一.发表主要论文 1. Jinghua Tang,† Fei Fan,† Xuefeng Cong,† Lixing Zhao, Meiming Luo, and Xiaoming Zeng* Reductive Cross-Coupling between Unactivated C(aryl)–N and C(aryl)–O Bonds by Chromium Catalysis Using a Bipyridyl Ligand J. Am. Chem. Soc. 2020, DOI: 10.1021/jacs.0c05730. (†These authors contributed equally) 
2. Jinghua Tang,† Liu Leo Liu,† Shangru Yang,† Xuefeng Cong, Meiming Luo, and Xiaoming Zeng* Chemoselective Cross-Coupling between Two Different and Unactivated C(aryl)–O Bonds Enabled by Chromium Catalysis J. Am. Chem. Soc. 2020, 142 (17), 7715–7720. (†These authors contributed equally) 
3. Xiaoming Zeng* Recent Advances in Chromium-Catalyzed Organic Transformations Synlett 2020, 31 (3), 205–210. 
4. Xue Zhang, Liang Ling, Meiming Luo, and Xiaoming Zeng* Accessing Equatorially Difluoromethylated and Trifluoromethylated cis-Cycloalkanes and Saturated Heterocycles by Preferential Hydrogen-Addition to the Substitution Sites for Dearomatization Angew. Chem. Int. Ed. 2019, 58 (47), 16785–16789. 
5. Zhi Rong, Meiming Luo,* and Xiaoming Zeng* Modular Arene Difunctionalization by Sequential Cleavage of Unactivated C–O and C–H Bonds in One Pot with Chromium Catalysis Org. Lett. 2019, 21(17), 6869–6873. 
6. Hong Meng, Sen Gao, Meiming Luo,* and Xiaoming Zeng* Iron and Phenol Co‐Catalysis for Rapid Synthesis of Nitriles under Mild Conditions Eur. J. Org. Chem. 2019, 2019 (28) 4617−4623.
7. Bo Han, Pengchen Ma, Xuefeng Cong, Hui Chen,* and Xiaoming Zeng* Chromium- and Cobalt-Catalyzed, Regiocontrolled Hydrogenation of Polycyclic Aromatic Hydrocarbons: A Combined Experimental and Theoretical Study J. Am. Chem. Soc. 2019, 141 (22), 9018−9026. 
8. Liang Ling, Yuan He, Xue Zhang, Meiming Luo, and Xiaoming Zeng* Hydrogenation of (Hetero)aryl Boronate Esters with a Cyclic (Alkyl)(amino)carbene-Rhodium Complex: Direct Access to cis-Substituted Borylated Cycloalkanes and Saturated Heterocycles Angew. Chem. Int. Ed. 2019, 58 (20), 6554–6558. 
9. Liang Ling, Changpeng Chen, Meiming Luo,* and Xiaoming Zeng* Chromium-Catalyzed Activation of Acyl C–O Bonds with Magnesium for Amidation of Esters with Nitroarenes Org. Lett. 2019, 21 (6), 1912–1916. 
10. Jinghua Tang, Xuejiao J. Gao, Huarong Tang,* and Xiaoming Zeng* Dioxygen activation with stable N-heterocyclic carbenes Chem. Commun. 2019, 55(11), 1584–1587. 
11. Pei Liu, Changpeng Chen, Xuefeng Cong, Jinghua Tang, and Xiaoming Zeng* Chromium-catalyzed para-selective formation of quaternary carbon centers by alkylation of benzamide derivatives Nat. Commun. 2018, 9, 4637. 
12. Jinghua Tang, Pei Liu, and Xiaoming Zeng* N-Heterocyclic carbene–chromium-catalyzed alkylative cross-coupling of benzamide derivatives with aliphatic bromides Chem. Commun. 2018, 54(67), 9325–9328. 
13. Fei Fan, Jinghua Tang, Meiming Luo,* and Xiaoming Zeng* Chromium-Catalyzed Regioselective Kumada Arylative Cross-Coupling of C(aryl)–O Bonds with a Traceless Activation Strategy J. Org. Chem. 2018, 83(21), 13549–13559. 
14. Changpeng Chen, Pei Liu, Meiming Luo, and Xiaoming Zeng* Kumada Arylation of Secondary Amides Enabled by Chromium Catalysis for Unsymmetric Ketone Synthesis under Mild Conditions ACS Catal. 2018, 8(7), 5864–5868. 
15. Yuan He, Jinghua Tang, Meiming Luo,* and Xiaoming Zeng* Regioselective and Chemoselective Reduction of Naphthols Using Hydrosilane in Methanol: Synthesis of the 5,6,7,8-Tetrahydronaphthol Core Org. Lett. 2018, 20(14), 4159–4163. 
16. Lei Jia, Qiang Tang, Meiming Luo,* and Xiaoming Zeng* Direct ortho-Selective Amination of 2-Naphthol and Its Analogues with Hydrazines J. Org. Chem. 2018, 83(9), 5082–5091.
17. Xuefeng Cong, Fei Fan, Pengchen Ma, Meiming Luo, Hui Chen,* and Xiaoming Zeng* Low-Valent, High-Spin Chromium-Catalyzed Cleavage of Aromatic Carbon–Nitrogen Bonds at Room Temperature: A Combined Experimental and Theoretical Study J. Am. Chem. Soc. 2017, 139(42), 15182−15190. 
18. Lei Jia, Qiang Tang, Meiming Luo,* and Xiaoming Zeng* One-Step Synthesis of Unsymmetric 1,1’-Biaryl-2,2'-diamines by the Reaction of 2-Naphthols with Aryl Hydrazines Chin. J. Org. Chem. 2018, 38, 443–450.
19. Jinghua Tang, Meiming Luo,* and Xiaoming Zeng* Chromium-Catalyzed, Regioselective Cross-Coupling of C–O Bonds Using Organic Bromides as Reactants Synlett, 2017, 28(19), 2577–2580. (Invited for cluster of “C–O bond activation”)
20. Sen Gao, Liming Gao, Hong Meng, Meiming Luo,* and Xiaoming Zeng* Iron-Catalyzed Synthesis of Benzoxazoles by Oxidative Coupling/Cyclization of Phenol Derivatives with Benzoyl Aldehyde Oximes Chem. Commun., 2017, 53(71), 9886–9889.
21. Changpeng Chen, and Xiaoming Zeng* Ruthenium-Catalyzed Alkynylation of Benzoic Acids Mediated by a Weakly-Coordination Directing Auxiliary Eur. J. Org. Chem. 2017, 2017(32), 4749–4752.
22. Changpeng Chen, Pei Liu, Jinghua Tang, Gongda Deng, and Xiaoming Zeng* Iridium-Catalyzed, Weakly Coordination-Assisted Ortho-Alkynylation of (Hetero)aromatic Carboxylic Acids without Cyclization Org. Lett. 2017, 19(10), 2474–2477.
23. Pei Liu, Jinghua Tang, and Xiaoming Zeng* Site-Selective Silylation of Aliphatic C–H Bonds Mediated by [1,5]-Hydrogen Transfer: Synthesis of α-Sila Benzamides Org. Lett. 2016, 18(21), 5536–5539.
24. Bin Rao, Jinghua Tang, and Xiaoming Zeng* Synthesis of 2-Benzylphenyl Ketones by Aryne Insertion into Unactivated C–C Bonds Org. Lett. 2016, 18(7), 1678–1681.
25. Xuefeng Cong, Shengxian Zhai, and Xiaoming Zeng* Low-Valent Cobalt-Catalyzed C–H Allylation Org. Chem. Front. 2016, 3(6), 673–677. (Invited as “2015 Emerging Investigator by OCF”)
26. Yuexuan Li, Gongda Deng, and Xiaoming Zeng* Chromium-Catalyzed Regioselective Hydropyridination of Styrenes Organometallics 2016, 35(5), 747–750. 
27. Bin Rao, Jinghua Tang, Yu Wei, and Xiaoming Zeng* Ring Expansion via Cleavage of Benzylic C–C Bonds Enabling Direct Synthesis of Medium Ring-fused Benzocarbocycles Chem.–Asian J. 2016, 11(7), 991–995.
28. Xuefeng Cong, Huarong Tang, and Xiaoming Zeng* Regio- and Chemoselective Kumada–Tamao–Corriu Reaction of Aryl Alkyl Ethers Catalyzed by Chromium Under Mild Conditions J. Am. Chem. Soc. 2015, 137(45), 14367–14372. (Highlights by Synfacts, 2016, 12, 0192; ChemInform, 2016, 47, 21-126) 
29. Yu Wei, and Xiaoming Zeng* Catalytic Strategies toward Selective Hydrogenation of Aromatic Ketones and Phenols: Facile Synthesis of Cyclohexyl Ketones Synlett 2016, 27(5), 650–655. (Invited Synpacts article) 
30. Bin Rao, Huarong Tang, Xiaoming Zeng*, Liu Liu, Mohand Melaimi and Guy Bertrand* Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals Angew. Chem. Int. Ed. 2015, 54(49), 14915–14919. 
31. Yu Wei, Bin Rao, Xuefeng Cong, and Xiaoming Zeng* Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes J. Am. Chem. Soc. 2015, 137(29), 9250–9253. (Highlights by Chin. J. Org. Chem. 2015, 35, 2019; ChemInform, 2016, 47, 03-038) 
32. Xiaoming Zeng* and Xuefeng Cong Chromium-Catalyzed Transformations Using Grignard Reagents: New Opportunities for Cross-Coupling Reactions Org. Chem. Front. 2015, 2(1), 69–72.
33. Xuefeng Cong, Yuexuan Li, Yu Wei, and Xiaoming Zeng* Nickel-Catalyzed C–H Coupling with Allyl Phosphates: A Site-Selective Synthetic Route to Linear Allylarenes Org. Lett. 2014, 16(15), 3926–3929. (Highlight by ChemInform, 2015, 46, 05-054)
34. Xuefeng Cong and Xiaoming Zeng* Iron-Catalyzed, Chelation-Induced Remote C–H Allylation of Quinolines via 8-Amido Assistance Org. Lett. 2014, 16(14), 3716–3719. (Highlight by ChemInform, 2015, 46, 02-047)
35. Yu Wei, Huarong Tang, Xuefeng Cong, Bin Rao, Chao Wu* and Xiaoming Zeng* Pd(II)-Catalyzed Intermolecular Arylation of Unactivated C(sp3)–H Bonds with Aryl Bromides Enabled by 8-Aminoquinoline Auxiliary Org. Lett. 2014, 16(8), 2248–2251. (Highlight by ChemInform, 2014, 45, 41-085)
36. Bin Rao and Xiaoming Zeng* Aminocyanation by the Addition of N–CN Bonds to Arynes: Chemoselective Synthesis of 1,2-Bifunctional Aminobenzonitriles Org. Lett., 2014, 16(1), 314–317. (Highlights by ChemInform, 2014, 45, 23-095; Org. Chem. Highlights 2014, October 13)
37. Xuefeng Cong, Huarong Tang, Chao Wu*, and Xiaoming Zeng* Role of Mono-N-Protected Amino Acid Ligands in Pd(II)-Catalyzed Dehydrogenative Heck Reactions of Electron-Deficient (Hetero)Arenes: Experimental and Computational Studies Organometallics, 2013, 32(21), 6565–6575.
38. Yu Wei, Jinghua Tang, Xuefeng Cong, and Xiaoming Zeng* Practical Metal-Free Synthesis of Chalcone Derivatives via a Tandem Cross-Dehydrogenative-Coupling/Elimination Reaction Green Chem. 2013, 15(11), 3165–3169. (Highlight by ChemInform, 2014, 45, 12-079)
39. Xiaoming Zeng* Recent Advances in Catalytic Sequential Reactions Involving Hydroelement Addition to Carbon–Carbon Multiple Bonds Chem. Rev. 2013, 113(8), 6864–6900. (ESI highly cited paper) 
40. Pei Guo, Xiaoming Zeng, Si Chen, and Meiming Luo* Au(I)–N-heterocyclic carbene complex-catalyzed synthesis of 1-substituted benzo[b][1,4]diazepines from N-substituted o-phenylenediamines and terminal alkynes J. Organomet. Chem. 2013, 751, 438–442.
41. Xiaoming Zeng, Laurean Ilies, and Eiichi Nakamura* Iron-Catalyzed Regio- and Stereoselective Chloro-sulfonylation of Terminal Alkynes with Aromatic Sulfonyl Chlorides Org. Lett. 2012, 14(3), 954–956. (Highlight by ChemInform, 2012, 43, 23-088)
42. Xiaoming Zeng, Laurean Ilies, and Eiichi Nakamura* Synthesis of Functionalized 1H-Indenes via Copper-Catalyzed Arylative Cyclization of Arylalkynes with Aromatic Sulfonyl Chlorides J. Am. Chem. Soc. 2011, 133(44), 17638–17640.
43. Laurean Ilies, Quan Chen, Xiaoming Zeng, and Eiichi Nakamura* Cobalt-Catalyzed Chemoselective Insertion of Alkene into the ortho-C–H Bond of Benzamide J. Am. Chem. Soc. 2011, 133(14), 5221–5223.
44. Xiaoming Zeng, Rei Kinjo, Bruno Donnadieu, and Guy Bertrand* Serendipitous Discovery of the Catalytic Hydroammoniumation and Methylamination of Alkynes Angew. Chem. Int. Ed. 2010, 49(5), 942–945.
45. Xiaoming Zeng, Guido D. Frey, Rei Kinjo, Bruno Donnadieu, and Guy Bertrand* Synthesis of a Simplified Version of Stable Bulky and Rigid Cyclic (Alkyl)(amino)carbenes, and Catalytic Activity of the Ensuing Gold(I) Complex in the Three-Component Preparation of 1,2-Dihydroquinoline Derivatives J. Am. Chem. Soc. 2009, 131(24), 8690–8696.
46. Xiaoming Zeng, Guido D. Frey, Shazia Kousar, and Guy Bertrand* A Cationic Gold(I) Complex as a General Catalyst for the Intermolecular Hydroamination of Alkynes: Application to the One-Pot Synthesis of Allenes from Two Alkynes and a Sacrificial Amine Chem.–Eur. J. 2009, 15(13), 3056–3060.
47. Xiaoming Zeng, Michele Soleilhavoup, and Guy Bertrand* Gold-Catalyzed Intermolecular Markovnikov Hydroamination of Allenes with Secondary Amines Org. Lett. 2009, 11(15), 3166–3169.
48. Xiaoming Zeng, Tongxin Zhang, Yuancheng Qin, Zhijun Wei, and Meiming Luo* Synthesis of a Carbene Transfer Organometallic Polymer and Application to Forming a Recyclable Heterogeneous Catalyst for the Suzuki Reactions of Arylchlorides Dalton Trans. 2009, 2009(39), 8341–8348.
49. Sujuan Zhang, Xiaoming Zeng, Zhijun Wei, Dongbing Zhao, Tairan Kang, Weifeng Zhang, Mei Yan, and Meiming Luo* Desulfitative Suzuki Cross-Couplings of Arylsulfonyl Chlorides and Boronic Acids Catalyzed by a Recyclable Polymer-Supported N-Heterocyclic Carbene-Palladium Complex Catalyst Synlett 2006, 18(12), 1891–1894.
50. Chun Yan, Xiaoming Zeng, Weifeng Zhang, and Meiming Luo* Polymer-Supported N-Heterocyclic Carbene–Rhodium Complex Catalyst for the Addition of Arylboronic Acids to Aldehydes J. Organomet. Chem. 2006, 691(15), 3391–3396.
二.授权专利 1. 曾小明、韩波、罗美明;一种铬盐/甲基溴化镁选择性催化氢化多环芳烃的方法,中国,专利号:ZL 2017 1 0396279.3,授权日期2019-07-09,申请日期2017-05-31. 2. 曾小明、韩波、罗美明;基于钴盐选择性催化氢化多环芳烃的方法,中国,专利号:ZL 2017 1 0396265.1,授权日期2019-07-09,申请日期2017-05-31. |