picture
 
付海燕
职称与职务
副教授
专      业
有机化学
电      话
028-85412904
E-Mail
简  历
教育经历
1994/9–1998/7,四川大学化学学院,学士
2000/9–2003/7,四川大学化学学院,硕士,导师:陈华
2003/9–2006/7,四川大学化学学院,博士,导师:陈华
科研与学术工作经历
2006/7-2009/7,四川大学化学学院,任教
2009/7-至今,四川大学化学学院,副教授
2011/4-2012/4,法国雷恩一大,访问学者,师从Henri Doucet教授
2013/9-2015/3,美国Scripps研究所,访问学者,师从余金权教授
主要研究方向
过渡金属催化的新型碳-碳,碳-杂偶联反应研究,包括Heck,Suzuki,Sonagashira等传统交叉偶联反应等;
 发展新的杂环化合物的构建及衍生方法;
缺电芳杂环的官能化反应研究;
导向C-H键官能化反应;

不对称氢甲酰化反应研究

主要工作业绩

主持或参加科研项目

国家自然科学基金面上项目,21072138, 负载金属催化剂表面羟基和溶剂水对羧基加氢的作用机理研究,2011/01-2014/12,36万,已结题,主研
国家自然科学基金青年基金项目, 21202104, 含氮四膦配体及其钯配合物的合成,表征及其催化Heck反应研究,2013/01--2015/12, 25万元,已结题,主持
在Science;J. Am. Chem. Soc.;Angew.Chem. Int. Ed.;Org. Lett.;Chem.Commun.;J. Org. Chem.;Adv. Synth.Catal.;Eur. J. Org. Chem.;J. Mol. Catal. A: Chem.; Appl. Catal. A: General等杂志上发表论文100多篇,申请发明专利2项,主持和参研自然科学基金及企业合作项目10余项。
代表性成果 (获奖成果、专著、论文、专利)
1. Zeng, Y.; Zhang, C.; Yin, C.; Sun, M.; Fu, H.*; Zheng, X.; Yuan, M.; Li, R.; Chen, H. *, Direct C-H Functionalization of Pyridine via a Transient Activator Strategy: Synthesis of 2,6-Diarylpyridines. Org Lett 2017, 19 (8), 1970-1973.
2. Huang, J.; Wang, W.; He, H.-Y.; Jian, L.; Fu, H.-Y. *; Zheng, X.-L.; Chen, H.; Li, R.-X.*, An Approach to the Synthesis of 1-Propenylnaphthols and 3-Arylnaphtho[2,1-b]furans. The Journal of Organic Chemistry 2017, 82 (5), 2523-2534.
3. Fu, H.; Shen, P. X.; He, J.; Zhang, F.; Li, S.; Wang, P.; Liu, T.; Yu, J. Q., Ligand-Enabled Alkynylation of C(sp3 )-H Bonds with Palladium(II) Catalysts. Angewandte Chemie 2017, 56 (7), 1873-1876.
4. Liu, H.; Han, W.; Li, C.; Ma, Z.; Li, R.; Zheng, X.; Fu, H. *; Chen, H. *, Practical Synthesis of Phenanthridinones by Palladium-Catalyzed One-Pot C-C and C-N Coupling Reaction: Extending the Substrate Scope too-Chlorobenzamides. European Journal of Organic Chemistry 2016, 2016 (2), 389-393.
5. Wang, W.; Huang, J.; Zhou, R.; Jiang, Z.-J.; Fu, H.-Y. *; Zheng, X.-L.; Chen, H.; Li, R.-X.*, A Simple and Efficient Access to Naphtho[b]furans by Claisen Rearrangement/Cyclization of Bromonaphthyl 3-Phenylallyl Ethers. Advanced Synthesis & Catalysis 2015, 357 (11), 2442-2446.
6. Ma, Z.; Liu, H.; Zhang, C.; Zheng, X.; Yuan, M.; Fu, H. *; Li, R.; Chen, H. *, One-Pot Synthesis of Symmetrical 2,6-DiarylpyridinesviaPalladium/Copper-Catalyzed Sequential Decarboxylative and Direct C?H Arylation. Advanced Synthesis & Catalysis 2015, 357 (6), 1143-1148.
7. Ge, Y.; Cheng, Y.; Fu, H. *; Zheng, X.; Li, R.; Chen, H. *; Li, X., Suzuki-Miyaura cross-coupling reaction catalyzed by a highly stable Pd(P-Phos)Cl-2 complex at room temperature under air. Chinese Journal of Catalysis 2013, 34 (9), 1667-1673.
8. Fu, H.; Chen, H.; Doucet, H., Palladium-catalyzed selective decarboxylative coupling reaction versus direct C?H arylation for arylation of heteroaromatics. Applied Organometallic Chemistry 2013, 27 (10), 595-600.
9. Fu, H. Y.; Zhao, L.; Bruneau, C.; Doucet, H., Palladium-Catalysed Direct Heteroarylations of Heteroaromatics Using Esters as Blocking Groups at C2 of Bromofuran and Bromothiophene Derivatives: A One-Step Access to Biheteroaryls. Synlett 2012,  (14), 2077-2082.
10.Fu, H. Y.; Chen, L.; Doucet, H., Phosphine-Free Palladium-Catalyzed Direct Arylation of Imidazo 1,2-a pyridines with Aryl Bromides at Low Catalyst Loading. Journal of Organic Chemistry 2012, 77 (9), 4473-4478.
11.Pi, X.; Zhou, Y.; Zhou, L.; Yuan, M.; Li, R.; Fu, H. *; Chen, H.*, Dicyclopentadiene Hydroformylation in an Aqueous/Organic Two Phase System in the Presence of a Cationic Surfactant. Chinese Journal of Catalysis 2011, 32 (4), 566-571.
12.Liu, H.; Yuan, M.; Guo, C.; Li, R.; Fu, H. *; Chen, H. *; Li, X., Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol over Ru/ZrO2 center dot xH(2)O Catalyst. Chinese Journal of Catalysis 2011, 32 (7), 1256-1261.
13.Fu, H. Y.; Doucet, H., Methyl 2-Furoate: An Alternative Reagent to Furan for Palladium-Catalysed Direct Arylation. European Journal of Organic Chemistry 2011,  (35), 7163-7173.
14.Fu, H.; Yuan, M.; Chen, H.; Li, R.; Li, X., Progress of Olefin Hydroformylation Catalyzed by Water-Soluble Rhodium-Phosphine Complexes. Chinese Journal of Catalysis 2010, 31 (3), 251-260.
15.Mao, H.; Fu, H. *; Chen, H. *; Li, R.; Li, X., Synergistic Effect of TPPTS and TPPDS on the Regioselectivity for 1-Decene Hydroaminomethylation in a Two-Phase Catalytic System. Chinese Journal of Catalysis 2009, 30 (12), 1192-1196.
16.Fu, H.; Li, M.; Mao, H.; Lin, Q.; Yuan, M.; Li, X.; Chen, H., Aqueous biphasic catalytic hydroformylation of higher olefins: Promotion effect of cationic gemini and trimeric surfactants. Catalysis Communications 2008, 9 (7), 1539-1544.
17.Fu, H.; Li, M.; Chen, J.; Zhang, R.; Jiang, W.; Yuan, M.; Chen, H.; Li, X., Application of a new amphiphilic phosphine in the aqueous biphasic catalytic hydroformylation of long chain olefins. Journal of Molecular Catalysis a-Chemical 2008, 292 (1-2), 21-27.
18.Fu, H.; Li, M.; Chen, H.; Li, X., Higher olefin hydroformylation in organic/aqueous biphasic system accelerated by double long-chain cationic surfactants. Journal of Molecular Catalysis a-Chemical 2006, 259 (1-2), 156-160.

19.Fu, H.; Guo, Y.; Lin, Q.; Chen, H.; Li, X., Cocatalytic effect of new surface-active phosphine in long-chain olefin hydroformylation. Chinese Journal of Catalysis 2006, 27 (12), 1053-1058.

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