picture
 
杨宇东
职称与职务
副教授
专      业
有机化学
电      话
028-85412285
E-Mail
简  历

2016.10—至今 四川大学化学学院,副教授

2014.7—2016.10 四川大学化学学院,讲师,合作导师:游劲松教授
2011.4—2014.3 名古屋工业大学,未来材料创成工学专业,博士学位,指导教师:Norio Shibata教授
2007.7—2010.7 北京化工大学,化学工程与技术专业,硕士学位,指导教授:杜洪光教授
2003.9—2007.7 北京化工大学,应用化学专业,学士学位
主要研究方向

(1)基于C-H键活化策略的(杂)芳环合成化学研究

(2)有机共轭材料分子的设计合成及性能研究

(3)含氟有机化合物的合成方法学研究

主要工作业绩

  作为负责人主持了国家自然科学基金青年基金、四川大学青年教师启动基金和四川大学优秀青年学者基金等研究项目。

  截止2017年9月,已在Chem. Rev., J. Am. Chem. Soc., Angew. Chem. Int. Ed.Chem. Commun.Org. Lett.等期刊发表SCI论文多篇;参与编写专著1部;申请专利1项。
主要奖励和荣誉
2017.6
2013级化学专业优秀生产实习队
2010.10-2014.03
日本文部科学省奖学金
2008.11
第六届中国“挑战杯”创业计划竞赛国家级银奖
2008.06
第五届“挑战杯”首都大学生创业计划竞赛特等奖
2008.04
北京化工大学第四届“寰球杯”创业计划与科技创新大赛一等奖
2007.06
北京市优秀毕业生
2006.11
北京化工大学优秀学生党员
2007.06
北京化工大学三好学生
2004.12
北京化工大学优秀学生干部

代表性成果 (获奖成果、专著、论文、专利)

研究论文:

1. Shiping Yang, Boya Feng, Yudong Yang*. “Rh(III)-Catalyzed Direct ortho-Chalcogenation of Phenols and Anilines”. J. Org. Chem. Accepted, DOI: 10.1021/acs.joc.7b02221.

2. Guangying Tan ? , Luoqiang Zhang ? , Xingrong Liao , Yang Shi , Yimin Wu , Yudong Yang , Jingsong You *. “Copper- or Nickel-Enabled Oxidative Cross-Coupling of Unreactive C(sp3)–H Bonds with Azole C(sp2)–H Bonds: Rapid Access to β-Azolyl Propanoic Acid Derivatives”. Org. Lett., 2017, 19(18), 4830?4833.
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3.  Juan Li , Yudong Yang , Zhigang Wang , Boya Feng , Jingsong You *. “Rhodium(III)-Catalyzed Annulation of Pyridinones with Alkynes via Double C–H Activation: A Route to Functionalized Quinolizinones”. Org. Lett.2017, 19(12), 3083?3086.
4. Zhen Long, Yudong Yang, Jingsong You*. “Rh(III)-Catalyzed [4+1]-Annulation of Azoxy Compounds with Alkynes: A Regioselective Approach to 2H-Indazoles”. Org. Lett. 2017, 19(11), 2781-2784.
5. Yudong Yang, Jingbo Lan, Jingsong You*. “Oxidative C–H/C–H Coupling Reactions between Two (Hetero)arenes”. Chem. Rev., 2017, 117(13), 8787?8863.
6. Chunxia Wang, Yudong Yang*. “Copper(II)-mediated intermolecular amination of inert C(sp3)–H bonds with simple alkylamines to construct α,α-disubstituted ß-amino acid derivatives”. Tetrahedron Lett., 2017, 58(10), 935?940.
7. Yudong Yang, Kaizhi Li, Yangyang Cheng, Danyang Wan, Mingliang Li, Jingsong You*. “Rhodium-catalyzed annulation of arenes with alkynes through weak chelation-assisted C–H activation”. Chem. Commun., 2016, 52, 2872?2884.
8. Yang Liu, Yudong Yang*, Yang Shi, Xiaojie Wang, Luoqiang Zhang, Yangyang Cheng, Jingsong You*. “Rhodium-Catalyzed Oxidative Coupling of Benzoic Acids with Terminal Alkynes: An Efficient Access to 3-Ylidenephthalides”. Organometallics, 2016, 35(10), 1350-1353.
9. Danyang Wan, Yudong Yang,* Xingyan Liu, Mingliang Li, Siling Zhao, Jingsong You*. “Radical Cyclization of Arenesulfonyl Chlorides and Alkynes: A Rapid Access to π-Conjugated Benzothiophenes”. Eur. J. Org. Chem., 2016, 55?59. (Most Accessed paper)
10. You Ran, Yudong Yang*. “Sodium chlorate as a viable substoichiometric oxidant for cobalt-catalyzed oxidative annulation of aryl sulfonamides with alkynes”. Tetrahedron Lett., 2016, 57(30), 3322-3325.
11. Chunxia Wang, Yudong Yang*, Dekun Qin, Zhen He, Jingsong You*. “Copper-Catalyzed Intramolecular Dehydrogenative Amidation of Unactivated C(sp3)-H Bonds Using O2 as the Sole Oxidant”. J. Org. Chem., 2015, 80(16), 8424?8429.
12. Mingliang Li, Yudong Yang, Danni Zhou, Danyang Wan, Jingsong You*. “Nickel-Catalyzed Addition-Type Alkenylation of Unactivated, Aliphatic C-H Bonds with Alkynes: A Concise Route to Polysubstituted γ-Butyrolactones”. Org. Lett., 2015, 17(10), 2546?2549.
13. Zhongyan Huang, Yu-Dong Yang, Etsuko Tokunaga, and Norio Shibata*. “Copper-Catalyzed Regioselective Trifluoromethylthiolation of Pyrroles by Trifluoromethanesulfonyl Hypervalent Iodonium Ylide”. Org. Lett., 2015, 17(5), 1094?1097.
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14. Zhongyan Huang, Yu-Dong Yang, Etsuko Tokunaga, and Norio Shibata*. “Synthesis of Billard–Langlois Reagents and their Derivatives by Copper-Catalyzed N-Trifluoromethylthiolation of Arylamines with a Trifluoromethanesulfonyl Hypervalent Iodonium Ylide”. Asian J. Org. Chem., 2015, 4(6), 525-527.
15. Yu-Dong Yang, Etsuko Tokunaga, Hidehiko Akiyama, Norimichi Saito, Norio Shibata, “Bis(pentafluorosulfanyl)phenyl Azide as an Expeditious Tool for Click Chemistry toward Antitumor Pharmaceuticals”, ChemMedChem 2014, 9(5), 913?917.
16. Yu-Dong Yang, Xin Wang, Seiji Tsuzuki, Etsuko Tokunaga, Norio Shibata, “Studies on the C/O–regioselectivity in Electrophilic Fluoromethylations of β-Ketoesters based on Thermodynamics by Ab initio Calculations”, Bull. Korean Chem. Soc. 2014, 35(6), 1851?1854.
17. Yu-Dong Yang, Ayaka Azuma, Etsuko Tokunaga, Mikio Yamasaki, Motoo Shiro, Norio Shibata, “Trifluoromethanesulfonyl hypervalent iodonium ylide for copper-catalyzed trifluoromethylthiolation of enamines, indoles, and β-keto esters”, J. Am. Chem. Soc. 2013, 135(24), 8782?8785.
18. Yu-Dong Yang, Kanji Iwamoto, Etsuko Tokunaga, Norio Shibata, “Transition-metal-free oxidative trifluoromethylation of unsymmetrical biaryls with trifluoromethanesulfinate”, Chem. Commun. 2013, 49, 5510?5512.
19. Hai Ma, Kohei Matsuzaki, Yu-Dong Yang, Etsuko Tokunaga, Daisuke Nakane, Tomohiro Ozawa, Hideki Masuda, Norio Shibata, “Enantioselective monofluoromethylation of aldehydes with 2-fluoro-1,3-benzodithiole-1,1,3,3-tetraoxide catalyzed by a bifunctional cinchona alkaloid-derived thiourea-titanium complex”, Chem. Commun. 2013, 49(95), 11206?11208.
Graphical abstract: Enantioselective monofluoromethylation of aldehydes with 2-fluoro-1,3-benzodithiole-1,1,3,3-tetraoxide catalyzed by a bifunctional cinchona alkaloid-derived thiourea–titanium complex
20. Yu-Dong Yang, Xu Lu, Guokai Liu, Etsuko Tokunaga, Seiji Tsuzuki, Norio Shibata, “Cation versus radical: studies on the C/O regioselectivity in electrophilic tri-, di, and monofluoromethylations of β-keto esters”, ChemistryOpen 2012, 1(5), 221?226.
21. Yu-Dong Yang, Xu Lu, Etsuko Tokunaga, Norio Shibata, “3,5-Bis(pentafluorosulfanyl)phenylboronic acid: a new organocatalyst for Conia-ene carbocyclization of 1,3-dicarbonyl compounds having terminal alkynes”, J. Fluorine Chem. 2012, 143, 204?209.
22. Tatsuya Furukawa, Yosuke Goto, Jumpei Kawazoe, Etsuko Tokunaga, Shuichi Nakamura, Yudong Yang, Hongguang Du, Akikazu Kakehi, Motoo Shiro, Norio Shibata, “2-Fluoro-1,3-benzodithiole-1,1,3,3-tetraoxide: a reagent for nucleophilic monofluoromethylation of aldehydes”, Angew. Chem. Int. Ed. 2010, 49(9), 1642?1647.
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专著:
1. Yudong Yang, Jingsong You, “Pd-Catalyzed Synthesis of Oxygen-Containing Heterocycles”. In “Transition Metal-Catalyzed Heterocycle Synthesis via C-H Activation” (Ed. Xiao-Feng. Wu), Wiley, Weinheim, Germany, 2016, pp65–89.

 

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