四川大学化学学院
师资力量

伍晚花     副教授

研究方向:分子光化学与光物理;光子能量上转换;超分子光化学;主客体作用;分子识别与传感;金属配合物等

联系方式:028-85416297;18780161648          Email:wuwanhua@scu.edu.cn; wuwanhua.510@163.com

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简历:

2019.06—至今      四川大学“双百人才工程”百人计划

2016.10—至今      副教授, 四川大学 化学学院

2014.01—2016.09    讲师,四川大学化学学院

2013.06—2013.12    研究助理,四川大学化学学院杨成教授课题组

2008.09—2013.06    博士,大连理工大学精细化工国家重点实验室

2004.09—2008.07    学士,大连理工大学化工学院

 

主要研究方向:

 

有机化学,光化学,光谱学

 

主要工作业绩

 

主要从事分子光化学与光物理、超分子化学方面的研究工作,重点研究通过分子光物理性质优化与超分子组装的方法来控制三线态-三线态湮灭上转换、光化学反应和分子传感等有机光化学与光物理行为。目前共sci研究80余篇,作为第一作者或通讯作者发表论文40篇,篇最高被引次数200余次。作为项目负责人主持国家自然科学基金面上项目、自然科学基金青年项目等省部级以上项目10

 

主持项目:

1. 国家自然科学基金面上项目,21971169,超分子组装提高TTA上转换效率的研究,2020.1-2023.1265万(直接经费),项目负责人

2. 四川大学青年科技学术带头人培育项目  35万,项目负责人

3. 四川省科技厅,2019YJ0090,超分子功能化三线态湮灭剂的合成与应用,2019.01-2020.1210万,项目负责人

4. 四川大学创新火花项目,2018SCUH0014,新型超分子三线态湮灭剂的组装行为对上转换发光的影响,2018.01-2020.1222万,项目负责人

5. 中国博士后面上基金,2017M612957,超分子自组装效应在三重态湮灭上转换中的应用研究,2017.1—2018.5,5 万,项目负责人

6. 四川省博士后科研项目特别资助(一等),10 万,项目负责人

7. 中国博士后基金特别资助,2018T110968,利用超分子组装体实现固相高效三重态湮灭上转换的研究,2018.02-2019.02, 15 万,项目负责人

8. 大连理工大学精细化工国家重点实验室开放课题,KF1508, 复合超分子主体用于提高三重态湮灭上转换效率的研究,2015.12-2018.035 万,主持

9. 国家自然科学基金-青年科学基金,21402129,超分子作用诱导的高效三重态湮灭光子上转换体系的研究,2015.01-2017.1225万,项目负责人

10. 四川大学青年教师科研启动基金,2014SCU11051,三重态光敏剂与受体一体化的高效TTA上转换体系的研究,2014.04-2015.129万,项目负责人

 

 

发表论文:

 

[40] Supramolecular spectral/visual detection of urinary polyamines through synergetic/competitive complexation with gamma-CD and CB[7]

Tian Haoyu; Yu Xingke; Yao Jiabin; Gao Guowei; Wu Wanhua*; Yang Cheng*.

Chem. Commun. 2021, 57 (14), 1806-1809.

 

[39] Guest-Binding-Induced Interhetero Hosts Charge Transfer Crystallization: Selective Coloration of Commonly Used Organic Solvents.

Mi Yan; Ma Jingyu; Liang Wenting; Xiao Chao; Wu Wanhua*; Zhou Dayang; Yao Jiabin; Sun Wenjia; Sun Junliang*; Gao Guowei; Chen Xiaochuan; Chruma J. Jason; Yang Cheng*

J. Am. Chem. Soc. 2021, 143 (3), 1553-1561.

 

[38] Trace mild acid-catalysed Z → E isomerization of norbornene-fused stilbene derivatives: intelligent chiral molecular photoswitches with controllable self-recovery.

Hao Taotao; Yang Yongsheng; Liang Wenting; Fan Chunying; Wang Xin; Wu Wanhua*; Chen Xiaochuan; Fu Haiyan*; Chen Hua; Yang Cheng*.

Chemical science 2021, 12 (7), 2614-2622.

 

[37] A dendritic DPA annihilator—syntheses, photophysical properties and application for co-assembling enhanced triplet-triplet annihilation upconversion.

Guo Qian; Li Guojuan; Rao Ming; Wei Lingling; Gao Fanrui; Wu Wanhua*; Yang Qingshan*; Cheng Guo*; Yang Cheng*

Dyes and Pigments 2020, 182, 108643

 

[36] pH-Controlled Chirality Inversion in Enantiodifferentiating Photocyclodimerization of 2-Antharacenecarboxylic Acid Mediated by gamma-Cyclodextrin Derivatives.

Kanagaraj Kuppusamy; Liang Wenting; Rao Ming; Yao Jiabin; Wu Wanhua*; Cheng Guo; Ji Jiecheng; Wei Xueqing; Peng Chao; Yang Cheng*.

Org Lett 2020, 22 (14), 5273-5278.

 

[35] Synergetic effects in the enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by beta-cyclodextrin-pillar[5]arene-hybridized hosts.

Ji Jiecheng; Wu Wanhua*; Wei Xueqing; Rao Ming; Zhou Dayang; Cheng Guo; Gong Qiyong; Luo Kui*; Yang Cheng*

Chemical communications 2020, 56 (46), 6197-6200.

 

[34] Pyrene-tiaraed pillar[5]arene: Strong intramolecular excimer emission applicable for photo-writing.

Peng Chao; Liang Wenting; Ji Jiecheng; Fan Chunying; Kanagaraj Kuppusamy; Wu Wanhua*; Cheng Guo; Su Dan; Zhong Zhihui; Yang Cheng*

Chinese Chemical Letters 2021, 32 (1), 345-348.

 

 

[33] A Quinoline-Appended Cyclodextrin Derivative as a Highly Selective Receptor and Colorimetric Probe for Nucleotides

Kanagaraj Kuppusamy; Xiao Chao; Rao Ming; Fan Chunying; Borovkov Victor*; Cheng Guo; Zhou Dayang; Zhong Zhihui; Su Dan; Yu Xingke; Yao Jiabin; Hao Taotao; Wu Wanhua*; Chruma J. Jason; Yang Cheng*

iScience 2020, 23, 100927.

 

[32] Fulleropillar[4]arene: The Synthesis and Complexation Properties.

Mi Yan; Yao Jiabin; Ma Jingyu; Dai Ling; Xiao Chao; Wu Wanhua*; Yang Cheng*,

Org Lett 2020, 22, 2118-2123. (封面文)

 

[31] Supramolecular enantiomeric and structural differentiation of amino acid derivatives with achiral pillar[5]arene homologs.

Ji Jiecheng; Li Yizhou; Xiao Chao; Cheng Guo; Luo Kui; Gong Qiyong; Zhou Dayang; Chruma J. Jason; Wu Wanhua*; Yang Cheng*

Chem. Commun. 2020, 56, 161-164

 

[30] Efficient Triplet-Triplet Annihilation Upconversion with an Anti-Stokes Shift of 1.08 eV Achieved by Chemically Tuning Sensitizers.

Chunying Fan, Lingling Wei, Tong Niu, Ming Rao, Guo Cheng, Jason J. Chruma, Wanhua Wu*, and Cheng Yang*.

J. Am. Chem. Soc. 2019, 141, 15070−15077. DOI:10.1021/jacs.9b05824

 

[29] Precise Manipulation of Temperature‐Driven Chirality Switching of Molecular Universal Joints through Solvent Mixing.  

Chunying Fan, Jiabin Yao, Guojuan Li, ChengGuo, WanhuaWu*, Dan Su, Zhihui Zhong, Dayang Zhou, Yuliang Wang, Jason J. Chruma, and Cheng Yang*.

Chem. Eur. J. 2019, 25, 12526-12537. DOI: 10.1002/chem.201902676

 

 


[28] Effects of Temperature and Host Concentration on the Supramolecular Enantiodifferentiating [4 + 4] Photodimerization of 2-Anthracenecarboxylate through Triplet-Triplet Annihilation Catalyzed by Pt-Modified Cyclodextrins

Ming Rao, Wanhua Wu*, Cheng Yang*.

Molecules, 2019, 24, 1502. DOI: https://doi.org/10.3390/molecules24081502




[27] Resolution and Racemization of a Planar-Chiral A1/A2-Disub-stituted Pillar[5]arene

Chao Xiao, Wenting Liang, Wanhua Wu*, Kuppusamy Kanagaraj, Yafen Yang, Ke Wen, Cheng Yang*.



  Symmetry, 2019,  11, 773.  DOI: https://www.mdpi.com/2073-8994/11/6/773

[26] Synthesis, enantioseparation and photophysical properties of planar-chiral pillar [5] arene derivatives bearing fluorophore fragments. 

Guojuan Li, Chunying Fan, Guo Cheng, Wanhua Wu* and Cheng Yang*.

Beilstein J. Org. Chem. 2019, 15, 1601-1611. DOI:10.3762/bjoc.15.164

 

[25]Assembly-enhanced triplet-triplet annihilation upconversion in the aggregation formed by Schiff-base Pt (II) complex grafting-permethyl-β-CD and 9, 10-diphenylanthracence dimer.   

Hongxia Lai, Ting Zhao, Yurong Deng, Chunyin Fan, Wanhua Wu*, Cheng Yang*.

Chin. Chem. Lett. 2019, 30, 1979-1983.

 

 

 

[24] A BODIPY- based near infrared fluorescent probe for Fe3+ in water

Jiecheng Ji, Syama S. Chereddy, Yi Ren, Xingming Chen, Dan Su, Zhihui Zhong, Tadashi Mori, Yoshihisa Inoue*, Wanhua Wu* and Cheng Yang*,

J. Photochem. Photobiol. A 2018, 355, 78. DOI.org/10.1016/j.jphotochem.2017.10.043




[23]  Supramolecular Photochirogenesis Driven by Higher-Order Complexation: Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylate to Slipped Cyclodimers via a 2: 2 Complex with β-Cyclodextrin

Xueqin Wei#, Wanhua Wu#, Ryohei Matsushita#, Zhiqiang Yan#, Dayang Zhou, Jason J. Chruma, Masaki Nishijima, Gaku Fukuhara, Tadashi Mori, Yoshihisa Inoue*, and Cheng Yang*., 

J. Am. Chem. Soc., 2018, 140, 3959. DOI: 10.1021/jacs.7b12085



[22] 聚集体中的三重-三重转换.

范春英; 伍晚花*; *, 

有机化学,  2018, 38, 1377. DOI: 10.6023/cjoc201712034


[21]  Enhanced Chiral Recognition by γ-Cyclodextrin-Cucurbit [6] uril-Cowheeled [4] Pseudorotaxanes. 

Ling Dai#, Wanhua Wu#, Wenting Liang, Wentong Chen, Xingke Yu, Jiecheng Ji, Chao Xiao and Cheng Yang. 

Chem. Commun. 2018, 54, 2643-2646. DOI: 10.1039/c8cc00840j




[20]  Switched enantioselectivity by solvent components and temperature in photocyclodimerization of 2-anthracenecarboxylate with 6A,6X-diguanidio−γ-cyclodextrins

Jigao Yi, Wenting Liang, Xueqin Wei, Jiabin Yao, Zhiqiang Yan, Dan Sua, Zhihui Zhong, Guowei Gao, Wanhua Wu*, Cheng Yang*

Chin. Chem. Lett., 2018, 29, 87-90. DOI: 10.1016/j.cclet.2017.05.004




[19] Photocatalytic Supramolecular Enantiodifferentiating Dimerization of 2‑Anthracenecarboxylic Acid through Triplet−Triplet Annihilation.

Ming Rao, Kuppusamy Kanagaraj, Chunying Fan, Jiecheng Ji, Chao Xiao, Xueqin Wei, Wanhua Wu* and Cheng Yang*, 

Org. Lett2018, 20, 1680−1683. DOI: 10.1021/ acs.orglett.8b00520


  


[18] Supramolecular Assembly‐Improved Triplet–Triplet Annihilation Upconversion in Aqueous Solution

Wei Xu, Wenting Liang, Wanhua Wu*, Chunying Fan, Ming Rao, Dan Su, Zhihui Zhong, Cheng Yang*

Chem. Eur. J., 2018, 24, 16677. DOI: 10.1002/chem.201804001



 


[17]   Induced chirality sensing through formation and aggregation of the chiral imines double winged with pyrenes or perylenes

Jianlin Wu, Wenting Liang, Tong Niu, Wanhua Wu*, Dahui Zhou, Chunying Fan, Jiecheng Ji, Guowei Gao*, Jian Meng, Cheng Yang* 

Chem. Commun. 2018, 54, 9206. DOI:10.1039/C8CC03660H




[16] Temperature-Driven Planar Chirality Switching of a Pillar[5]arene-Based Molecular Universal Joint. Jiabin Yao#, Wanhua Wu#, Wenting Liang, Yujun Feng, Dayang Zhou, Jason J. Chruma, Gaku Fukuhara, Tadashi Mori, Yoshihisa Inoue, Cheng Yang*

Angew. Chem., Int. Ed. 2017, 56 (24), 6869-6873.

 

 

 

 

[15] Enhanced Triplet-Triplet Energy Transfer and Upconversion Fluorescence through Host-Guest Complexation.

Chunying Fan#, Wanhua Wu#, Jason J. Chruma, Jianzhang Zhao, Cheng Yang,

J. Am. Chem. Soc. 2016, 138, 15405-15412.

 

 

[14] Recent advance of photochromic diarylethenes-containing supramolecular systems.

Chao Xiao, Weiye Zhao, Dayang Zhou, Yan Huang, Ye Tao, Wanhua Wu*, Cheng Yang*,

Chin. Chem. Lett. 2015, 26, 817-824.

 

[13] Red-light excitable fluorescent platinum(ii) bis(aryleneethynylene) bis(trialkylphosphine) complexes showing long-lived triplet excited states as triplet photosensitizers for triplet-triplet annihilation upconversion.

Wanhua Wu, Jianzhang Zhao, Jifu Sun, Ling Huang, Xiuyu Yi,

J. Mater. Chem. C 2013, 1 (4), 705-716.

 

[12] Observation of the room temperature phosphorescence of Bodipy in visible light-harvesting Ru(ii) polyimine complexes and application as triplet photosensitizers for triplet-triplet-annihilation upconversion and photocatalytic oxidation.

Wanhua Wu, Jifu Sun, Xiaoneng Cui, Jianzhang Zhao*

J. Mater. Chem. C 2013, 1 (30), 4577-4589.

 

[11] Red-light-absorbing diimine Pt(II) bisacetylide complexes showing near-IR phosphorescence and long-lived 3IL excited state of Bodipy for application in triplet-triplet annihilation upconversion.

Wanhua Wu, Lianlian Liu, Xiaoneng Cui, Caishun Zhang, Jianzhang Zhao.

Dalton Trans. 2013, 42 (40), 14374-14379.

 

[10] Hetero Bodipy-dimers as heavy atom-free triplet photosensitizers showing a long-lived triplet excited state for triplet-triplet annihilation upconversion.

Wanhua Wu, Xiaoneng Cui, Jianzhang Zhao*,

Chem. Commun. 2013, 49 (79), 9009-9011.

 

[9] Light-Harvesting Fullerene Dyads as Organic Triplet Photosensitizers for Triplet-Triplet Annihilation Upconversions.

Wanhua Wu, Jianzhang Zhao*, Jifu Sun, Song Guo.

J. Org. Chem. 2012, 77 (12), 5305-5312.

 

[8] Long-lived room-temperature near-IR phosphorescence of BODIPY in a visible-light-harvesting N(caret)C(caret)N PtII-acetylide complex with a directly metalated BODIPY chromophore.

Wanhua Wu, Jianzhang Zhao*, Huimin Guo, Jifu Sun, Shaomin Ji, Zilong Wang,

Chem. - Eur. J. 2012, 18 (7), 1961-1968

 

[7] Ruthenium(II)-Polyimine-Coumarin Light Harvesting Molecular Arrays: Design Rationale and Application for Triplet-Triplet-Annihilation-Based Upconversion.

Wanhua Wu, Shaomin Ji, Wenting Wu, Jinyin Shao, Huimin Guo, Tony D. James, Jianzhang Zhao*,

Chem. - Eur. J. 2012, 18 (16), 4953-4964

 

[6] Development of triplet-triplet annihilation upconversion.

Wanhua Wu, Song Guo, Jianzhang Zhao*

Zhongguo Kexue: Huaxue 2012, 42 (10), 1381-1398.

 

[5] Tuning the emission property of carbazole-caped cyclometalated platinum(II) complexes and its application for enhanced luminescent oxygen sensing.

Wanhua Wu, Wenting Wu, Shaomin Ji, Huimin Guo, Jianzhang Zhao*.

J. Organomet. Chem. 2011, 696 (11-12), 2388-2398.

 

[4] Tuning the emissive triplet excited states of platinum(II) Schiff base complexes with pyrene, and application for luminescent oxygen sensing and triplet-triplet-annihilation based upconversions.

Wanhua Wu, Jifu Sun, Wenting Wu, Jianzhang Zhao*, Huimin Guo.

Dalton Trans. 2011, 40 (43), 11550-11561.

 

[3] Organic Triplet Sensitizer Library Derived from a Single Chromophore (BODIPY) with Long-Lived Triplet Excited State for Triplet-Triplet Annihilation Based Upconversion.

Wanhua Wu, Huimin Guo, Wenting Wu, Shaomin Ji, Jianzhang Zhao*.

J. Org. Chem. 2011, 76 (17), 7056-7064.

 

[2] Tuning the emission properties of cyclometalated platinum(II) complexes by intramolecular electron-sink/arylethynylated ligands and its application for enhanced luminescent oxygen sensing.

Wanhua Wu, Wenting Wu, Shaomin Ji, Huimin Guo, Peng Song, Keli Han, Lina Chi, Jinyin Shao, Jianzhang Zhao*.

J. Mater. Chem. 2010, 20 (43), 9775-9786.

 

[1] Enhanced luminescence oxygen sensing property of Ru(II) bispyridine complexes by ligand modification.

Wanhua Wu, Shaomin Ji, Wenting Wu, Huimin Guo, Xin Wang, Jianzhang Zhao*, Zhonggang Wang,

Sens. Actuators, B 2010, 149 (2), 395-406.

 

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