四川大学化学学院
师资力量

苏志珊     教 授(博士生导师)

研究方向:绿色化学、物理化学

联系方式:028-85415608          Email:suzhishan@scu.edu.cn

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简历

2015至今,四川大学,化学学院,教授

20102013,韩国仁荷大学,自然科学学院,Assistant Professor

20102015,四川大学,化学学院,副教授

20022010,四川大学,化学学院,讲师

2000至今,四川大学,化学学院,任教

20012006,四川大学化学学院攻读博士学位,理学博士

19972000,四川大学化学学院攻读硕士学位,理学硕士

19931997,四川大学化学学院本科学习,理学学士

主要研究方向

不对称催化反应机理理论研究及相关分子设计

主要工作业绩

近年来承担国家自然科学基金、教育部博士点(新教师)基金、四川大学青年优秀学者基金(B)等多项科研项目,在不对称反应机理及新催化剂设计方面开展理论研究工作。在J. Am. Chem. Soc., Chem. Eur. J., J. Catal., Organometallics,   J. Org. Chem., Org. Lett., ACS Sustainable Chem. Eng.等国际期刊上发表SCI 收录论文60余篇。2013年入选教育部新世纪优秀人才支持计划,同年获四川大学青年骨干教师荣誉称号2014年入选四川省学术和技术带头人后备人选。

科研项目:

1) 手性胍-金属配合物结构、性质及催化重氮酯不对称X-H(X=NCO) 入反应机理理论研究

(国家自然科学基金面上项目,No. 219730662020.01-2023.12, 负责人,65.0 万)

2)  生物质溶剂解形成的寡聚物的结构特性和催化转化研究

(国家自然科学基金国际(地区)合作与交流项目,No. 21911540465, 2019.07.01- 2021.06.30,负责人,11.0 万)

3) 手性胍/金属配合物催化重氮酯不对称C-HO-H插入反应机理研究

(四川大学创新火花项目,2019.5.5-2022.5.5,负责人,24.0 万)

4) 手性双氮氧-金属配合物结构、性质及催化Roskamp-Feng反应机理研究

(国家自然科学基金面上项目,No.215721412016.01-2019.12,   负责人,76.24 万)

5) 多环天然产物合成中的手性控制

(国家自然科学基金委重大项目,子课题二,No.212901802013.01-2017.12355.0万元,冯小明教授主持,本人参加,110.0万)

6) 手性Al-Schiff 碱催化C=O C=N 双键氢膦酰化反应机理研究

(国家自然科学基金青年基金No.211020962012.1-2014.12,负责人,28.0万)

7) 手性C2对称双氮氧-过渡金属配合物催化不对称反应机理研究

(四川大学优秀青年学者研究基金(B)No.2013SCU04B172013.09-2015.12负责人,20.0)

8) 手性Al-Schiff 碱催化醛氢膦酰化反应机理理论研究

(教育部博士点新教师基金,No.2008061010072009.01-2011.12负责人,3.6 万元)

9) 手性Al-Schiff 碱催化醛氢膦酰化反应机理理论研究

(四川大学校青年基金,No.校青070542008.1-2009.12负责人,1.0 万元)

 

人才基金项目:

教育部新世纪优秀人才支持计划(2013)No. NCET-13-039050.0   万元,负责人

代表性成果 (获奖成果、专著、论文、专利)

1)       Jing Li, Xiangxiang Meng, Changwei Hu, Zhishan Su*, Cooperative   catalysis of chiral guanidine and Rh2(OAc)4 in asymmetric   O−H insertion of carboxylic acid: a theoretical investigation, J. Org.   Chem., 2019, DOI:10.1021/acs.joc.8b02850.

2)       Dong Jing, Cong Lu, Zhuo Chen, Songyang Jin, Lijuan Xie, Ziyi   Meng, Zhishan Su, Ke Zheng*, Light-driven intramolecular   C-N cross-coupling via a long-lived photo-active photoisomer complex, Angew.   Chem. Int. Ed., 2019, DOI: 10.1002/anie.201906112

3)       Qiong Tang, Kai Fu, Peiran Ruan, Shunxi Dong,* Zhishan Su,   Xiaohua Liu, Xiaoming Feng*, Asymmetric catalytic formal 1, 4-allylation of b, γ-unsaturated a-ketoesters: allylboration/   oxy-copeRearrangement, Angew. Chem. Int. Ed., 2019, 58, 11846-11851.

4)       Ya Wu, Hua Chen, Wenyu Yang, Yu Fan, Lu Gao,* Zhishan Su,   Changwei Hu, Zhenlei Song*, Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl   allyloxysilanes via chirality transfer from siliconto carbon, RSC Adv.,   2019, 9, 26209-26213.

5)       Xiangxiang Meng, Jing Li, Yini Zuo, Changwei Hu, Zhishan Su*,   Theoretical study on asymmetric [2 + 2] cycloaddition of an alkynone with a cyclic   enol silyl ether catalyzed by a chiral N, N’‑Dioxide-Zn(II) complex,   Organometallics, 2019, 38, 3111-3123.

6)       Wangbin Wu, Weidi Cao, Linfeng Hu, Zhishan Su, Xiaohua   Liu*, Xiaoming Feng*, Asymmetric Baeyer–Villiger oxidation: classical and parallel   kinetic resolution of 3-substituted cyclohexanones and desymmetrization of meso-disubstituted   cycloketones, Chem. Sci., 2019, 10, 7003-7008.

7)       Yini Zuo, Xiangxiang Meng, Changwei Hu, Jing Li, Zhishan Su*,   Mechanism study on asymmetric Michael addition reaction between alkynone   and α-angelica lactone catalyzed by chiral N, N'-dioxide-Sc(III)   complex, Catalysis Today, 2019, Doi.org/10.1016/ j.cattod.2019.03.056.

8)       Junming Wang, Zengjin Liu, Jing Li, Zhenlei Song*, Changwei Hu, Zhishan   Su*, Exo/endo selectivity control in Diels−Alder reactions of geminal bis(silyl)   dienes: theoretical and experimental studies, J. Org. Chem., 2019,   84, 3940-3952.

9)       Cong Lu, Zhishan Su(共同一作), Dong Jing, Songyang Jin, Lijuan Xie, Liangrui Li, Ke Zheng*, Intramolecular   reductive Cyclization of o-nitroarenes via biradical recombination, Org.   Lett., 2019, 21, 1438-1443.

10)    Shulin Ge, Weidi Cao, Tengfei Kang, Bowen Hu, Hang Zhang, Zhishan   Su, Xiaohua Liu, Xiaoming Feng*, Bimetallic Catalytic Asymmetric Tandem   Reaction of β-Alkynyl Ketones to Synthesize 6,6-Spiroketals, Angew.   Chem. Int. Ed., 2019, 131, 4057-4061.

11)    Iris K.M. Yu, Daniel C. W. Tsang*, Alex C. K. Yip, Zhishan Su*,   Karine De Oliveira Vigier, François Jérôme, Chi Sun Poon, Yong Sik Ok*, Organic   Acid-Regulated Lewis Acidity for Selective Catalytic Hydroxymethylfurfural   Production from Rice Waste: An Experimental−Computational Study, ACS   Sustainable Chem. Eng., 2019, 7, 1437-1446.

12)    Yiping Luo, Zheng Li, Yini Zuo, Zhishan Su, Changwei Hu*, Effects of γ-Valerolactone/H2O Solvent on the   Degradation of pubescens for Its Fullest Utilization, J. Agric. Food   Chem., 2018, 66 (24), 6094-6103.

13)    Iris K. M. Yu, Daniel C. W. Tsang*, Zhishan Su, Alex C.   K. Yip, Jin Shang, Yong Sik Ok, Ki-Hyun Kim*, Chi Sun Poon, Contrasting Roles   of Maleic Acid in Controlling Kinetics and Selectivity of Sn(IV)- and Cr(III)-Catalyzed   Hydroxymethylfurfural, ACS Sustainable Chem. Eng., 2018, 6 (11),   14264-14274.

14)    Jing Li, Zhishan Su*, Junming Wang, Changwei Hu,   Mechanistic investigations on asymmetric N-H insertion of amines catalyzed by   palladium-chiral guanidine complex, J. Catal., 2018, 364,   426-436.

15)    Yini Zuo, Na Yang, Xunkun Huang, Changwei Hu, and Zhishan Su*,   Mechanism and origins of stereoinduction in an asymmetric Friedel−Crafts alkylation   reaction of chalcone catalyzed by chiral N, N'‑dioxide−Sc(III) complex,   J. Org. Chem., 2018, 83, 4628-4640.

16)    Zhishan Su, Yini Zuo, Changwei Hu*, Theoretical investigation on direct vinylogous   Aldol reaction of isatin, catalyzed by chiral N, N'-dioxide   Sc(III) complex, Molecular Catalysis 2018, 453, 22-30.

17)    Zhishan Su, Weiying He, Junming Wang,   Yini Zuo and Changwei Hu*, Theoretical investigation on donor–acceptor   interaction between a carbonyl compound and an N,N'-dioxide–Sc(III)   complex, RSC Adv., 2017, 7, 56054-56061.

18)    Yiping Luo, Zheng Li, Yini Zuo, Zhishan Su, and Changwei   Hu*, A Simple two-step method for the selective conversion of hemicellulose   in pubescens to furfural, ACS Sustainable Chem. Eng., 2017,   5(9), 8137-8147.

19)    Yini Zuo, Zhishan Su*, Junming Wang, and Changwei Hu,   Theoretical study on the mechanism and selectivity of asymmetric   cycloaddition reactions of 3-vinylindole catalyzed by chiral N, N'-dioxide-Ni(II)   complex, Catalysis Today, 2017, 298, 130-137.

20)    Junming Wang, Yini Zuo, Zhishan Su*, Changwei Hu,   Theoretical and experimental studies on the structure–property relationship   of chiral N,N'-dioxide–metal catalysts probed by the carbonyl–ene reaction of   isatin, Catal. Sci. Technol., 2017, 7, 2183-2193.

21)    Zubao Gan, Zhiwen Chu, Jia Hu, Zhishan Su, Changwei Hu,   Lu Gao, Zhenlei Song*, Tunable reactivity of geminal bis(silyl) enol   derivatives leading to selective exo-IEDDA or Sakurai allylation with a β, γ-unsaturated   ketoester, Chem. Commun., 2016, 52, 10137-10140.

22)    Junming Wang, Zhishan Su*, Na Yang, Changwei Hu, Mechanistic   study on asymmetric carbonyl-ene reaction between alkyl enol ethers and isatin catalyzed by NN'-dioxide-Mg(OTf)2   complex, J. Org. Chem., 2016, 81 (15),   6444-6456.

23)    Xinglong Lin, Zubao Gan, Ji Lu, Zhishan Su, Changwei Hu,   Yuebao Zhang, Ya Wu, Lu Gao*, Zhenlei Song*, Visible light-promoted radical   cyclization of silicon-tethered alkyl iodide and phenyl alkyne: An efficient   approach to synthesize benzosilolines, Chem. Commun., 2016, 52, 6189-6192.

24)      Zengjin Liu, Xinglong Lin, Na Yang, Zhishan Su*, Changwei Hu, Peihong   Xiao, Yanyang He, Zhenlei Song*, Unique steric effect   of geminal bis(silane) to control the high exoselectivity in intermolecular   Diels−Alder reaction, J. Am. Chem. Soc.,   2016, 138, 1877-1883.

25)    Zhishan Su, Chan Kyung Kim,* Trienamine   catalysis for asymmetric Diels–Alder reactions of 2,4-dienones: a theoretical   investigation, Org. Biomol. Chem., 2015, 13, 6313–6324.

26)    Na Yang, Zhishan Su,* Xiaoming Feng, Changwei Hu,* Theoretical   studies on chiral N,N′-dioxide−Sc(III) complex catalyzed asymmetric   Baeyer-Villiger oxidation reaction of 4-phenylcyclohexanone with m-chloroperoxobenzoic   acid, Chem. Eur. J., 2015, 21, 7264 -7277.

27)    Haofei Huang, Qian Chen, Misun Choi, Raju Nandhakumar, Zhishan   Su*, Sihyun Ham,* and Kwan Mook Kim*, High Enantioselective extraction of   underivatized amino acids by the uryl-pendant hydroxyphenyl-binol ketone,   Chem. Eur. J., 2014, 20, 2895.

28)    Ya Wu, Linjie Li, Hongze Li, Lu Gao, Hengmu Xie, Zhigao Zhang, Zhishan   Su, Changwei Hu*, and Zhenlei Song,* Regioselective nucleophilic addition   of organometallic reagents to 3-geminal bis(silyl) N-acyl pyridinium, Org.   Lett., 2014, 16, 1880-1883.

29)    Xincui Ye, Xianwei Sun, Zhenggang Huang, Na Yang, Zhishan Su,   Changwei Hu and Zhenlei Song*, Regioselective 1,4- over 1,2-addition of   3,3-bis(silyl) allyloxy lithium to enals, enones and enoates, the remarkable   α-effect of silicon, Org. Biomol. Chem., 2014, 12, 3021-3025.

30)    Haofei Huang, Raju Nandhakumar, Misun Choi, Zhishan Su*,   and Kwan Mook Kim* Enantioselective liquid–liquid extractions of underivatized   general amino acids with a chiral ketone extractant, J. Am. Chem. Soc.,   2013, 135 (7), 2653.

31)    Na Yang, Liang Dong, Zhishan Su and Changwei Hu*, Theoretical   study on the mechanism of Pd(OAc)2 catalyzed dehydrogenative   cross-coupling of two heteroarenes, RSC Adv., 2013, 3, 20772.

32)    Zhishan Su and Chan Kyung Kim*, DFT   investigation of C-H bond activation of malononitrile in the presence of   amines, New J. Chem., 2013, 37, 3920.

33)    Zhishan Su, Weiyi Li, Jun Wang,   Changwei Hu*, and Xiaoming Feng*, A theoretical investigation on the Strecker   reaction catalyzed by a TiIV complex catalyst generated from a cinchona   alkaloid, achiral substituted 2,2’-biphenol,   and tetraisopropyl titanate, Chem. Eur. J. 2013, 19, 1637.

34)    Zhishan Su, Hai Whang Lee, and Chan   Kyung Kim*, Asymmetric 1,4-Michael addition reactions catalyzed by a cinchona   alkaloid derived primary amine: a theoretical investigation of the reaction mechanism   and enantioselectivity, Eur. J. Org. Chem. 2013, 1706.

35)    Weiyi Li, Zhishan Su, and Changwei Hu*, Mechanism of ketone   allylation with allylboronates as catalyzed by zinc compounds: A DFT Study, Chem.   Eur. J. 2013, 19, 124.

36)    Weiyi Li, Song Qin, Zhishan Su, Changwei Hu*, and   Xiaoming Feng*, Theoretical study on the mechanism and stereochemistry of   salicylaldehyde–Al(III)-catalyzed hydrophosphonylation of benzaldehyde, Computational   and Theoretical Chemistry, 2012, 989, 44.

37)    Liang Dong, Jun Wen, Song Qin, Na Yang, Huaqing Yang, Zhishan   Su, Xiaoqi Yu*, and Changwei Hu*, Iron-Catalyzed Direct Suzuki−Miyaura   Reaction: Theoretical and experimental studies on the mechanism and the regioselectivity,   ACS Catal. 2012, 2, 1829.

38)    Chang Kon Kim, In Suk Han, Chang Kook Sohn, Yu Hee Yu, Zhishan   Su, and Chan Kyung Kim*, Comparative studies on the reactions of carbamyl   and thiocarbamyl halides with NH3    in the gas phase and in aqueous solution: a theoretical study, BULLETIN   OF THE KOREAN CHEMICAL SOCIETY, 2012, 33(6), 1955.

39)    Liang Dong, Song Qin, Huaqing Yang, Zhishan Su, and Changwei   Hu*, Theoretical investigation on copper hydrides catalyzed hydrosilylation   reaction of 3-methylcyclohex-2-enone: mechanism and ligands' effect, Catal.   Sci. Technol., 2012, 2, 564.

40)    Weiyi Li, Song Qin, Zhishan Su, Huaqing Yang, and   Changwei Hu*, Theoretical study on the mechanism of Al(salalen)-catalyzed hydrophosphonylation   of aldehydes, Organometallics 2011, 30, 2095.

41)    Zhishan Su, Hai Whang Lee, and Chan   Kyung Kim*, Theoretical investigation on mechanism of asymmetric Michael   addition of malononitrile to chalcones catalyzed by Cinchona alkaloid   aluminium(III) complex, Org. Biomol. Chem. 2011, 9, 6402.

42)    Zhishan Su, Song Qin, Changwei Hu*,   and Xiaoming Feng*, Theoretical investigations on the mechanism of hetero-Diels–Alder   reactions of Brassard’s diene and 1, 3-butadiene catalyzed by a tridentate   Schiff base titanium(IV) complex, Chem. Eur. J. 2010, 16, 4359.

43)    Xiuli Cao, Song Qin, Zhishan Su, Huaqing Yang, Changwei   Hu*, and Xiaoming Feng*, Theoretical study on hetero-Diels–Alder reaction of butadiene   with benzaldehyde catalyzed by chiral InIII complexes, Eur.   J. Org. Chem. 2010, 3867.

44)    Liang Dong, Song Qin, Zhishan Su, Huaqing Yang, and   Changwei Hu*, Computational investigation on the mechanism and the   stereoselectivity of Morita–Baylis–Hillman reaction and   the   effect of the bifunctional catalyst N-methylprolinol, Org.   Biomol. Chem. 2010, 8, 3985.

45)    Jie Liu, Zhigang Yang, Zhen Wang, Fei Wang, Xiaohong Chen,   Xiaohua Liu, Xiaoming Feng*, Zhishan Su, and Changwei Hu*, Asymmetric direct   Aldol reaction of functionalized ketones catalyzed by amine organocatalysts based   on bispidine, J. Am. Chem. Soc. 2008, 130, 5654.

46)    Xiaohong Chen, Jun Wang, Yin Zhu, Deju Shang, Bo Gao, Xiaohua   Liu, Xiaoming Feng*, Zhishan Su, and Changwei Hu*, Secondary amine amide   organocatalyst for the asymmetric nitroaldol reaction of α-ketophosphonates, Chem.   Eur. J. 2008, 14, 10896.

47)    Zhigang Yang, Jie Liu, Xiaohua Liu, Zhen Wang, Xiaoming Feng*, Zhishan   Su, and Changwei Hu*, Highly efficient amine organocatalysts based on bispidine   for the asymmetric Michael addition of ketones to nitroolefins, Adv.   Synth. Catal. 2008, 350, 2001.

48)    Song Qin, Changwei Hu*, Huaqing Yang, Zhishan Su, and   Dianyong Tang, Computational investigation on stereochemistry in titanium-salicylaldehydes-catalyzed   cyanation of benzaldehyde, J. Org. Chem. 2008, 73, 4840.

 

 

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