主要研究方向

环境友好高分子材料 

聚合反应新方法 

有机催化不对称反应 

办公室： 第一理科楼北208 

课题组诚招副教授一名，长期招收博士后、博士、硕士研究生、研究助理、以及联合培养学生，同时欢迎各学科背景本科生利用课余时间从事科研项目，完成毕业论文等。

主要工作业绩

朱剑波博士，四川大学化学学院特聘研究员，博士生导师，环保型高分子材料国家地方联合实验室固定成员，入选第十五批海外高层次人才项目青年项目。在攻读博士学位期间，主要从事主族化学研究，首次实现了膦催化环丙烷化反应；博士后工作期间，针对废旧塑料污染问题，发展了一类基于五元环内酯的高性能可化学回收高分子材料，该研究为解决废旧塑料回收问题提供新的途径；同时，采用路易斯酸碱对作为催化剂，成功实现内消旋丙交酯高效定量转化为工业上更有经济价值的外消旋丙交酯。相关成果以第一作者身份发表在Science、J. Am. Chem. Soc.、Angew.Chem. Int. Ed.、ACS Catal、Chem. Commun.等国际学术期刊上。其中可完全回收聚酯工作(Science2018, 360, 398-403) 被美国化学与工程新闻杂志(C&EN)选为2018年年度成果(Selected as the Research of the Year 2018 by C&EN)。

代表性成果 (获奖成果、专著、论文、专利)

1. Zhu, J.-B.; Chen, E. Y.-X.*  Catalyst-Sidearm-Induced   Stereoselectivity Switching in Polymerization of a Racemic Lactone for   Stereocomplexed Crystalline Polymer with a Circular Life Cycle ", Angew.   Chem. Int. Ed. 2019, 58, 1178-1182. 

2. Zhu, J.-B.; Chen, E. Y.-X.* Living Coordination   Polymerization of a Six‐Five Bicyclic Lactone to Produce Completely   Recyclable Polyester, Angew. Chem. Int. Ed. 2018, 57,   12588-12562.

3. Zhu, J.-B.; Watson, E. M.; Tang, J.;   Chen, E. Y.-X.*"A Synthetic Polymer System with Repeatable Chemical   Recyclability ", Science 2018, 360, 398-403.   Highlighted by Science (Plastics recycling with a difference)，Science News (This   plastic can be recycled over and over and over again), C&EN (Strong, stable polymer can be recycled   again and again) and The Times (New ‘infinitely recyclable’   plastic created); Selected as the Research of the Year 2018 by C&EN!

4. Zhu, J.-B.; Tang, X.; Falivene, L.;* Caporaso,   L.; Cavallo, L.; Chen, E. Y.-X.* "Organocatalytic Coupling of   Bromo-Lactide with Cyclic Ethers and Carbonates to Chiral Bromo-Diesters: NHC   or Anion Catalysis?", ACS Catal. 2017, 7, 3929-3933.

5. Zhu, J.-B.; Chen, E. Y.-X.* "From   meso-Lactide to Isotactic Polylactide: Epimerization by B/N Lewis Pairs and   Kinetic Resolution by Organic Catalysts", J. Am. Chem. Soc. 2015,   137, 12506-12509.

6. Zhu, J.-B.; Chen, H.; Liao, S.; Li, Y.-X.; Tang,   Y*. A sidearm-assisted phosphine for catalytic ylide intramolecular   cyclopropanation. Org. Chem. Front. 2014, 1, 1035-1039.

7. Zhu, J.-B.; Chen, H.; Wang, L.; Tang, Y*.   Stereospecific synthesis of highly functionalized benzo[3.1.0]bicycloalkanes   via multistep cascade reactions. Org. Chem. Front. 2014, 1,   965-968.

8. Zhu, J.-B.; Wang, P.; Liao, S.; Tang, Y*. Ylide   hydrolysis in tandem reactions: a highly Z/E-selective access to   3-alkylidene dihydrobenzofurans and related analogues. Org. Lett. 2013,   12, 3054-3057.

9. Zhu, J.-B.; Wang, P.; Liao, S.; Tang,   Y*. PPh3-mediated intramolecular conjugation of alkyl halides with   electron-deficient olefins: facile synthesis of   chromans and relevant analogues. Chem. Commun. 2013,49,   4570-4572.