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董 顺 喜
职称与职务
教 授
专      业
有机化学
电      话
15719421858
E-Mail
课题组网站:
简  历

 教育经历:

2004.09~2008.06 四川大学  化学专业  理学学士学位  
2008.09~2013.06 四川大学  有机化学  理学博士学位  导师:冯小明
研究及工作经历:
2013.11~2016.02 德国亚琛工业大学  洪堡学者  (Carsten Bolm教授)
2016.07~2017.12 德国明斯特大学  博士后  (Gerhard Erker教授)
2018.01~至今 四川大学化学学院  特聘研究员
主要研究方向

手性配体或催化剂的设计合成及其在不对称催化中的应用
金属有机化学

主要工作业绩

研究经历

董顺喜博士毕业于四川大学,师从冯小明教授,博士研究方向主要是手性胍类小分子催化剂的设计、合成及其在吖内酯参与的环化反应中的应用。2013作为洪堡学者赴德国亚琛工业大学Carsten Bolm教授课题组开展博士后研究工作。主要从事氨基酸衍生的pentathiepin设计合成以及手性氮杂环卡宾(NHO)催化的不对称转化领域的研究。2016年,加入德国明斯特大学Gerhard Erker课题组,开展主族元素有机化学的研究,主要从事新型受阻Lewis酸碱对(FLP)的设计合成及其反应性研究。目前为止,已取得了一系列创新性的研究成果, 在Chem.Soc. Rev., J. Am. Chem. Soc., Angew. Chem. Int. Ed., Org. Lett., Chem.Commun., Chem. -Eur. J. 以及 Dalton. Trans. 等刊物发表 SCI 论文26篇,多篇工作被Synfacts杂志刊登并给予高度评价。其中以第一作者身份发表 SCI 论文7篇,作为共同通讯作者论文1篇。

主要奖励及荣誉
2013     德国洪堡学者博士后奖学金
2011     教育部 “博士研究生学术新人奖”
2011     云天化奖学金
2006     国家奖学金
代表性成果 (获奖成果、专著、论文、专利)
论文发表情况
(1)     Dong, S. X.; Feng, X. M.; Liu, X. H.* "Chiral Guanidine and Their Derivatives
in Asymmetric Synthesis" Chem. Soc. Rev. (Minor Revision).
(2)     Zhong, X.; Tang, Q., Zhou, P. F.; Zhong, Z. W. Dong, S. X.*; Liu, X. H.; Feng, X. M.*, Asymmetric Synthesis of Polysubstituted Methylenecyclobutanes via Catalytic [2+2] Cycloaddition Reaction of N-Allenamides, Chem. Commun. 2018, 54, 10511.
(3)     Dong, S. X.; Frings, M.; Cheng, H. C.; Wen, J.; Zhang, D.; Rabbe, G.; Bolm, C.* " Organocatalytic Kinetic Resolution of Sulfoximines" J. Am. Chem. Soc. 2016, 138, 2166. Highlight by Synfacts ( 2016, 634)
Abstract Image
(4)     Dong, S. X.; Liu X. H*.; Zhu, Y.; He, P.; Lin, L. L.; Feng, X. M.* " Organocatalytic Oxyamination of Azlactones: Kinetic Resolution of Oxaziridines and Asymmetric Synthesis of Oxazolin-4-ones" J. Am. Chem. Soc. 2013, 135, 10026. Highlight by Synfacts ( 2013, 1006)
(5)     Dong, S. X.; Liu, X. H.; Chen, X. H.; Mei, F.; Gao, B.; Lin, L. L.; Feng, X. M.* " Chiral Bisguanidine-Catalyzed Inverse-Electron-Demand Hetero-Diels-Alder Reaction of Chalcones with Azlactones" J. Am. Chem. Soc. 2010, 132, 10650. Highlight by Synfacts ( 2010, 1105)
(6)     Dong, S. X.; Frings, M.; Zhang, D.; Guo. Q. Q.; Danilliuc, C. G.; Cheng, H. C.; Bolm, C.* " Organocatalytic Asymmetric Synthesis of trans-γ-Lactams" Chem. Eur. J. 2017, 23, 13888.
(7)     Dong, S. X.; Wang, L.; Wang, T.; Daniliuc, C. G.; Brinkkötter, M.; Eckert, H.; Kehra. G.; Erker, G. " Formation and Reactions of Active Five-membered Phosphane/borane Frustrated Lewis Pair Ring Systems" Dalton Trans. 2018, 47, 4449.
(8)     Dong, S. X.; Liu, X. H*.; Zhang, Y. L.; Lin, L. L.; Feng, X. M *. " Asymmetric Synthesis of 3,4-Diaminochroman-2-ones Promoted by Guanidine and Bisguanidium Salt" Org. Lett. 2011, 13, 5060.
(9)     Liu, X. H.; Dong, S. X.; Lin, L. L.; Feng, X. M.* " Chiral Amino Acids-Derived Catalysts and Ligands " Chin. J. Chem, 2018, 36, 791.
(10)Guo, J.; Dong, S. X.; Zhang, Y. L.; Kuang, Y. L.; Feng, X. M.* " Chiral Scandium(III)-Catalyzed Enantioselective α-Arylation of N-Unprotected 3-Substituted Oxindoles with Diaryliodonium Salts" Angew. Chem., Int. Ed. 2013, 52, 10245. Highlight by Synfacts ( 2013, 1262)
(11)Wang, L.; Dong, S. X.; Daniliuc, C. G.; Liu, L.; Grimme, S.; Knitsch, R.; Eckert, H.; Hansen, M. R.; Kehra. G.; Erker, G." Formation of Macrocyclic Ring Systems by Carbonylation of Trifunctional P/B/B Frustrated Lewis Pairs" Chem. Sci. 2018, 9, 1544.
(12)Xu, X.; Zhang, J. L.; Dong, S. X.; Lin. L. L.; Lin, X. B.; Liu, X. H.; Feng, X. M.* " Nickel(II)-Catalyzed Asymmetric Propargyl [2,3]-Wittig Rearrangement of Oxindole Derivatives: A Remarkable Chiral Amplification Effect" Angew. Chem., Int. Ed. 2018, 57, 8734.
(13)Zhu, Y.; Liu, X. H.;* Dong, S. X.; Zhou, Y. H.; Li, W.; Lin, L. L.; Feng, X. M.* " Asymmetric N-H Insertion of Secondary and Primary Anilines under the Catalysis of Palladium and Chiral Guanidine Derivatives" Angew. Chem., Int. Ed. 2014, 53, 1636.
(14)Wen, J.; Cheng, H. C.; Dong, S. X.; Bolm, C.* " Copper-Catalyzed S-C/S-N Bond Interconversions" Chem. Eur. J. 2016, 22, 5547.
(15)Chen, X. Y.; Bohmann, R. A.; Wang, L.; Dong, S. X.; Räuber, C.; Bolm, C.* " Palladium/Copper-Cocatalyzed Oxidative Amidobrominations of Alkenes" Chem. Eur. J. 2015, 21, 10330.
(16)Cheng, H.; Dong, W.; Dannenberg, C. A.; Dong, S. X.; Guo, Q.; Bolm, C.* " Ruthenium-Catalyzed Hydroarylations of Oxa- and Azabicyclic Alkenes" ACS Cat. 2015, 5, 2770.
(17)Yao, Q.; Yu, H.; Zhang, H.; Dong, S. X.; Chang, F. Z.; Lin, L. L.; Liu, X. H.; Feng, X. M.* " Lewis acid catalyzed asymmetric [4+2] cycloaddition of cyclobutenones to synthesize α,β-unsaturated δ-lactones" Chem. Commun. 2018, 54, 3375.
(18)Chen, X. H.; Dong, S. X.; Qiao, Z.; Zhu, Y.; Xie, M. S.; Lin, L. L.; Liu, X. H.;* Feng, X. M.* " Guanidine Organocatalyst for Asymmetric Mannich-Type Reaction between α-Isothiocyanato Imide and Sulfonyl Imines" Chem. Eur. J. 2011, 17, 2583.
(19)Zhang, Y. L.; Dong, S. X.; Liu, X. H.; Xie. M. S.; Zhu, Y.; Lin, L. L.; Feng, X. M. * " Asymmetric Synthesis of cis-4-Aminobenzopyran Derivatives Catalyzed by N,N'-Dioxide-Sc(OTf)3 Complex " Chem. Eur. J. 2011, 17, 13684.
(20)Yang, Y.; Dong, S. X.; Liu, X. H.; Lin, L. L.; Feng, X. M. * " Chiral guanidine-catalyzed asymmetric direct vinylogous Michael reaction of α,β-unsaturated γ-butyrolactams with alkylidene malonates " Chem. Commun., 2012 , 48, 5040.
(21)Xiao, X.; Liu X. H *.; Dong, S. X.; Cai, Y. F.; Lin, L. L.; Feng, X. M. * " Asymmetric Synthesis of 2,3-Dihydroquinolin-4-one Derivatives Catalyzed by Chiral Bisguanidium Salt" Chem. Eur. J. 2012, 18, 15922.
(23)Wang, J.; Liu, X. H.; * Dong, S. X.; Lin, L. L.; Feng, X. M. * " Asymmetric Organocatalytic Cyclopropanation of Cinnamone Derivatives with Stabilized Sulfonium Ylides" J. Org. Chem. , 2013 , 78, 6322.
(24)Xiong, Y.; Wang, F.; Dong, S. X.; Liu, X. H.; Feng, X. M. * " Asymmetric Bisprolinamide-Catalyzed Cross-Aldol Reaction of Aldehydes" Synlett. 2008, 1, 73.
(25)Zhu, Y.; Chen, X. H.; Xie, M. S.; Dong, S. X.; Qiao, Zhen.; Lin, L. L.; Liu, X. H.; Feng, X. M. * " Asymmetric Diels–Alder and Inverse-Electron-Demand Hetero-Diels–Alder Reactions of β,γ-Unsaturated α-Ketoesters with Cyclopentadiene Catalyzed by N,N′-Dioxide Copper(II) Complex" Chem. Eur. J. 2010, 16, 11963.

(26)Wen, Y. H.; Gao, B.; Fu, Y. Z.; Dong, S. X.; Liu, X. H.;Feng, X. M. * " Asymmetric Three-Component Strecker Reactions Catalyzed by trans-4-Hydroxy-L-proline-Derived N,N′-Dioxides" Chem. Eur. J. 2008, 14, 6789. 

 

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