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李首建
职称与职务
教 授
专      业
放射化学
电      话
85412329
E-Mail
简  历
      四川大学化学学院放射化学教研室主任,应用化学专业实验室主任。 1977 年四川大学化学系放射化学专业毕业后留校任教至今。1988.9-1991.9 苏州医学院放射卫生专业,获硕士学位。 1999.12-2002.12 在 在美国北依利诺依斯大学 (Northern Illinois University, NIU) 化学及生物化学系固体材料化学研究组作客座研究员。现任中国核学会核化学与放射化学分会理事,中国核学会核化工分会理事。国家基础科学人才培养基金四川大学放射化学特殊学科点项目执行负责人。
主要研究方向
主讲课程:
本科:核技术基础及应用;应化设计实验(核辐射测量);天然药物化学导论
研究生:结晶化学;核技术基础及应用;研究专题(新型炭质功能材料的制备及铀等放射性核素分离性能与机理研究;核废物处理与处置);
 
研究生招生专业方向
  •       放射化学分离材料与技术
  •    核燃料循环与材料
  •  锕系元素化学
  • 主要研究方向   
主要从事新型功能材料的设计、合成及其在放射化学分离及核废物处理与处置中的应用研究。研究方向为:
  • 新型固体功能材料的设计及合成
  • 放射化学分离方法与技术
  •     核废物处理与处置
  •      锕系元素化学
主要工作业绩
利用炭质材料具有绝大多数其它无机固体材料所不能比拟的优良特性:较大的比表面积,耐高温,抗辐射,对各种酸碱环境有较高稳定性,而且本身无毒,环境友好等,从事新型炭质功能材料的设计、合成及在放射性核素分离领域的应用研究。研究涉及的炭质材料包括传统的活性炭、石墨和氧化石墨,以及新近开发的多孔炭、水热炭、石墨烯和石墨烯量子点等。采用多种方法探讨不同炭材料的表面化学性质、结构修饰方法和相应固相萃取剂的制备;考察合成材料对铀等核素的吸附行为和吸附动力学、热力学性能以及配位结构和配位(萃取)机制。
先后负责国家自然科学基金(4项)、中国核工业科学基金(3项)、四川省科技厅科学基金(3项)、中国工程物理研究院院外基金(2项)等19项科研项目,参加2项美国国家科学基金的研究工作。发表有关研究论文78篇,其中SCI论文59篇。
获2013年度四川大学十佳师德奖。
代表性成果 (获奖成果、专著、论文、专利)
近十年(截止至2014.09)发表的主要论文:
1. S.-J. Li, C. Zheng, Hj. Mattausch and A. Simon, Crystal structure of decacerium pentagallium tetrabromide, Ce10Ga5Br4, Z. Kristallogr. NCS, 2005, 220(4),521-522.
2.    Ying Lan, Zhe Su, Xingliang Li, Zhaoqun Jiang, Jun Jin, Jiali Xie, Shoujian Li*, Synthesis of a New Microporous Indium Sulphide and Its Capabilities to the Separation of Strontium, J. Radioanalytical Nuclear Chemistry. 2007, 273(1): 99-102.
3. Zhe Su, Xingliang Li, Ying Lan, Jintang Wen, Guangming Jin, Jiali Xie, Chong Zheng, Jun Jin, Shoujian Li*, A New Chalcogenide Ion Exchanging Material: Porous Indium Sulfide Built from Condensed [In10S18]6- T3 Supertetrahedral Clusters, Materials Letters. 2008, 62(17), 2802–2805.
4. Li Wang, Miao Feng, Chunxia Liu, Yongsheng Zhao, Shuqiong Li, Hang Wang, Liang Yan, Gan Tian, Shoujian Li*, Supporting of Potassium Copper Hexacyanoferrate on Porous Activated Carbon Substrate for Cesium Separation, Sep. Sc. Tech. 2009, 44(16), 4023–4035.
5. Miao Feng, Li Wang, Yongsheng Zhao, Chunxia Liu, Zhen Chen, Liang Yan, Gan Tian, Hang Wang, Shoujian Li*, Synthesis and Characterization of a New Activated carbon supported Ammonium Molybdophosphate composite and Its Cesium-selective Adsorption Properties, Radiochim Acta, 2010, 98 (1), 39-44.
6. Yongsheng Zhao, Chunxia Liu, Miao Feng, Zhen Chen, Shuqiong Li, Gan Tian, Li Wang, Jingbo Huang, Shoujian Li*, Solid phase extraction of uranium(VI) onto benzoylthiourea-anchored activated carbon, J. Hazard. Mater. 2010, 176, 119–124.
7. Liang Yan, Feng Zhao, Shoujian Li, Zhongbo Hu and Yuliang Zhao*, Low-toxic and safe nanomaterials by surface-chemical design, carbon nanotubes, fullerenes, metallofullerenes, and graphenes, Nanoscale, 2011, 3,362-382.
8. Gan Tian, Junxia Geng, Yongdong Jin, Chunli Wang, Shuqiong Li, Zhen Chen, Hang Wang, Yongsheng Zhao and Shoujian Li*, Sorption of uranium(VI) using oxime-grafted ordered mesoporous carbon CMK-5, J. Hazard. Mater. 2011,190, 422-450.
9. Shuqiong Li, Zhen Chen, Yongdong Jin, Shuihua Chen, Hang Wang, Junxia Geng, Qiang Song, Xiaodan Yang, Lijian Ma, Shoujian Li*, Zhi Qin*, and Chong Zheng, A new approach for preparation of magnetite-graphite composite: intercalation of polyhydroxy iron cation into graphite oxide in L-arginine medium, Solid State Science, 2011, 13: 862-866.
10. Zhen Chen, Lijian Ma, Shuqiong Li, Junxia Geng, Qiang Song, Jun Liu, Chunli Wang, Hang Wang, Juan Li, Zhi Qin, Shoujian Li*, Simple approach to carboxyl-rich materials via low-temperature heat treatment of hydrothermal carbon in air, Applied Surface Science, 2011 257(20), 8686– 8691.
11. Liang Yan, Yue Bing Zheng, Feng Zhao, Shoujian Li, Xingfa Gao, Bingqian Xu, Paul S. Weiss* and Yuliang Zhao*, Chemistry and physics of a single atomic layer: strategies and challenges for functionalization of graphene and graphene-based materials, Chem Soc Rev, 2012, 41, 97–114.
12. Gan Tian, Zhanjun Gu,*, Xiaoxiao Liu, Liangjun Zhou, Wenyan Yin, Liang Yan, Shan Jin,Wenlu Ren, Gengmei Xing, Shoujian Li,and Yuliang Zhao*, Facile Fabrication of Rare-Earth-Doped Gd2O3 Hollow Spheres with Upconversion Luminescence, Magnetic Resonance, and Drug Delivery Properties, |J. Phys. Chem. C, 2011, 115, 23790–23796.
13. Gan Tian, Zhanjun Gu,* Liangjun Zhou, Wenyan Yin, Xiaoxiao Liu, Liang Yan, Shan Jin, Wenlu Ren, Gengmei Xing, Shoujian Li, and Yuliang Zhao*, Mn2+ Dopant-Controlled Synthesis of NaYF4:Yb/Er Upconversion Nanoparticles for in vivo Imaging and Drug Delivery, Adv. Mater. 2012, 24, 1226–1231.
14. Junxia Geng, Lijian Ma, Hang Wang, Jun Liu, Chiyao Bai, Qiang Song, Juan Li, Min Hou, and Shoujian Li∗, Amidoxime-Grafted Hydrothermal Carbon Microspheres for Highly Selective Separation of Uranium, Journal of Nanoscience and Nanotechnology, 2012, 12 (9), 7354–7363.
15. Hang Wang, Lijian Ma, Kecheng Cao, Junxia Geng, Jun Liu, Qiang Song, Xiaodan Yang, Shoujian Li*, Selective Solid-phase Extraction of Uranium by Salicylideneimine-functionalized Hydrothermal Carbon, J. Hazard. Mater. 2012, 229-230, 321-330.
16. Qiang Song, Lijian Ma, Jun Liu, Chiyao Bai, Junxia Geng, Hang Wang, Bo Li, Liyue Wang, Shoujian Li*, Preparation and Adsorption Performance of 5-azacytosine-functionalized Hydrothermal Carbon for Selective Solid-phase Extraction of Uranium, Journal of Colloid and Interface Science, 2012, 386, 291–299.
17. Jun Liu, Juan Li, Xiaodan Yang, Qiang Song, Chiyao Bai, Yong Shi, Lan Zhang, Chunxi Liu, Shoujian Li*, Lijian Ma*, Facile preparation of polyphenolic hydroxyl functionalized uranium-selective chelating sorbent: simple oxidation of styrene–divinylbenzene copolymer microparticles by Hummers method, Materials Letters, 2013, 97, 117-180.
18. Zhanjun Gu, Liang Yan, Gan Tian, Shoujian Li, Zhifang Chai, and Yuliang Zhao*, Recent Advances in Design and Fabrication of Upconversion Nanoparticles and Their Safe Theranostic Applications, Adv. Mater. 2013, 25(28) 3758–3779.
19. Xingliang Li, Wanjun Mu, Bijun Liu, Wenbin Zhong, Hongyuan Wei, Yuan, Jian, Zhengkun Zhong, Shunzhong Luo & Shoujian Li*, Adsorption kinetic, isotherm and thermodynamic studies of Sr2+ onto hexagonal tungsten oxide, J Radioanal Nucl Chem (2013) 298(1), 47-53.
20. Xiaodan Yang, Juan Li, Jun Liu, Yin Tian, Bo Li, Kecheng Cao, Songbai Liu, Min Hou, Shoujian Li* and Lijian Ma*, Simple Small Molecule Carbon Source Strategy for Synthesis of Functional Hydrothermal Carbon: Preparation of Highly Efficient Uranium Selective Solid Phase Extractant, Journal of Materials Chemistry A, 2014, 2(5), 1550-1559.
21. Bo Li, Lijian Ma, Yin Tian, Xiaodan Yang, Juan Li, Chiyao Bai, Xiaoyu Yang, Shuang Zhang, Shoujian Li, Yongdong Jin, A catechol-like phenolic ligand-functionalized hydrothermal carbon: One-pot synthesis, characterization and sorption behavior toward uranium, J. Hazard. Mater., 2014, 217, 41–49.
22. Chiyao Bai, Juan Li, Songbai Liu, Xiaoyu Yang, Xiaodan Yang, Yin Tian, Kecheng Cao, Ying Huang, Lijian Ma*, Shoujian Li*, In situ preparation of nitrogen-rich and functional ultramicro porous carbonaceous COFs by “segregated” microwave irradiation, Microporous and Mesoporous Materials, 2014, 197, 148–155.
23. Ying Huang, Chiyao Bai, Kecheng Cao, Yin Tian, Yue Luo, Chuanqin Xia, Songdong Ding, Yongdong Jin, Lijian Ma* and Shoujian Li*, Chaos to order: an eco-friendly way to synthesize graphene quantum dots. RSC Adv., 2014, 4, 43160–43165.
24. K. Cao, Y. Tian, Y. Zhang, C. Bai, Y. Luo, X. Zhao, L. Ma* and S. Li*, “Strategy and Mechanism for Controlling Direction of Defect Evolution in Graphene: Preparation of High-Quality Defect-Healed and Hierarchically Porous Graphene”, Nanoscale. 2014, DOI:10.1039/C4NR04453C.
25. Yin Tian, Jia Fu, Yi Zhang, Kecheng Cao, Chiyao Bai, Dongqi Wang, Shoujian Li,* Ying Xue,* Lijian Ma,* Chong Zheng*, Insight into the mechanism of solid phase extraction of uranium: a combined experimental and theoretical study, Inorg. Chem. 2014, submitted.
 
 
 

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