四川大学化学学院
师资力量

伍晚花     副教授

研究方向:有机化学

联系方式:028-85416297;18780161648          Email:wuwanhua@scu.edu.cn; wuwanhua.510@163.com

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简历

2019.06—至今四川大学“双百人才工程”百人计划

2016.10—至今副教授,四川大学化学学院

2014.01—2016.09      讲师,四川大学化学学院

2013.06—2013.12      研究助理,四川大学化学学院杨成教授课题组

2008.09—2013.06      博士,大连理工大学精细化工国家重点实验室

2004.09—2008.07      学士,大连理工大学化工学院

主要研究方向

超分子光化学与光物理;金属配合物;三重态-三重态湮灭上转换;光催化

主要工作业绩

   主要从事三重转换光敏光物理性研究及主客体作用用于提高上转换效率的研究。目前共sci研究60余篇,作为第一作者或通讯作者发表论文30篇,篇最高被引次数200余次。作为项目负责人主持国家自然科学基金面上项目、自然科学基金青年项目等省部级以上项目9

主持项目:

1.国家自然科学基金面上项目,21971169,超分子组装提高TTA上转换效率的研究,2020.1-2023.1265万(直接经费),项目负责人

2. 四川省科技厅,2019YJ0090,超分子功能化三线态湮灭剂的合成与应用,2019.01-2020.1210万,项目负责人

3. 四川大学创新火花项目,2018SCUH0014,新型超分子三线态湮灭剂的组装行为对上转换发光的影响,2018.01-2020.1222万,项目负责人

4.中国博士后面上基金,2017M612957,超分子自组装效应在三重态湮灭上转换中的应用研究,2017.1—2018.5,5   万,项目负责人

5. 四川省博士后科研项目特别资助(一等),10 万,项目负责人

6.中国博士后基金特别资助,2018T110968,利用超分子组装体实现固相高效三重态湮灭上转换的研究,2018.02-2019.02,   15 万,项目负责人

7. 大连理工大学精细化工国家重点实验室开放课题,KF1508, 复合超分子主体用于提高三重态湮灭上转换效率的研究,2015.12-2018.035 万,主持

8.国家自然科学基金-青年科学基金,21402129,超分子作用诱导的高效三重态湮灭光子上转换体系的研究,2015.01-2017.1225万,项目负责人

9.四川大学青年教师科研启动基金,2014SCU11051,三重态光敏剂与受体一体化的高效TTA上转换体系的研究,2014.04-2015.129万,项目负责人

代表性成果 (获奖成果、专著、论文、专利)

 发表论文:

[30] Efficient   Triplet-Triplet Annihilation Upconversion with an Anti-Stokes Shift of 1.08   eV Achieved by Chemically Tuning Sensitizers.

Chunying Fan, Lingling Wei, Tong Niu, Ming Rao, Guo Cheng,   Jason J. Chruma, Wanhua Wu*, and Cheng Yang*.

J. Am.   Chem. Soc. 2019, 141, 15070−15077.DOI:10.1021/jacs.9b05824

 

[29]Precise Manipulation of Temperature‐Driven   Chirality Switching of Molecular Universal Joints through Solvent   Mixing.  

Chunying Fan, Jiabin Yao, Guojuan Li,   ChengGuo, WanhuaWu*, Dan Su, ZhihuiZhong, DayangZhou, YuliangWang,   Jason J. Chruma, and Cheng Yang*.

Chem. Eur. J.2019, 25,12526-12537.DOI:   10.1002/chem.201902676

 




 

 


 

 

 

 


 
[28] Effects of Temperature and Host Concentration on   the Supramolecular Enantiodifferentiating [4 + 4] Photodimerization of   2-Anthracenecarboxylate through Triplet-Triplet Annihilation Catalyzed by   Pt-Modified Cyclodextrins

Ming Rao, Wanhua Wu*, Cheng Yang*.

Molecules, 2019,   24, 1502. DOI: https://doi.org/10.3390/molecules24081502


   

 
 
 

[27] Resolution   and Racemization of a Planar-Chiral A1/A2-Disub-stituted Pillar[5]arene

Chao Xiao, Wenting Liang, Wanhua Wu*, Kuppusamy   Kanagaraj, Yafen Yang, Ke Wen, Cheng Yang*. 

 





  Symmetry, 2019, 11, 773. DOI: https://www.mdpi.com/2073-8994/11/6/773

 

 

 

[26]Synthesis,   enantioseparation and photophysical properties of planar-chiral pillar [5]   arene derivatives bearing fluorophore fragments. 

Guojuan Li, Chunying Fan, Guo Cheng, Wanhua Wu* and   Cheng Yang*.

Beilstein J. Org. Chem.2019, 15,   1601-1611.DOI:10.3762/bjoc.15.164

 

 

[25]Assembly-enhanced   triplet-triplet annihilation upconversion in the aggregation formed by   Schiff-base Pt (II) complex grafting-permethyl-β-CD and 9,   10-diphenylanthracencedimer. 

HongxiaLai,TingZhao,YurongDeng,ChunyinFan,WanhuaWu*,ChengYang*.

Chin. Chem. Lett.2019, DOI:   doi.org/10.1016/j.cclet.2019.09.009

 

TOC-图片3.jpg

 

 

[24] A BODIPY- based near infrared fluorescent probe for Fe3+ in   water

Jiecheng Ji, Syama S. Chereddy, Yi Ren, Xingming Chen, Dan Su,   Zhihui Zhong, Tadashi Mori, Yoshihisa Inoue*, Wanhua Wu* and Cheng   Yang*,

J. Photochem. Photobiol. A2018, 355, 78. DOI.org/10.1016/j.jphotochem.2017.10.043


 

 
 
[23]  Supramolecular   Photochirogenesis Driven by Higher-Order Complexation: Enantiodifferentiating   Photocyclodimerization of 2-Anthracenecarboxylate to Slipped Cyclodimers via   a 2: 2 Complex with β-Cyclodextrin

Xueqin Wei#, Wanhua Wu#, Ryohei   Matsushita#, Zhiqiang Yan#, Dayang Zhou, Jason J.   Chruma, Masaki Nishijima, Gaku Fukuhara, Tadashi Mori, Yoshihisa Inoue*, and   Cheng Yang*., 

J. Am. Chem. Soc., 2018, 140, 3959. DOI:   10.1021/jacs.7b12085


 

 
 


 
[22] 聚集体中的三重-三重转换.

范春英; 伍晚花*; *, 

有机化学,  2018, 38,   1377. DOI: 10.6023/cjoc201712034
 
 
 
[21]  Enhanced Chiral Recognition by   γ-Cyclodextrin-Cucurbit [6] uril-Cowheeled [4] Pseudorotaxanes. 

Ling   Dai#, Wanhua Wu#, Wenting Liang, Wentong Chen,   Xingke Yu, Jiecheng Ji, Chao Xiao and Cheng Yang. 

Chem.   Commun. 2018,54, 2643-2646. DOI: 10.1039/c8cc00840j


 


 
 
[20]  Switched   enantioselectivity by solvent components and temperature in   photocyclodimerization of 2-anthracenecarboxylate with 6A,6X-diguanidio−γ-cyclodextrins

Jigao   Yi, Wenting Liang, Xueqin Wei, Jiabin Yao, Zhiqiang Yan, Dan Sua, Zhihui   Zhong, Guowei Gao, Wanhua Wu*, Cheng Yang*

Chin. Chem.   Lett., 2018, 29, 87-90. DOI: 10.1016/j.cclet.2017.05.004


 


 
 
[19] Photocatalytic   Supramolecular Enantiodifferentiating Dimerization of 2‑Anthracenecarboxylic   Acid through Triplet−Triplet Annihilation.

Ming   Rao, Kuppusamy Kanagaraj, Chunying Fan, Jiecheng Ji, Chao Xiao, Xueqin Wei, Wanhua   Wu* and Cheng Yang*, 

Org. Lett2018,   20, 1680−1683. DOI: 10.1021/acs.orglett.8b00520


    


 
[18] Supramolecular Assembly‐Improved   Triplet–Triplet Annihilation Upconversion in Aqueous Solution

Wei   Xu, Wenting Liang, Wanhua Wu*, Chunying Fan, Ming Rao, Dan Su, Zhihui   Zhong, Cheng Yang*

Chem. Eur. J.,2018, 24, 16677. DOI:   10.1002/chem.201804001


 

   

 
 


 
[17]   Induced chirality sensing   through formation and aggregation of the chiral imines double winged with   pyrenes or perylenes

Jianlin   Wu, Wenting Liang, Tong Niu, Wanhua Wu*, Dahui Zhou, Chunying Fan,   Jiecheng Ji, Guowei Gao*, Jian Meng, Cheng Yang* 

Chem.   Commun.2018,   54, 9206. DOI:10.1039/C8CC03660H


 

 
 

 

 

[16] Temperature-Driven Planar Chirality Switching of a   Pillar[5]arene-Based Molecular Universal Joint.Jiabin Yao#, Wanhua Wu#, Wenting   Liang, Yujun Feng, Dayang Zhou, Jason J. Chruma, Gaku Fukuhara, Tadashi Mori,   Yoshihisa Inoue, Cheng Yang*

Angew.   Chem., Int. Ed. 2017, 56 (24), 6869-6873.

 

 

 

 

[15]Enhanced Triplet-Triplet   Energy Transfer and Upconversion Fluorescence through Host-Guest   Complexation.

Chunying Fan#,Wanhua Wu#, Jason   J. Chruma,Jianzhang Zhao,Cheng Yang,

J. Am. Chem. Soc.2016, 138, 15405-15412.

 

 

[14] Recent advance of photochromic diarylethenes-containing   supramolecular systems.

Chao Xiao, Weiye Zhao, Dayang Zhou, Yan Huang, Ye Tao, Wanhua   Wu*, Cheng Yang*,

Chin. Chem. Lett.2015, 26, 817-824.

 

[13] Red-light excitable   fluorescent platinum(ii) bis(aryleneethynylene) bis(trialkylphosphine)   complexes showing long-lived triplet excited states as triplet   photosensitizers for triplet-triplet annihilation upconversion.

Wanhua Wu, Jianzhang Zhao, Jifu Sun, Ling Huang, Xiuyu Yi,

J. Mater. Chem. C2013, 1 (4), 705-716.

 

[12] Observation of the room   temperature phosphorescence of Bodipy in visible light-harvesting Ru(ii)   polyimine complexes and application as triplet photosensitizers for   triplet-triplet-annihilation upconversion and photocatalytic oxidation.

Wanhua Wu, Jifu Sun, Xiaoneng Cui, Jianzhang Zhao*

J. Mater. Chem. C 2013, 1 (30),   4577-4589.

 

[11] Red-light-absorbing   diimine Pt(II) bisacetylide complexes showing near-IR phosphorescence and   long-lived 3IL excited state of Bodipy for application in triplet-triplet   annihilation upconversion.

Wanhua Wu, Lianlian Liu, Xiaoneng Cui, Caishun Zhang, Jianzhang Zhao.

Dalton Trans. 2013, 42 (40),   14374-14379.

 

[10] Hetero Bodipy-dimers as   heavy atom-free triplet photosensitizers showing a long-lived triplet excited   state for triplet-triplet annihilation upconversion.

Wanhua Wu, Xiaoneng Cui, Jianzhang Zhao*,

Chem. Commun. 2013, 49 (79),   9009-9011.

 

[9] Light-Harvesting Fullerene Dyads as Organic Triplet   Photosensitizers for Triplet-Triplet Annihilation Upconversions.

Wanhua Wu, Jianzhang Zhao*, Jifu Sun, Song Guo.

J. Org. Chem.2012, 77 (12), 5305-5312.

 

[8] Long-lived room-temperature near-IR phosphorescence of   BODIPY in a visible-light-harvesting N(caret)C(caret)N PtII-acetylide complex   with a directly metalated BODIPY chromophore.

Wanhua Wu, Jianzhang Zhao*, Huimin Guo, Jifu Sun, Shaomin Ji,   Zilong Wang,

Chem. - Eur. J. 2012,18 (7), 1961-1968

 

[7] Ruthenium(II)-Polyimine-Coumarin Light Harvesting Molecular   Arrays: Design Rationale and Application for Triplet-Triplet-Annihilation-Based   Upconversion.

Wanhua Wu, Shaomin Ji, Wenting Wu, Jinyin Shao, Huimin Guo, Tony   D. James, Jianzhang Zhao*,

Chem. - Eur. J. 2012,18 (16), 4953-4964

 

[6] Development of triplet-triplet annihilation upconversion.

Wanhua Wu, Song Guo, Jianzhang Zhao*

Zhongguo Kexue: Huaxue2012,42 (10),   1381-1398.

 

[5]Tuning the emission property of carbazole-caped   cyclometalated platinum(II) complexes and its application for enhanced   luminescent oxygen sensing.

Wanhua Wu, Wenting Wu, Shaomin Ji, Huimin Guo, Jianzhang Zhao*.

J. Organomet. Chem.2011,696 (11-12), 2388-2398.

 

[4] Tuning the emissive triplet excited states of platinum(II)   Schiff base complexes with pyrene, and application for luminescent oxygen   sensing and triplet-triplet-annihilation based upconversions.

Wanhua Wu,Jifu Sun, Wenting Wu, Jianzhang Zhao*, Huimin Guo.

Dalton Trans.2011,40 (43), 11550-11561.

 

[3]Organic Triplet Sensitizer Library Derived from a Single   Chromophore (BODIPY) with Long-Lived Triplet Excited State for   Triplet-Triplet Annihilation Based Upconversion.

Wanhua Wu, Huimin Guo, Wenting Wu, Shaomin Ji, Jianzhang Zhao*.

J. Org. Chem.2011, 76 (17), 7056-7064.

 

[2]Tuning the emission properties of cyclometalated platinum(II)   complexes by intramolecular electron-sink/arylethynylated ligands and its   application for enhanced luminescent oxygen sensing.

Wanhua Wu, Wenting Wu, Shaomin Ji, Huimin Guo, Peng Song, Keli   Han, Lina Chi, Jinyin Shao, Jianzhang Zhao*.

J. Mater. Chem.2010,20 (43), 9775-9786.

 

[1]Enhanced luminescence oxygen sensing property of Ru(II)   bispyridine complexes by ligand modification.

Wanhua Wu, Shaomin Ji, Wenting Wu, Huimin Guo, Xin Wang,   Jianzhang Zhao*, Zhonggang Wang,

Sens. Actuators, B2010,149 (2), 395-406.

 

 

 

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