C–H arylation: regioselective synthesis of N-heterocycle-fused phenanthridines as versatile blue-emitting luminophores. Org. Biomol. Chem., 2013, 11, 7966–7977.

42)    Xiaoyu Li, Bijin Li, Jingsong You, Jingbo Lan.* Copper-catalysed oxidative C–H/N–H cross-coupling between formamides and amides through chelation-assisted N–H activation. Org. Biomol. Chem., 2013, 11, 1925–1928.

43)   Bijin Li, Xurong Qin, Jingsong You,* Xuefeng Cong, Jingbo Lan.* Direct arylation of phenanthroline derivatives via oxidative C–H/C–H cross-coupling: synthesis and discovery of excellent ligands. Org. Biomol. Chem., 2013, 11 (8), 1290–1293.

44)   Bo Liu, Zhi Wang, Ningjie Wu, Mingliang Li, Jingsong You,* Jingbo  Lan,* Discovery of full-color-tunable fluorescent core framework via direct CH (hetero)arylation of N-heterocycles. Chem. Eur. J., 2012, 18, 1599–1603.

45)   Xurong Qin, Boya Feng, Jiaxing Dong, Xiaoyu Li, Ying Xue, Jingbo  Lan,* Jingsong You,* Copper(II)-catalyzed dehydrogenative cross-coupling between two azoles. J. Org. Chem. 2012, 77, 7677−7683.

46)   Rongqi Zhou, Bijin Li, Ningjie Wu, Ge Gao, Jingsong You, Jingbo Lan,* Cyclen-functionalized perylenebisimides as sensitive and selective fluorescent sensors for Pb2+ in aqueous solution. Chem. Commun., 2011, 47, 6668–6670.

47)   Xurong Qin, Xuefeng Cong, Dongbing Zhao, Jingsong You, Jingbo Lan,* One-pot synthesis of benzofused heteroaryl azoles via tandem C-heteroatom coupling/C–H activation of azoles. Chem. Commun., 2011, 47, 5611–5613.

48)   Liang Cheng, Jiaxing Dong, Jingsong You, Ge Gao,* Jingbo Lan,* A highly syn-selective nitroaldol reaction catalyzed by CuII-bisimidazoline. Chem. Eur. J., 2010, 16, 6761–6765.

49)   Li Yang, Song Qin, Xiaoyu Su, Fei Yang, Jingsong You,* Changwei Hu, Rugang Xie, Jingbo Lan,* 1,1’-Binaphthyl-based imidazolium chemosensors for highly selective recognition of tryptophan in aqueous solutions. Org. Biomol. Chem., 2010, 339–348.

50)   Weida Wang, Afu Fu, Jingsong You, Ge Gao, Jingbo Lan,* Lijuan Chen,* Squaraine-based colorimetric and fluorescent sensors for Cu2+-specific detection and fluorescence imaging in living cells. Tetrahedron, 2010, 66, 36953701.

 

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