四川大学化学学院
师资力量

游劲松     教授(博导)、院长

研究方向:构建有机光电材料的合成化学基础;柔性显示材料与器件(OLED);有机电子和空穴传输材料​

联系方式:+86-28-85412203          Email:jsyou@scu.edu.cn

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简历

游劲松 博士,教授化学学院院长。四川大学双一流建设化学与绿色化工学科群首席科学家,四川大学学术委员会委员,四川大学教学指导委员会委员

学习经历

1985.9-1989.6工学学士,重庆大学应用化学系

1992.9-1995.6理学硕士,四川大学化学系有机化学专业,指导教师:蓝仲薇教授

1995.9-1998.6理学博士,四川大学化学系有机化学专业,指导教师:谢如刚教授

工作与研究经历

1989.7-1992.8成都化肥厂,助理工程师、车间主任

1995.7-2000.6四川大学化学系,讲师

1999.2-2000.7台湾中兴大学化学系,博士后

2000.7-2003.5四川大学化学学院,副教授

2001.3-2002.5德国ROSTOCK有机催化研究所 Institute für Organische Katalyseforschung),Research Scientist

2002.5-2003.5美国爱荷华州立大学   (Iowa State University) 化学系,Postdoctoral

2003.5-2004.4美国加州大学尔湾分校 (University of California, Irvine) 化学系,Research Associate

2004.5 - 至今:四川大学教授,博士生导师

2005.8-2011.6四川大学化学学院教授委员会主任

2011.3 – 2017.6四川大学化学学院副院长、化学实验教学中心主任、有机教研室主任

2017.6 – 至今:四川大学化学学院院长、四川大学学术委员会委员,四川大学教学指导委员会委员

2018.1 – 至今:四川大学双一流建设化学与绿色化工学科群首席科学家

主要研究方向

1. 构建有机光电材料的合成化学基础

2. 柔性显示材料与器件(OLED

3. 有机电子和空穴传输材料

主要工作业绩

 1. 主要科研成果

C–H键活化和有机功能材料两个领域做出了系统性创新性研究工作。致力于有机光电功能分子合成的化学基础研究,发展基于C–H键直接高效、高选择性转化构筑各种π共轭结构的新方法、新策略,特别是在芳环或芳杂环之间C–H/C–H氧化偶联反应构筑联(杂)芳基结构方面取得了一系列创新性成果,发现了电子差异原则构筑联杂芳基骨架,发展了螯合导向作用构筑稠杂环策略,为构建有机共轭骨架提供了高效高选择性合成途径,为开发新型先进性功能材料提供了重要合成基础。

游劲松教授团队是国内最早,也是国际上率先开展C–H键活化构筑有机功能材料的代表性课题组之一。团队致力于发展结构新颖、性能优异的有机发光材料和有机电子和空穴传输材料。最近,在构建非传统结构的高性能新型TADF材料方面取得了突破性进展,开发了新型七元环二酰亚胺类TADF材料,通过的微妙平衡,获得了迄今为止最优性能的非掺杂OLED器件,对于推进非掺杂OLED器件的发展和应用具有重要的意义。

在工程化应用方面积极开展工作。作为项目首席专家,承担了863“新型纳米能源材料及器件制备关键技术项目(项目总经费2717万元)。作为技术负责人,承担了江苏省省级科技创新与成果转化项目(超高强高模杂环芳纶III单体的关键技术研发及产业化,项目经费1000万元)。发展了拥有自主知识产权的新型聚酰亚胺高性能材料,工程项目已在江苏开工建设,并实现工程化批量化生产。

项目负责人迄今发表论文270余篇,其中在Rev. Chem.J. Am. Chem. Soc.Angew. Chem. Int. Ed.Nat. Commun.等具有重要影响的期刊上发表论文近70篇,授权国际国内发明专利24项。已主持863项目、国家自然科学基金重点项目、国家杰出青年科学基金、以及多项企业合作项目等,总经费超过4000万元。部分研究成果获得教育部自然科学奖一等奖。

 

2. 主要荣誉与奖励

2016年万人计划科技创新领军人才

2014年国家中青年科技创新领军人才

2010年获得国家杰出青年科学基金

2013新型纳米能源材料及器件关键制备技术”863项目首席专家

2012年获得国务院特殊津贴专家称号

2013年四川省学术和技术带头人

2006年获得四川省突出贡献专家

2006年成都市优秀青年教师称号

2005年入选四川省杰出青年学科带头人培养计划(省杰青)

2004年入选教育部新世纪优秀人才资助计划

2012四川大学唐立新青年科技之星奖

2010年获得教育部自然科学一等奖:简单金属盐催化的C-C键和C-N键形成反应

2005年获得四川省青年科技奖

2001年获得四川省科技进步三等奖:生物功能体系的分子模拟

代表性成果 (获奖成果、专著、论文、专利)

 

一、 代表性论文(20203月为止)

1. Zhenmei Huang, Zhengyang Bin,* Rongchuan Su, Feng Yang, Jingbo   Lan, Jingsong You.* Molecular Design for Non-Doped OLEDs Based on a   Twisted Heptagonal Acceptor: Delicate Balance between Rigidity and   Rotatability. Angew. Chem. Int. Ed., 2020, DOI:   10.1002/anie.201915397.

2. Shuaijun Yang, Ping-An Yin, Lin Li, Qian Peng, Xinggui Gu, Ge   Gao, Jingsong You, Ben Zhong Tang.* Crystallization‐Induced Reversal   from Dark to Bright Excited States for Construction of Solid‐Emission‐Tunable   Squaraines. Angew. Chem. Int. Ed., 2020, DOI:   10.1002/anie.201914437.

3. Zhiqian Yu, Yan Zhang, Junbin Tang, Luoqiang Zhang, Qianhui Liu,   Qian Li, Ge Gao,* and Jingsong You*. Ir-catalyzed Cascade C−H   Fusion of Aldoxime Ethers and Heteroarenes: Scope and Mechanisms. ACS   Catal. 2020, 10, 203-209.

4. Jiangliang Yin, Yuming Zhang, Jian Li, Lei Zhu, Yu LanJingsong You* Acyl radical to   rhodacycle addition and cyclization relay to access butterfly flavylium   fluorophores Nat. Commun 2019, 9 , 10, 5664.

5. Guangying Tan, Yimin Wu, Yang Shi, Jingsong You.*   Syngas-Free Highly Regioselective Rhodium-Catalyzed TransferHydroformylation   of Alkynes to α,β-Unsaturated Aldehydes. Angew. Chem. Int. Ed., 2019,   58 (22), 7440–7444.

6. Zhishuo Wang, Jiangliang Yin, Fulin Zhou, Yunqi Liu, Jingsong   You*, Multicomponent Reactions of Simple Pyridines to Ring-Fused   Pyridiniums via in Situ Activation Strategy Using 1,2-Dichloroethane as a   Vinyl Equivalent. Angew. Chem. Int. Ed., 2019, 58 (1),   254–258.

7. Jiangliang Yin, Jingsong You.*   Concise Synthesis of Polysubstituted Carbohelicenes by a C–H   Activation/Radical Approach/C–H Activation Sequence. Angew. Chem. Int. Ed.   2019, 58 (1), 302 –306.

8. Shiping Yang, Rui Cheng, Min Zhang, Zhengyang Bin, and Jingsong   You*. “Rh/Ag-Mediated Peri-Selective Heteroarylation/Single Electron   Transfer Annulation Cascade of 1-(Methylthio)naphthalenes and Analogues: Road   Less Traveled to Benzo[de]thioacenes”. ACS Catal., 2019,   9 (7), 6188-6193.

9. Luoqiang Zhang, Yanbing Wang, Yang Shi, Yimin Wu, Jingbo Lan,*   Weixin Ma, Jingsong You.* “Highly regio- and chemoselective oxidative   C−H/C−H cross-couplings of anilines and phenols enabled by a co-oxidant-free   Rh(I)/Zn(NTf2)2/air catalytic system”. ACS Catal.   2019, 9, 5358−5364.

10. Shuyou Chen, Min Zhang, Rongchuan Su, Xingyu Chen, Boya Feng, Yudong   Yang,* and Jingsong You*. “C2/C4 Regioselective Heteroarylation of   Indoles by Tuning C−H Metalation Modes”. ACS Catal. 2019, 9   (7), 6372−6379.

11. Min Zhang, Anping Luo, Yang Shi,   Rongchuan Su, Yudong Yang* and Jingsong You*. “F+   Reagent-Promoted Pd-Catalyzed C7−H Arylation of 1-Naphthamides”. ACS Catal. 2019,   9, 11802-11807.

12. Chengming Li, Lei Zhu, Wenbo Liang, Rongchuan Su, Jiangliang   Yin, Yanmei Hu, Yu Lan, Di Wu*, Jingsong You*, An unusual [4+2]   fusion strategy to forge meso-N/O-heteroarene-fused (quinoidal)   porphyrins with intense near-infrared Q-bands. Chem. Sci., 2019,   10 (30), 7274−7280.

13. Yang Shi, Luoqiang Zhang, Jingbo Lan*, Min Zhang, Fulin Zhou,   Wenlong Wei, Jingsong You.* Oxidative C−H/C−H Cross-Coupling Reactions   between N-Acylanilines and Benzamides Enabled by a Cp*-Free RhCl3/TFA   Catalytic System. Angew. Chem. Int. Ed. 2018, 57 (29),   9108−9112.

14. Guangying Tan, Qiulin You, Jingbo Lan, Jingsong You*,   Iridium-Catalyzed Annulation Reactions of Thiophenes with Carboxylic Acids:   Direct Evidence for a Heck-type Pathway. Angew. Chem. Int. Ed. 2018,   57 (21), 6309–6313.

15. Zhijie She, Yi Wang, Deping Wang, Yinsong Zhao, Tianbao Wang,   Xuesong Zheng, Zhi-Xiang Yu,* Ge Gao,* Jingsong You*, Two-Fold C−H/C−H Cross-Coupling Using   RhCl3·3H2O as the Catalyst: Direct Fusion of N-(Hetero)arylimidazolium   Salts and (Hetero)arenes. J. Am. Chem Soc., 2018, 140 (39), 12566–12573.

16. Guangying Tan, Qiulin You, Jingsong You*,   Iridium-Catalyzed Oxidative Heteroarylation of Arenes and Alkenes: Overcoming   the Restriction to Specific Substrates, ACS Catal. 2018, 8   (9), 8709−8714.

17. Luoqiang Zhang, Lei Zhu, Yuming Zhang, Yudong Yang, Yimin Wu,   Weixin Ma, Yu Lan,* Jingsong You.* Experimental and Theoretical   Studies on Ru(II)-Catalyzed Oxidative C−H/C−H Coupling of Phenols with   Aromatic Amides Using Air as Oxidant: Scope, Synthetic Applications, and   Mechanistic Insights. ACS Catal. 2018, 8 (9),   8324−8335.

18. You Ran, Yudong Yang, Huansha You, Jingsong You*.   RhCl3-Catalyzed Oxidative C−H/C−H Cross-Coupling of   (Hetero)aromatic Sulfonamides with (Hetero)arenes. ACS Catal. 2018,   8 (3), 1796-1801.

19. Yimin Wu, Wei Li, Linfeng Jiang, Luoqiang Zhang, Jingbo Lan, Jingsong You.* Rhodium-catalyzed ortho-heteroarylation of phenols:   directing group-enabled switching of the electronic bias for heteroaromatic   coupling partner. Chem. Sci., 2018, 9 (33), 6878–6882.

20. Jiangliang Yin, Fulin Zhou, Lei Zhu, Mufan Yang, Yu Lan, Jingsong   You.* Annulation cascade of arylnitriles with alkynes to   stable delocalized PAH carbocations via intramolecular rhodium migration. Chem.   Sci., 2018, 9 (24), 5488-5493.

21. Bijin Li, Linsen Zhou, Hu Cheng, Quan   Huang, Jingbo Lan,* Liang Zhou*, Jingsong You*. Dual-emissive   2-(2’-hydroxyphenyl)oxazoles for high performance organic electroluminescent   devices: discovery of a new equilibrium of excited state intramolecular   proton transfer with a reverse intersystem crossing process. Chem. Sci.,   2018, 9 (5), 1213–1220.

22. Guangying   Tan, Lei Zhu, Xingrong   Liao, Yu Lan*, Jingsong   You*, Rhodium/Copper   Cocatalyzed Highly trans-Selective 1,2-Diheteroarylation of Alkynes with   Azoles via C–H Addition/Oxidative Cross-Coupling: A Combined Experimental and   Theoretical Study. J. Am. Chem. Soc., 2017, 139 (44),   15724–15737.

23. Jiangliang Yin, Meiling Tan, Di Wu, Ruyong Jiang,Chengming Li, Jingsong   You*, Synthesis of Phenalenyl-Fused Pyrylium Cations: Divergent C−H   Activation/Annulation Reaction Sequence of Naphthalene Aldehydes with   Alkynes. Angew. Chem. Int. Ed. 2017, 56, 13094–13098.

24. Yudong Yang, Jingbo Lan, Jingsong You*. Oxidative C–H/C–H   Coupling Reactions between Two (Hetero)arenes. Chem. Rev., 2017,   117(13), 8787−8863.

25. Bijin Li, Guoqiang Tang, Linsen Zhou, Di Wu, Jingbo Lan,* Liang   Zhou,* Zhiyun Lu, Jingsong You,* Unexpected Sole Enol-Form Emission of   2-(2′-Hydroxyphenyl)oxazoles for Highly Efficient Deep-Blue-Emitting Organic   Electroluminescent Devices. Adv. Funct. Mater., 2017, 27,   1605245.

26. Yinsong Zhao, Shiqing Li, Xuesong Zheng, Junbin Tang, Zhijie   She, Ge Gao,* Jingsong You,* Rh/Cu-Catalyzed Cascade [4+2] Vinylic C−H   O-Annulation and Ring Contraction of α-Aryl Enones with Alkynes in   Air. Angew. Chem. Int. Ed., 2017, 56(15), 4286−4289.

27. Yangyang Cheng, Gaocan Li, Yang Liu,   Yang Shi, Ge Gao,* Di Wu, Jingbo Lan, Jingsong You.* Unparalleled Ease   of Access to a Library of Biheteroaryl Fluorophores via Oxidative   Cross-Coupling Reactions: Discovery of Photostable NIR Probe for   Mitochondria. J. Am. Chem Soc., 2016, 138 (14), 4730–4738.

28. Qian Wu, Yi Luo, Aiwen Lei,* Jingsong   You.* Aerobic Copper-Promoted Radical-Type Cleavage of Coordinated   Cyanide Anion: Nitrogen Transfer to Aldehydes to Form Nitriles. J. Am. Chem Soc., 2016,   138 (9), 2885–2888.

29. Jie Wu, Yangyang Cheng, Jingbo Lan*, Di   Wu, Shengyou Qian, Lipeng Yan, Zhen He, Xiaoyu Li, Kai Wang, Bo Zou*, Jingsong   You.* Molecular Engineering of Mechanochromic Materials by Programmed C–H   Arylation: Making a Counterpoint in the Chromism Trend. J. Am. Chem Soc., 2016, 138 (39),   12803–12812.

30. Guangying Tan, Shuang He, Xiaolei Huang,   Xingrong Liao, Yangyang Cheng, Jingsong You.* Cobalt-Catalyzed Oxidative   C–H/C–H Cross-Coupling between Two Heteroarenes. Angew. Chem. Int. Ed.,   2016, 55 (35), 10414–10418.

31. Yangyang Cheng, Yimin Wu, Guangyin Tan, Jingsong   You.* Nickel Catalysis-Enabled Oxidative C(sp2)−H/C(sp2)−H   Cross-Coupling Reactions between Two Heteroarenes. Angew. Chem. Int. Ed.,   2016, 55 (40), 12275 –12279.

32. Zhuang Yang, Taijin Wang, Fang Wang,   Ting Niu, Zhuowei Liu, Xiaoxin Chen, Chaofeng Long, Minghai Tang, Dong Cao,   Xiaoyan Wang, Wei Xiang, Yuyao Yi, Liang Ma, Jingsong You,* Lijuan   Chen.* Discovery of Selective Histone Deacetylase 6 Inhibitors Using the   Quinazoline as the Cap for the Treatment of Cancer. J. Med. Chem., 2016,   59 (4), 1455–1470.

33. Kaizhi Li, Qian Wu, Jingbo Lan,   Jingsong You.* Coordinating activation strategy for C(sp3)-H/C(sp3)-H   Cross-Coupling to Access b-Aromatic a-Amino Acids. Nat. Commun., 2015,   6, 8404.

34. Zhen He, Xiaotian Qi, Shiqing Li,   Yinsong Zhao, Ge Gao,* Yu Lan,* Yiwei Wu, Jingbo Lan, Jingsong You.* Transition-Metal-Free   Formal Decarboxylative Coupling of α-Oxocarboxylates with α-Bromoketones   under Neutral Conditions: a Simple Access to 1,3-Diketones. Angew. Chem.   Int. Ed., 2015, 54(3),   855−859.

35. Xurong Qin, Xiaoyu Li, Quan Huang, Hu Liu, Di Wu, Qiang Guo,   Jingbo Lan,* Ruilin Wang, Jingsong You.* Rhodium(III)-Catalyzed ortho   C–H Heteroarylation of (Hetero)aromatic Carboxylic Acids: A Rapid and Concise   Access to p-Conjugated Poly-heterocycles. Angew. Chem. Int. Ed., 2015, 54(24), 7167−7170.

36. Xiaolei Huang, Yan   Wang, Jingbo Lan, Jingsong You.* Rhodium(III)-Catalyzed   Activation of Csp3-H Bonds and Subsequent Intermolecular Amidation at Room   Temperature, Angew. Chem. Int. Ed., 2015, 54(32), 9404−9408.

37. Bijin Li, Jingbo Lan,* Di Wu, Jingsong   You.* Rhodium(III)-Catalyzed ortho-Heteroarylation of Phenols through   Internal Oxidative C−H Activation: Rapid Screening of Single-Molecular   White-Light-Emitting Materials, Angew. Chem. Int. Ed., 2015, 54(47),   14008−14012.

38. Qian Wu, Chenglong Du, Yumin Huang,   Xingyan Liu, Zhen Long, Feijie Song, Jingsong You.* Stoichiometric to   Catalytic Reactivity of the Aryl Cycloaurated Species with Arylboronic Acids:   Insight into the Mechanism of Gold-Catalyzed Oxidative C(sp2)–H   Arylation. Chem. Sci., 2015, 6(1), 288−293.

39. Yang Shi, Zhen Wang, Yangyang Cheng,   Jingbo Lan, Zhijie She and Jingsong You.* Oxygen as an Oxidant in   Palladium/Copper-Cocatalyzed Oxidative C–H/C–H Cross-Coupling between Two   Heteroarenes, Sci. China Chem., 2015, 58, 1292–1296.

40. Xingyan Liu, Gaocan Li, Feijie Song, Jingsong   You.* Unexpected Regioselective Carbon–Hydrogen Bond   Activation/Cyclization of Indolyl Aldehydes or Ketones with Alkynes to   Benzo-Fused Oxindoles. Nat. Commun., 2014, 5, 5030.

41. Yumin Huang, Di Wu, Jingsheng Huang,   Qiang Guo, Juan Li, Jingsong You.* Wilkinson's Catalyst for the   ortho-C-H Heteroarylation of Aromatic Amines: A Facile Access to Highly   Extended π-Conjugated Heteroacenes for Organic Semiconductors. Angew.   Chem. Int. Ed., 2014, 53(45),   12158−12162.

42. Yuanhong Ma, Shuai Zhang, Shiping Yang,   Feijie Song,* Jingsong You.* Gold-Catalyzed Cascade C(sp3)–H/C(sp)–H   Coupling/Cyclization/Oxidative Alkynylation: A Powerful Strategy for the   Synthesis of 3-Alkynyl Polysubstituted Furans. Angew. Chem. Int. Ed., 2014, 53(30), 7870–7874.

43. Gaocan Li, Feijie Song, Di Wu, Jingbo   Lan, Xingyan Liu, Jie Wu, Shuaijun Yang, Dan Xiao, Jingsong You.*   Cation-Anion Interaction-Directed Molecular Design Strategy for   Mechanochromic Luminescence. Adv. Funct. Mater., 2014, 24 (6),   747−753.

44. Gaocan Li, Shiyong Zhang,*   Ningjie Wu, Yangyang Cheng, Jingsong You.* Spontaneous   Counterion-Induced Vesicle Formation: Multivalent Binding to Europium(III)   for a Wide Range Optical pH Sensor.   Adv. Funct. Mater., 2014, 24 (39),   6204−6209.

45. Zhuang Yang, Wenshuang Wu, Jingjing   Wang, Li Liu, Luyuan Li, Jianhong Yang, Guangcheng Wang, Dong Cao, Ronghong   Zhang, Minghai Tang, Jiaolin Wen, Jun Zhu, Wei Xiang, Fang Wang, Liang Ma,   Mingli Xiang, Jingsong You, Lijuan Chen.* Synthesis and Biological   Evaluation of Novel Millepachine Derivatives As a New Class of Tubulin   Polymerization Inhibitors. J. Med. Chem., 2014, 57, 7977−7989.

46. Dongbing Zhao, Gaocan Li, Di Wu, Xurong Qin, Patrik Neuhaus,   Yangyang Cheng, Shuaijun Yang, Zhiyun Lu, Xuemei Pu, Chao Long, Jingsong   You.* Regiospecific N-Heteroarylation of Amidines for Full-Color-Tunable   Boron Difluoride Dyes with Mechanochromic Luminescence. Angew. Chem. Int.   Ed., 2013, 52 (51), 13676−13680.

47. Xiaolei Huang, Jingsheng Huang, Chenglong Du, Xingyi Zhang,   Feijie Song, Jingsong You.* N-Oxide as a Traceless Oxidizing Directing Group: Mild Rhodium(III)-Catalyzed C–H Olefination   for the Synthesis of ortho-Alkenylated Tertiary Anilines. Angew.   Chem. Int. Ed., 2013, 52 (49), 12970−12974.  

48. Kaizhi Li, Guangying Tan, Jingsheng Huang, Feijie Song, Jingsong   You.* Iron-Catalyzed Oxidative C–H/C–H Cross-Coupling: An Efficient Route to   α-Quaternary α-Amino Acid Derivatives. Angew. Chem. Int. Ed., 2013, 52   (49), 12942–12945.

49. Hongjun Zhou, Yinsong Zhao, Ge Gao,* Shiqing Li, Jingbo Lan,   Jingsong You.* Highly Selective Fluorescent Recognition of Sulfate in Water   by Two Rigid Tetrakisimidazolium Macrocycles with Peripheral Chains. J.   Am. Chem. Soc., 2013, 135 (40), 14908−14911.

50. Gaocan Li, Shengyou Qian, Chunxia Wang, Jingsong You.*   Palladium(II)-Catalyzed Dehydrogenative Cross-Coupling between Two Csp3–H   Bonds: Unexpected C=C Bond Formation. Angew. Chem. Int. Ed.,   2013, 52 (30), 7837–7840.

51. Jiaxing Dong, Zhen Long, Feijie Song,   Ningjie Wu, Qiang Guo, Jingbo Lan, Jingsong You.* Rhodium or   Ruthenium-Catalyzed Oxidative C–H/C–H Cross-Coupling: Direct Access to   Extended π-Conjugated Systems. Angew. Chem. Int. Ed., 2013,   52 (2), 580–584.

52. Bo Liu, Yumin Huang, Jingbo Lan, Feijie Song, Jingsong You.*   Pd-Catalyzed Oxidative C–H/C–H Cross-Coupling of Pyridines with Heteroarenes.   Chem. Sci., 2013, 4 (5), 2163–2167.

53. Xurong Qin, Hu Liu, Dekun Qin, Qian Wu,   Jingsong You,* Dongbing Zhao, Qiang Guo, Xiaolei Huang, Jingbo Lan.*   Chelation-Assisted Rh(III)-Catalyzed C2-Selective Oxidative C–H/C–H   Cross-Coupling of Indoles/Pyrroles with Heteroarenes. Chem. Sci., 2013,   4 (5), 1964–1969.

54. Shuaijun Yang, Jingsong You,*   Jingbo Lan, Ge Gao.* Facile Access to Extremely Efficient Energy-Transfer   Pairs via an Unexpected Reaction of Squaraines with Ketones. J. Am. Chem.   Soc., 2012, 134 (29), 11868–11871.

55. Siping Wei, Xiyu Li, Zhuang Yang, Jingbo   Lan, Ge Gao, Ying Xue, Jingsong You.* Ligand-Switching and   Counteranion-Induced Hierarchical Self-Assembly of Silver-NHC Complexes. Chem.   Sci., 2012, 3 (2), 359–363.

56. Zhen Wang, Kaizhi Li, Dongbing Zhao,   Jingbo Lan, Jingsong You.* Palladium-Catalyzed Oxidative C–H/C–H   Cross-Coupling of Indoles and Pyrroles with Heteroarenes. Angew. Chem.   Int. Ed. 2011, 50 (23), 5365–5369.

57. Peihua Xi, Fan Yang, Song Qin, Dongbing   Zhao, Jingbo Lan, Ge Gao, Changwei Hu,* Jingsong You.* Palladium(II)-Catalyzed   Oxidative C–H/C–H Cross-Coupling of Heteroarenes. J. Am. Chem. Soc. 2010,   132 (6), 1822–1824.

58. Dongbing Zhao, Ningjie Wu, Shuai Zhang,   Peihua Xi, Xiaoyu Su, Jingbo Lan, Jingsong You.* Synthesis of Phenol,   Aromatic Ether, and Benzofuran Derivatives by Copper-Catalyzed Hydroxylation   of Aryl Halides. Angew. Chem. Int. Ed. 2009, 48 (46),   8729−8732.

59. Dongbing Zhao, Wenhai Wang, Fei Yang,   Jingbo Lan, Li Yang, Ge Gao, Jingsong You.* Copper-Catalyzed   Direct C Arylation of Heterocycles with Aryl Bromides: Discovery of   Fluorescent Core Frameworks. Angew. Chem. Int. Ed. 2009, 48   (18), 3296−3300.

60. Shiyong Zhang, Shuaijun Yang, Jingbo   Lan, Yurong Tang, Ying Xue, Jingsong You.* Ultrasound-Induced   Switching of Sheetlike Coordination Polymer Microparticles to Nanofibers   Capable of Gelating Solvents. J. Am. Chem. Soc. 2009, 131   (5), 1689−1691.

61. Liwei Yan, Li Yang, Jingbo Lan, Jingsong   You.* A New Perylene Diimide-Based Colorimetric and Fluorescent   Sensor for Selective Detection of Cu2+ Cation. Sci. China Chem., 2009, 52 (4), 518−522.

62. Fei Yang, Dongbing Zhao, Jingbo Lan,   Peihua Xi, Li Yang, Shuhuai Xiang, Jingsong You.* Self-Assembled   Bifunctional Catalysis Induced by Metal Coordination Interactions: An Exceptionally   Efficient Approach to Enantioselective Hydrophosphonylation. Angew. Chem.   Int. Ed. 2008, 47 (30), 5646−5649.

63. Wen Chen, Yuanyuan Zhang, Liangbo Zhu,   Jingbo Lan, Rugang Xie, Jingsong You.* A Concept of Supported Amino   Acid Ionic Liquids and Their Application in Metal Scavenging and   Heterogeneous Catalysis. J. Am. Chem. Soc. 2007, 129   (45), 13879–13886.

64. Jingsong You, John G. Verkade.* A General Method for the Direct   α-Arylation of Nitriles with Aryl Chlorides. Angew. Chem. Int. Ed.,   2003, 42, 5051–5053.

65. Jingsong You, Hans-Joachim Drexler, Songlin Zhang, Christine   Fischer, Detlef Heller.* Preparation and Asymmetric Hydrogenation of   β-Aryl-Substituted β-Acylaminoacrylates. Angew. Chem. Int. Ed., 2003, 42   (8), 913–916.

66. Jingsong You, Juhua Xu, and John G. Verkade.* A Highly Active   and Selective Catalyst System for the Baylis–Hillman Reaction. Angew.   Chem. Int. Ed. 2003, 42, 5054–5056.

67. Detlef Heller*, Hans-Joachim Drexler, Anke Spannenberg, Barbara   Heller, Jingsong You, Wolfgang Baumann.* The Inhibiting Influence of Aromatic   Solvents on the Activity of Asymmetric Hydrogenations. Angew. Chem. Int.   Ed., 2002, 41 (5), 777–780.

二、授权专利

1. 胡国宜、胡雪明、周国平、游劲松、兰静波:2,4,4'-三硝基苯甲酰苯胺的制备方法,中国,专利号:CN102633674B,授权日期: 2014-05-07, 申请日期2012-03-27. IPC分类号: C07C231/02; C07C233/66.

2. 游劲松、闵雪锋、胡国宜、李开治、兰静波、丁志伟:吲哚-4-甲醛的制备方法, 中国,专利号:CN102351774A,授权日期: 2014-01-17。申请日期2011-08-31. IPC分类号: C07D209/08.

3. 游劲松、闵雪锋、吴建华、胡国宜、兰静波、屈季春、吴宁捷:双(对氨基苯氧基)烷烃的制备方法,中国,专利号CN102381985B,授权日期:2014-03-26, 申请日期 2011-08-31IPC分类号: C07C217/84;   C07C213/02

4. 游劲松、闵雪锋、胡国宜、兰静波、吴建华、杨状、杨磊:2-苯基-4,4’-二氨基二苯醚的制备方法,中国,专利号:CN102276484B   (ZL201110254946.7),授权日期:2013-12-18, 申请日期 2011-08-31. IPC分类号: C07C213/02; C07C217/90.

5. 胡国宜、薛建伟、闵雪锋、缪文宏、杨飞、游劲松、兰静波:2,2’-(三氟甲基)-4,4’-二氨基联苯的制备方法,中国,专利号CN101525294B (ZL20091 0029005.6),授权日期:   2013-02-27。申请日期2009-01-20. IPC分类号: C07C209/54; C07C211/52.

6. 胡国宜、薛建伟、闵雪锋、缪文宏、杨莉、杨飞、游劲松、兰静波:N,N’ –(4-乙氧基羰基苯基)-N’-苄基甲脒的制备方法,中国,专利号CN101481331B (ZL200910029007.5),授权日期:   2013-2-13。申请日期2009-01-20. IPC分类号: C07C249/00; C07C257/12.

7. 胡国宜、丁志伟、缪文宏、闵雪峰、周国平、丛雪丰、游劲松、兰静波:制备4,4’-二苯醚二甲酸的方法,中国,专利号CN101774909B (ZL201010113376.5),授权公告日2012-10-3。申请日期2010-02-24. IPC分类号: C07C51/265; C07C65/24.

8. Heller, D.; Drexler, H.-J.; You, J.;   Zhang, S: E-isomeric b-Aromatic or   Heteroaromatic Substituted b-Acylamino-Acrylates   and Methods of Preparing the Same: WO 2004011414 A1, 授权日期2004-02-05. 申请日期2002-07-26. IPC: C07C229/34;   C07C233/47; (IPC1-7): C07C231/02.

9. 吴迪、郭强、游劲松、董嘉兴:一类双噻吩基吡咯并[3,4-c]吡咯-1,4-二酮与(杂)芳烃共聚物的制备方法,中国,专利号:CN103012751A (ZL201210502479.X),授权日期:   2015-05-20。申请日期 2012-11-30IPC分类号: C08G61/12.

10. 游劲松、李开治、吴迪、郭强、兰静波、高戈:基于非贵金属催化的C–H/C–H氧化偶联反应高效制备β-()芳基丙氨酸衍生物的方法,中国,专利号: CN104788331A;公开(公告)号 : CN104788331B;公开(公告)日 : 2016-05-04;专利号:ZL 201510189661.8,授权日期:2016-07-22,申请日期2015-04-21. IPC分类号: C07C229/36; C07C269/00; C07C271/22; C07C227/20.

11. 胡国宜、胡雪明、周国平、游劲松、兰静波:2-(对氨基苯基)-5-氨基苯并咪唑的精制方法,中国,公开号CN102603648B,授权日期2016-04-13,申请日期 2012-03-27IPC分类号: C07D235/18

12. 王镇, 赵东兵, 王韦达, 兰静波, 游劲松: (6R)-四氢生物喋呤盐酸盐的制备方法, PCT(国际),WO2010CN01836, 申请日期2010-11-15, 授权日期2012-04-19. IPC: C07D475/04

13. 胡国宜、金晓贤、闵雪锋、胡雪明、李高参、董嘉兴、游劲松、兰静波:N-(4-乙氧基羰基苯基)-N’-甲基-N’-苯基甲脒的制备方法,中国,公开号: CN102060734A,授权日期2015-05-20,申请日期 2011-01-14IPC分类号: C07C257/12

14. 游劲松、郭强、秦绪荣、兰静波、吴迪、高戈:基于铑催化的C–H/C–H氧化偶联反应高效制备双()芳环并吡喃酮/环戊酮衍生物的方法,中国,专利公开号¬: CN201410503476;专利号:ZL 201410503476.7,授权日期2016-08-17,申请日期: 2014-09-28IPC分类号: C07D493/04; C07D333/78; C07D495/04; C07D495/14.

15. 游劲松、李必进、兰静波、吴迪、高戈:基于过渡金属催化的C–H/C–H氧化偶联反应高效制备邻羟基苯基杂环类衍生物的方法,中国,专利申请号:   201510217606.5,申请日期:2015-05-04;公开(公告)号 : CN104829550A;公开(公告)日 : 2015.08.12;授权号:ZL 201510217606.5;授权日期2016-10-05IPC分类号: C07D263/57;   C07J43/00; C07D413/04

16. 高戈、李世清、杨帆、游劲松、兰静波、宋飞杰:由硼酸制备咪唑类鎓盐的新方法,中国,专利申请号201410026715.4,申请日期 2014-01-21;公开(公告)号 : CN103755638A;公开(公告)日 : 2014-04-30;授权号:证书尚未到手;授权日期:2016-9-14IPC分类号: C07D233/58;   C07D409/14; C07D487/04; C07D471/04; C07D235/06

17. 胡锦平、胡国宜、吴建华、游劲松、兰静波、高戈、吴迪、李娟:4-羟基邻苯二甲酸的制备方法,中国,申请号 : CN201410516726.0;申请日期: 2014-09-30;授权公开号-: CN201410516726,授权日期:2016-09-21IPC分类号: C07C51/02; C07C65/03。四川大学为第二申请人

18. 游劲松、李必进、兰静波、吴迪、高戈:有机单分子白光材料双三苯胺取代邻羟基苯基唑类衍生物的制备及应用,中国,申请号: 201510219515.5,申请日期:2015-05-04;公开(公告)号 : CN104962277;公开(公告)日: 2015-10-07;授权公告号¬: CN104962277B,专利号:ZL 2015 1 0219515.5, 授权日期:2017-05-24IPC分类号: C07D263/32(2006.01)I; C07D277/28(2006.01)I; H01L33/50(2010.01)I

19. 游劲松、佘智杰、兰静波、吴迪、程杨洋、张骆强:一类用于染料敏化太阳能电池的吩噻嗪直接取代联吡啶钌染料,中国,专利号:CN105131043B (ZL201510556082.2),授权日期:2017-10-27,申请日期2015-09-05. IPC分类号: C07F15/00.

20. 游劲松、李成明、吴迪:一类可用于染料敏化太阳能电池的吲哚啉卟啉染料,中国,专利号:CN105131641B (ZL201510556048.5),授权日期:2017-11-28,申请日期:2015-09-05. IPC分类号:C09B47/08.

21. 游劲松、万丹阳、吴迪:一类用于染料敏化太阳能电池的吲哚啉基卟啉类近红外染料及其制备,中国,专利号:CN105176135B (ZL201510557739.7),授权日期:2017-11-28,   申请日期:2015-09-05. IPC分类号: C09B47/08.

22. 游劲松、李必进、兰静波、吴迪、高戈:有机单分子白光材料双三苯胺取代邻羟基苯基唑类衍生物的制备及应用,中国,专利号:CN 104962277B (201510219515.5),授权日期:2017-05-24,申请日期:2015-05-04. IPC分类号: C07D263/32.

23. 吴迪、江汝泳、杨修光、游劲松:具有宽吸收光谱的吲哚基氮杂氟硼荧类染料,中国,专利号:CN107189488B (ZL201710356574.6),授权日期:2019-03-01,申请日期2017-05-19. IPC分类号: C07D209/08.

24. 游劲松、李啸宇、兰静波:咪唑鎓为阳离子的水溶性联吡啶-钌类光敏剂及其在染料敏化太阳能电池中的应用,中国,专利号:CN105175455B (ZL201510557794.6),授权日期:2019-04-16,申请日期2015-09-05. IPC分类号: C07F15/00.

三、专

1. 谢如刚主编,2007,《现代有机合成化学》(十一五国家重点图书),游劲松完成绪论有机合成设计与评价有机合成中的网络资源和原料三章,华东理工大学出版社。

2. 胡跃飞、林国强主编,2008,《现代有机反应》,游劲松完成斯泰特反应一章(第四卷:碳-碳键的生成反应),化学工业出版社。

3. 胡跃飞、林国强主编,2012,《现代有机反应》,游劲松完成金属催化的芳环直接芳基化反应一章(第六卷:金属催化反应),化学工业出版社。

4. Yudong Yang; Jingsong You, Chapter 3, Pd-Catalyzed Synthesis of   Oxygen-Containing Heterocycles, p65-90, Transition Metal-Catalyzed   Heterocycle Synthesis via C-H Activation, Edited by Xiao-Feng Wu, 2016,   Wiley-VCH Verlag Gmgh & Co., Germany (ISBN 978-3-527-33888-7)

 

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