四川大学化学学院
师资力量

袁立华     教 授(博导)

研究方向:有机化学,高分子化学

联系方式:028-85418755;028-85412890          Email:lhyuan@scu.edu.cn

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简历

袁立华博士,博士生导师,1998年晋升教授,第八届四川大学教学名师奖 和首届四川大学卓越教学奖 1998年至2005年先后在香港大学和美国纽约州立大学从事研究工作。研究方向涉及有机化学、高分子合成、超分子自组装与功能材料以及放射化学领域。从事本科教学30多年,主讲过《有机反应机理(双语)》、《高分子科学导论(双语)》、《高分子化学》、《精细化学品检测与剖析》、《大分子合成(英语)》、《趣味化学》、《合成化学》、《化学实验安全技术》、《三级英语》等课程。

工作经历(科研与学术工作经历,按时间倒序排序):

2006/01 - 至今 四川大学化学学院 教授

2002/01 - 2005/12 美国纽约州立大学 Research   Scientist

1998/03 - 2002/12 香港大学化学系 Research   Associate

1998/06 - 2002/12 四川大学化学学院 教授

1993/11 - 1998/05 四川大学化学系 副教授

1992/09 - 1993/10 四川大学化学系 讲师

1984/07 - 1986/09 四川大学化学系 助教

主要研究方向

主要涉及与有机化学、高分子化学以及放射化学相关的超分子功能材料的设计、合成及其应用研究。

1. 超分子组装与功能材料

主要研究基于分子内含三中心氢键的大环芳酰胺和非环寡聚芳酰胺的超分子组装与功能材料,包括主-客体络合、纳米管组装、准轮烷及轮烷构筑、超分子凝胶调控、液晶行为调控、离子对识别以及金属离子络合萃取等方面。

2. 有机功能材料 的制备及其 在离子识别与核素分离中应用研究

研究主要基于柱芳烃、杯芳烃、环芳酰胺等大环分子的设计合成及其对镧锕系离子、过渡金属离子以及碱金属离子的识别与萃取性能。其中,首次在国际上将柱芳烃衍生物萃取剂用于镧锕系离子识别与分离研究。

主要工作业绩

先后主持或主研过国家自然科学基金、教育部博士点基金等省部级科研项目 30多项,在J. Am. Chem. Soc.Angew. Chem. Int. Ed.Chem. Sci.Chem. Commun.Org. Lett.等国内外刊物上发表论文100余篇。2017年四川省科技进步二等奖(第三完成人),2015年获首届四川大学卓越教学奖三等奖,2013年获第八届四川大学教学名师奖和四川大学-唐立新教学名师奖2015年、2014年和2012年度四川大学课堂教学质量优秀奖,2016年和2012年度获大学生课外科技实践活动优秀指导教师,2011年荣获四川大学第五届优秀本科教学一等奖,2012年四川大学校级优秀教材书目一等奖(排名第三),2009年获四川大学教学名师培养对象,2008年获四川大学教育教学成果奖二等奖2项;指导的本科毕业论文多次荣获优秀本科论文一等奖、二等奖和三等奖。

代表性成果 (获奖成果、专著、论文、专利)

 近年代表性成果:

1. Li, X. W.; Yuan, X. Y.; Deng; P. C.; Chen, L. X.; Ren,   Y.; Wang, C. Y.; Wu L. X.; Feng, W.; Gong, B.; Yuan, L. H.*,   Macrocyclic shape-persistency of cyclo[6]aramide results in enhanced   multipoint recognition for the highly efficient template-directed synthesis   of rotaxanes, Chem. Sci., 2017,8, 2091-2100.

2. Yuan, X. Y.; Jia, Y. M.; Cai, Y. M.; Feng, W.*; Li, Y.   M.; Li, X. P.*; Yuan, L. H.*, Unusual binding selectivity with   non-selective homoditopic pillar[5]arene oxime: serendipitous discovery of a   unique approach to heterobinuclear metalation in solution, Chem.   Commun., 2017, 53, 2838-2841.

http://202.115.32.186:8080/_vsl/5DC35A61C57816E7983439FC961F6E8A/2AABC042/3B07

3. Mao, L. J.; Pan, W.; Fu, Y. H.; Chen, L. X.; Xu, M.;   Ren, Y.;Feng, W.;Yuan, L. H.*, Reversibly tunable lower critical   solution temperature behavior induced by H-bonded aromatic amide macrocycle   and imidazolium host-guest complexation, Org. Lett., 2017,   19, 18-21.

http://202.115.32.186:8080/_vsl/90CCF5E926A15E623612B7F62C1D4237/FE8CF05D/3013

4. Kang, K.; Huang W.; Fu, Y. H.; Chen, L. X.; Hu, J. C.;   Ren, Y.; Feng, W.; Yuan, L. H.*, Pyridine-incorporated cyclo[6]aramide   for recognition of urea and its derivatives with two different binding modes,   Supramol. Chem., 2017, 29, 730-740.

http://202.115.32.186:8080/_vsl/E513D2E4142CCC437229FC2CF61D83C7/BA847CFC/27F8

5. Li, C. X.; Wu, L.; Chen, L. X.; Yuan, X. Y.; Cai, Y. M.;   Feng, W.*; Liu, N.; Ren, Y.; Sengupta, A.*; Murali, S. M.; Mohapatra, K. P.;   Tao, G. H.; Zeng, H. Q.; Ding, S. D.; Yuan, L. H.*, Highly efficient extraction   of actinides with pillar[5]arene-derived diglycolamides in ionic liquid via a   unique mechanism involving competitive host-guest interactions, Dalton   Trans., 2016, 45, 19299-19310.

http://202.115.32.186:8080/_vsl/7B0D6047CA6B161C4B7EBC5E22B18AE1/66F23C6A/45DC

6. Shi, S. S.; Zhu, Y. M.; Li, X. W.; Yuan, X. Y.; Ma, T.; Yuan,   W. L; Tao, G. H.; Feng, W.; Yuan, L. H.*, Ion-pair recognition of   amidinium salts by partially hydrogen-bonded heteroditopic cyclo[6]aramide, RSC   Adv., 2016, 6, 39839-39845.

7. Chen, L.; Yuan, X. Y.; Wang, Z. X.; Luo, Y, R.; Huang,   W.; Zhang, S.; Yuan, W. L.; Qin, S.; Tao, G. H.; Yuan, L. H.*, A   redox-responsive complex system based on 2 D shape-persistent cyclo[6]aramide   and ferrocenium, Asian J. Org. Chem., 2016, 5, 966-970.

8. Li, X. W.; Li, B.; Chen, L.; Hu, J. C.; Wen, C. D.;   Zheng, Q. D.; Wu, L. X.; Zeng, H. Q.; Gong, B.* Yuan, L. H.*,   Liquid-crystalline mesogens based on cyclo[6]aramides: Distinctive phase   transitions in response to macrocyclic host-guest interactions, Angew.   Chem. Int. Ed., 2015, 54, 11147-11152.

http://202.115.32.186:8080/_vsl/44EB2153668F61A96B2FA50BEAE606C0/332E451F/4D42

9. Fang, Y. Y.; Yuan, X. Y.; Wu, L.; Peng, Z. Y.; Feng,   W.*; Liu, N.; Xu, D. G.; Li, S. J.; Sengupta, A.; Mohapatra, P. K; Yuan,   L. H.*, Ditopic CMPO-pillar[5]arenes as unique receptors for efficient   separation of americium(III) and europium(III), Chem. Commun.,   2015, 51, 4263-4266.

http://202.115.32.186:8080/_vsl/68F70B05C55CA17EC38D8A6CD7C4640F/2722DD53/3E5F

10. Chen, L.; Peng, Z. Y.; Liu, S.; Li, X. W.; Chen, R. Z.;   Ren Y.; Feng W.; Yuan, L. H.*, Cyclo[6]aramide-tropylium charge   transfer complex as a colorimetric chemosensor for differentiation of   intimate and loose ion pairs, Org. Lett., 2015, 17,   5950-5953.

http://202.115.32.186:8080/_vsl/FEB160F532B527EA0F2CD97573E411C7/9E1B1E7D/36D7

11. Fang, Y. Y.; Li, C. X.; Wu, L.; Bai, B.; Li, X.; Jia,   Y. M.; Feng, W.*; Yuan, L. H.*, A non-symmetric pillar[5]arene based   on triazole-linked 8-oxyquinolines as a sequential sensor for thorium(IV)   followed by fluoride ions, Dalton Trans., 2015, 44,   14584-14588. (Front cover)

http://202.115.32.186:8080/_vsl/512FD7CC63505B082A6A66BAA9ACFC6A/33020C86/2C45

12. Xu, M.; Chen, L.; Jia, Y. M.; Mao, L. J.; Wen, F.; Yuan,   L. H.*, A rare case for binding a diquat salt by two cyclo[6]aramides, Supramol.   Chem., 2015, 27, 436-443.

http://202.115.32.186:8080/_vsl/816B7A46A0B596B2073B9E5B0D62BD81/B655EA7F/35B6

13. He, Y. Z.; Xu, M.; Gao, R. Z.; Li, X. W.; Li, F. X.;   Wu, X. D.; Xu, D. G.*, Zeng, H. Q.; Yuan, L. H.*, Two-component   supramolecular gels derived from amphiphilic shape-persistent   cyclo[6]aramides for specific recognition of native arginine , Angew. Chem. Int. Ed., 2014,   53, 11834-11839.

Link to full-size graphical abstract

14. Hu, J. C.; Chen, L.; Shen, J.; Luo, J.; Deng, P. C.;   Ren, Y.; Zeng, H. Q.; Feng, W.*; Yuan, L. H.*, Convergent   heteroditopic cyclo[6]aramides as macrocyclic ion-pair receptors for   constructing [2]pseudorotaxanes, Chem. Commun., 2014, 50,   8024-8027.

http://202.115.32.186:8080/_vsl/E4A75552D0B1C7265752250EBEE84396/4DBDAFCF/2D30

15. Wu, L.; Fang, Y. Y.; Jia, Y. M.; Yang, Y. Y.; Liao, J.   L.; Liu, N.; Yang, X. S.; Feng, W.*, Ming, J. L.; Yuan, L. H.*,   Pillar[5]arene-based diglycolamides for highly efficient separation of   americium(III) and europium(III), Dalton Trans.,2014, 43,   3835-3838. (Front cover)

http://202.115.32.186:8080/_vsl/18B2A3B213DBFC9F44362B48B7332B9E/E771E94C/3AFA

16. Chu, H. Z.; He, L. T.; Jiang, Q.; Fang, Y. Y.; Jia, Y.   M.; Yuan, X. Y.; Zou, S. L.; Li, X. H.; Feng, W.*; Yang, Y. Y.; Liu, N.; Luo,   S. Z.; Yang, Y. Q.; Yang, L.; Yuan, L. H.*, CMPO-calix[4]arenes with   spacer containing intramolecular hydrogen bonding: Effect of local   rigidification on solvent extraction towards f-block elements, J.   Hazard. Mater., 2014, 264, 211-218.

17. Jia, Y. M.; Fang, Y. Y.; Li, Y.; He, L. T.; Fan, W. H.;   Feng, W.*; Yang, Y. Y.; Liao, J. L.; Liu, N.; Yuan, L. H.*,   Pillar[5]arenes bearing phosphine oxide pendents as Hg2+ selective   receptors, Talanta, 2014, 125, 322-328.

18. Li, Y.; Jia, Y. M.; Wang, Z. W.; Li, X. H.; Feng, W.;   Deng, P. C.*; Yuan, L. H.*, An insight into the extraction of transition metal ions by   picolinamides associated with intramolecular hydrogen bonding and rotational   isomerization ,   RSC Adv., 2014, 4, 29702-29714.

19. Hu, J. C.; Chen, L.; Ren, Y,; Deng, P. C.; Li, X. W.;   Wang, Y. J.; Jia, Y. M.; Luo, J.; Yang, X. S.; Feng, W.*; Yuan, L. H.*;   Nonaggregational shape-persistent cyclo[6]aramide and its macrocyclic effect   toward binding secondary ammonium salts in moderately polar media, Org.   Lett., 2013, 15, 4670-4673.

http://202.115.32.186:8080/_vsl/CC2F0DAFC1EDD934B122E076B2CE9F5C/4228F9AC/22E3

20. Li, Y. B.; Liu, C. H.; Xie, Y. Z.; Li, X.; Fan, X. L.*,   Yuan, L. H.* and Zeng, Q. D.*, Single-molecule observation of the K+-induced   switching of valinomycin within a template network, Chem. Commun., 2013, 49,   9021-9023 .

21. Li, X. H.; Jia, Y. M.; Ren, Y.; Wang, Y. J.; Hu, J. C.;   Ma, T.; Feng, W.; Yuan, L. H.*, Quadruply hydrogen-bonded   heteroduplexes based on imide and urea units arrayed with ADDA/DAAD sequence,   Org. Biomol. Chem., 2013, 11, 6975-6983.

22. Fang, Y. Y.; Wu, L.; Jia, Y. M.; Chen, L.; Yang, Y. Y.;   Liu, N.; He, L. T.; Zou, S. L.; Feng, W.*; Yuan, L. H.*, Pillar[5]arene-based   phosphine oxides: novel ionophores for solvent extraction separation of   f-block elements from acidic media, RSC Adv., 2013, 3,   12376-12383.

23. Pan, X. S.; Chen, C.; Peng, J.; Yang, Y. A.; Wang Y.   H.; Feng, W.*;Deng, P. C.*; Yuan, L. H.*,Supramolecular graft   copolymers in moderately polar media based on hydrogen-bonded aromatic   oligoamide units, Chem. Commun., 2012, 48,   9510-9512.

24. Zou, S. L.; He, L. T.; Zhang, J.; He, Y. Z.; Yuan,   L. H.*; Wu, L. X*.; Luo, J.; Wang, Y. H.; Feng, W., Tunable   mesogens based on shape-persistent aromatic oligoamides: From lamellar, columnar,   to nematic liquid crystalline phase , Org. Lett., 2012, 14, 3584-3587.

25. Yang, X. S.; Chen, L.; Yang, Y. A.; He, Y. Z.; Zou, S.   L.; Feng, W. *; Yang, Y. Y.; Liu, N.; Liao, J. L.; Yuan, L. H.*;   Synthesis of crescent aromatic oligoamides with preorganized chelating groups   and their extraction towards transition metal ions, J. Hazard. Mater.,   2012, 217-218, 171-176.

26. Zhong, L. J.; Chen, L.; Feng, W.; Zou, S. L.; Yang, Y.   Y.; Liu, N.; Yuan, L. H.*, Shape-persistent macrocycles: efficient   extraction towards lanthanide and actinide elements, J. Incl. Phenom.   Macrocycl. Chem.,2012, 72, 367-373.

27. Yang, Y. A.; Feng, W.; Hu, J. C.; Zou, S. L.; Gao, R.   Z.; Yamato, K.; Kline, M.; Cai, Z. H.; Gao, Y.; Wang, Y. B.; Li, L. B.; Yang,   Y. L.; Yuan, L. H.*; Zeng, X. C.*; Gong, B.*, Strong aggregation and   directional assembly of aromatic oligoamide macrocycles, J. Am. Chem.   Soc., 2011,133, 18590-18593.

28. Zhang, P. H.; Chu, H. Z.; Li, X. H.; Feng, W.; Deng, P.   C.; Yuan, L. H.*; Gong, B., Alternative strategy for adjusting the   association specificity of hydrogen-bonded duplexes, Org. Lett.,   2011, 13, 54-57.

29. Zeng, J. S.; Wang, W.; Deng, P. C.; Feng, W.; Zhou, J.   J.; Yang, Y. Y.; Yuan, L. H.*; Yamato, K.; Gong, B.*, Interplay of   olefin metathesis and multiple hydrogen bonding interactions: Covalently   cross-linked zippers, Org. Lett., 2011, 13,   3798-3801.

30. Li, X. H.; Fang, Y. Y.; Deng, P. C.; Feng, W.; Hu, J.   C.; Li, T.; Yuan, L. H.*, Self-complementary quadruply hydrogen-bonded   duplexes based on imide and urea units, Org. Lett., 2011,   13, 4628-4631.

31. Yuan, L. H.*; Zhang,P. H.; Feng,   W.; Gong, B*, Hydrogen-bonded oligoamide duplexes as programmable molecular   recognition units: A systematic approach towards directed self-assembly and   controlled non-covalent synthesis, Curr. Org. Chem., 2011,   15, 1250-1265.

32. Cao, R. K.; Zhou, J. J.; Wang, W.; Feng, W.; Li, X. H.;   Zhang, P. H.; Deng, P. C.; Yuan, L. H.*; Gong, B.*, Oligoamide   duplexes as organogelators, Org. Lett., 2010, 12,   2958-2961.

33. Feng, W.; Yamato, K.; Yang, L. Q.; Ferguson, J. S.;   Zhong, L. J.; Zou, S. L.; Yuan, L. H.*; Zeng, X. C.* and Gong, B.*,   Efficient kinetic macrocyclization, J. Am. Chem. Soc., 2009,   131, 2629-2637.

34. Yang, L. Q.; Zhong, L. J.; Yamato, K.; Zhang, X. H.;   Feng, W.; Deng, P. C., Yuan, L. H.*; Zeng, X. C.* and Gong, B.*,   Aromatic oligoamide macrocycles from the bimolecular coupling of folded   oligomeric precursors, New J. Chem., 2009, 33,   729-733.

授权专利:

1.袁立华、吴雷、冯文、方玉宇、杨心师,一种酰胺荚醚修饰的柱[5]芳烃衍生物及其制备方法和应用,专利号:ZL 201310550276.2

2. 袁立华,杨晓勇,刘洪乐,冯文,罗凯,吴勇,一种从含酸敏感基团化合物制备全氟烯醚的方法,专利号:ZL 200810046269.8

3. 袁立华,冯文,岳亚荣,张鹏辉,张路,杨永安,蒲文臣,2,7-二羟基-3,6-萘二酸的制备方法,专利号:ZL 200910167604.4

4. 袁立华,钟利健,冯文,陈龙,含三中心氢键的环芳酰胺萃取剂在分离稀土元素中的应用,专利号:ZL 201010595583.9

5. 冯文、方玉宇、袁立华、吴雷、陈龙,一种氧化膦修饰的柱[5]芳烃衍生物及其应用,专利号:ZL 201310033390.8

 

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