picture
 
高戈
职称与职务
教 授(博导)
专      业
有机化学
电      话
028-85418195
E-Mail
简  历

1994年9月 ~ 1998年7月,四川大学化学系,本科

1998年9月 ~ 2004年7月,四川大学化学系,博士研究生

 2004年7月 ~ 2005年2月,四川大学化学学院,工作

 2005年3月 ~ 2008年5月,美国University of Virginia,博士后

2008年7月 ~ 现在,四川大学化学学院,任教

主要研究方向
芳杂环构筑 荧光功能材料 及应用

有机合成方法学

主要工作业绩
入选2013年教育部“新世纪优秀人才支持计划”。
“简单金属盐催化的C-C键和C-N键形成反应”, 教育部自然科学奖一等奖 ,2011年1月,第6完成人。
论文 Angew. Chem. Inter. Ed.2006, 45(1), 122-125荣获 第一届 中国百篇最具影响优秀国际学术论文 ”。

代表性成果 (获奖成果、专著、论文、专利)
1. Li, S.; Tang, J.; Zhao, Y.; Jiang, R.; Gao, G.;* You, J.* Cu-Catalyzed Selective C?H Mono-/Di-/Triarylation of Imidazolium Salts for Ionic Functional MaterialsChem. Commun. 2017, DOI: 10.1039/c7cc01076a.
2. Zhao, Y.; Li, S.; Zheng, X.; Tang, J.; She, Z.; Gao, G.;* You, J.* Rh/Cu-Catalyzed Cascade [4+2] Vinylic C–H O-Annulation and Ring Contraction of a-Aryl Enones with Alkynes in AirAngew. Chem. Int. Ed.2017, DOI: 10.1002/anie.201612147.
3. Tang, J.; Li, S.; Liu, Z.; Zhao, Y.; She, Z.; Kadam, V. D.; Gao, G.;* Lan, J.; You, J.* Cascade C?H Annulation of Aldoximes with Alkynes using O2 as the Sole Oxidant: One-Pot Access to Multisubstituted Protoberberine SkeletonsOrg. Lett.2017, 19, 604.
4. He, Z.; Qi, X.; She, Z.; Zhao, Y. Li, S.; Tang, J.; Gao, G.;* Lan, Y.;* You, J.* Room-Temperature Coupling/Decarboxylation Reaction of α?Oxocarboxylates with α?Bromoketones: Solvent-Controlled Regioselectivity for 1,2- and 1,3-DiketonesJ. Org. Chem.2017, 82, 1403.
5. Feng, B.; Wan, D.; Yan, L.; Kadam, V. D.; You, J.; Gao, G.* A Facile Access to Substituted Cationic 12-Azapyrene Salts by Rhodium(III)-Catalyzed C–H Annulation of N-Arylpyridinium SaltsRSC Adv.2016, 6, 66407.
6. Cheng, Y.; Li, G.; Liu, Y.; Shi, Y.; Gao, G.;* Wu, D.; Lan, J.; You, J.* Unparalleled Ease of Access to a Library of Biheteroaryl Fluorophores via Oxidative Cross-Coupling Reactions: Discovery of Photostable NIR Probe for MitochondriaJ. Am. Chem. Soc.2016, 138, 4730.
7. Zhao, Y.; He, Z.; Li, S.; Tang, J.; Gao, G.;* Lan, J.; You, J.* An Air-stable Half-sandwich RuII Complex as Efficient Catalyst for [3+2] Annulation of 2-Arylcyclo-2-enones with AlkynesChem. Commun. 2016, 52, 4613. (Cover story)
8. Qin, D.; Wang, J.; Qin, X.; Wang, C.; Gao, G.;* You, J.* Rh(III)-catalyzed oxime ether-directed heteroarylation of arene through oxidative C–H/C–H cross-couplingChem. Commun. 2015, 51, 6190.
9. He, Z.; Qi, X.; Li, S.; Zhao, Y.; Gao, G.;* Lan, Y.;* Wu, Y.; Lan, J.; You, J.* Transition-Metal-Free Formal Decarboxylative Coupling of α-Oxocarboxylates with α-Bromoketones under Neutral Conditions: A Simple Access to 1,3-DiketonesAngew. Chem. Int. Ed.2015, 54, 855.
10. Li, J.; Wang, Z.; Wu, N.; Gao, G.* You, J.* Radical Cascade Cyanomethylation of Activated Alkenes to Construct Cyano Substituted OxindolesChem. Commun.,2014, 50 (95), 15049.
11. Li, C.; Gao, C.; Lan, J.; You, J.; Gao, G.* An AIE Active Y-shaped Diimidazolylbenzene: Aggregation and Disaggregation for Cd2+ and Fe3+ Sensing in Aqueous SolutionOrg. Bio. Chem., 2014, 12, 9524.
12. Gao, C.; Gao, G.;* Lan, J.; You, J.* An AIE Active Monoimidazolium Skeleton: High Selectivity and Fluorescence Turn-on for H2PO4- in Acetonitrile and ClO4- in WaterChem. Commun.2014, 50, 5623.
13. Li, S.; Yang, F.; Lv, T.; Lan, J.; Gao, G.;* You, J.* Synthesis of Unsymmetrical Imidazolium Salts by Direct Quaternization of N-Substituted Imidazoles with Arylboronic AcidsChem. Commun.2014, 50, 3941.
14. Zhou, H.; Zhao, Y.; Gao, G.;* Li, S.; Lan, J.; You, J.* Highly Selective Fluorescent Recognition of Sulfate in Water by Two Rigid Tetrakisimidazolium Macrocycles with Peripheral ChainsJ. Am. Chem. Soc.2013, 135, 14908.
15. Lv, T.; Yang, L.; Zhao, Y.; Song, F.; Lan, J.; You, J.;* Gao, G.* One-pot Synthesis of Diarylimidazolium Salts from 1H-ImidazoleChin. Chem. Lett.2013, 24, 773.
16. 王志,周红军,胡俊毅,游劲松*,高戈* 十字架型间二咪唑(鎓)苯的合成及对有机酸的识别化学学报2013, 71, 1257.
17. Hu, J.; He, Z.; Wang, Z.; Li, X.; You, J.; Gao, G.* A Simple Approach to Aggregation-Induced Emission in Difluoroboron Dibenzoylmethane DerivativesTetrahedron Lett.2013, 54, 4167.
18. Lv, T.; Wang, Z.; You, J.* Lan, J.; Gao, G.;* Copper-Catalyzed Direct Aryl Quaternization of N-Substituted Imidazoles to Form Imidazolium SaltsJ. Org. Chem.2013, 78, 5723.
19. Zhou, H.; Wang, Z.; Gao, C.; You, J.; Gao, G.* Synthesis and Characterization of a Luminescent and Fully Rigid Tetrakisimidazolium MacrocycleChem. Commun.2013, 49, 1832.
20. Gao, C.; Zhou, H.; Wei, S.; Zhao, Y.; You, J.; Gao, G.* Novel Bisimidazolium Pincers as Low Loading Ligands for in situ Palladium-Catalyzed Suzuki-Miyaura Reaction in the Ambient AtmosphereChem. Commun.2013, 49, 1127.
21. 周红军,兰静波,高戈,游劲松 咪唑鎓大环的研究进展中国科技论文2013, 8, 587.
22. Yang, S.; You, J.;* Lan, J.; Gao, G.* Facile Access to Extremely E?cient Energy-Transfer Pairs via an Unexpected Reaction of Squaraines with KetonesJ. Am. Chem. Soc.2012, 134, 11868.
23. Cheng, L.; Dong, J.; You, J.; Gao, G.;* Lan, J.* A Highly syn-Selective Nitroaldol Reaction Catalyzed by CuII-BisimidazolineChem. -Eur. J.2010, 16(23), 6761.
24. Gao, G.;* Pu, L.* γ-Hydroxy-α,β-acetylenic esters: asymmetric syntheses and applicationsSci China Chem.2010, 53, 21.
25. Gao, G.; Wang, Q.; Yu, X. -Q.*; Xie, R. -G.; Pu, L.* Highly Enantioselective Synthesis of γ-Hydroxy-α,β-acetylenic Esters by Asymmetric Alkyne Addition to Aldehydes Angew. Chem. Int. Ed.2006, 45(1), 122.
26. Gao, G.; Xie, R. -G.; Pu, L.* Highly Enantioselective Alkyne Additions to Aldehydes in the Presence of BINOL and HMPAProc. Natl. Acad. Sci. USA2004, 101(15), 5417.
27. Gao, G.; Moore, D.; Xie, R. -G.; Pu, L.* Highly Enantioselective Phenylacetylene Additions to Both Aliphatic and Aromatic AldehydesOrg. Lett.2002, 4(23), 4143.
28. Gao, G.; Xiao, R.; Yuan, Y.; Zhou, C. -H.; You, J. -S.; Xie, R. -G.* Efficient Imidazolium Catalysts for the Benzoin CondensationJ. Chem. Res. -S.2002, (6), 262.